| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 戴郁潔 | zh_TW |
| DC.creator | Yu-chieh Tai | en_US |
| dc.date.accessioned | 2015-7-29T07:39:07Z | |
| dc.date.available | 2015-7-29T07:39:07Z | |
| dc.date.issued | 2015 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=102223048 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 本論文研究合成一系列間位四咔唑二苯胺(Bis(3,5-di(9H-carbazol-9-yl)phenyl)amine, CzPA)衍生物，以開發藍色或綠色有機發光二極體主體材料為目標，將CzPA單體與不同拉電子基團(oxdiazole、benzoimidazole、diphenylphenanthroimidazole)組成雙極性主體材料CzPA-2OXD、CzPA-2P-OXD、CzPA-2P-PPI、CzPA-2P-PBI、CzPA-3P-PBI，以及將CzPA單體與N-phenylnaphthlen組成形成傳電洞性主體材料CzPA-NPD、CzPA-2P-NPD、CzPA-3P-NPD。所得之主體材料被應用於綠色或藍色磷光OLED元件製作。其中以CzPA-2OXD為主體材料製作單層濕式製程之綠色元件之電流效率最大可以達到6.9 cd/A，最大功率效率為1.5 lm/W，其電激發光光譜最大放光峰為514 nm。 | zh_TW |
| dc.description.abstract | In this dissertation, we designed and synthesized a series of bis(3,5-di(9H-carbazol-9-yl)phenyl)amine (CzPA) derivatives as the host materials for the application of green and blue phosphorscence organic light-emittung diodes. In general, the molecular design of host material was introduced the -spacer between the electron-donating (D) and electron-withdrawing (A) moieties to achieve highly efficient PhOLEDs. We designed several “D--A” host materials (CzPA-2OXD, CzPA-2P-OXD, CzPA-2P-PPI, CzPA-2P-PBI and CzPA-3P-PBI), comprising of -spacer linking CzPA (donor) and N-phenylbenzimidazole/1,3,4-oxadiazole/ diphenylphenanthroimidazole (acceptor). We also designed several host materials of hole transporting type molecules (CzPA-NPD, CzPA-2P-NPD and CzPA-3P-NPD), comprising of different -spacer linking CzPA and N-phenylnaphthlen (NPD). The results showed that the CzPA-2OXD host with a green phosphor Ir(ppy)3 gave a maximum current efficiency (c) of 6.9 cd/A and power efficiency (p) of 1.5 lm/W. | en_US |
| DC.subject | 有機發光二極體 | zh_TW |
| DC.subject | 主體材料 | zh_TW |
| DC.title | 間位四咔唑二苯胺衍生物應用於藍色磷光有機發光二極體主體材料之合成與鑑定 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Synthesis and Characterization of Bis(3,5-di(9H-carbazol-9-yl)phenyl)amine (CzPA) Derivates for the Host Material of Blue Phosphorescence Organic Light-emitting Diodes. | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |