DC 欄位 值 語言 DC.contributor 化學學系 zh_TW DC.creator 吳雅雯 zh_TW DC.creator Ya-Wen Wu en_US dc.date.accessioned 2017-7-18T07:39:07Z dc.date.available 2017-7-18T07:39:07Z dc.date.issued 2017 dc.identifier.uri http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=104223001 dc.contributor.department 化學學系 zh_TW DC.description 國立中央大學 zh_TW DC.description National Central University en_US dc.description.abstract 本論文主要可以分為有機薄膜電晶體 (OTFTs)、有機光伏打電池電池 (OPVs) 和有機發光二極體 (OLEDs) 的材料介紹。 本研究主要設計出新興可溶性噻吩並吡咯酮衍生物的有機光電材料，以具有支碳鏈之噻吩並吡咯酮 (TP) 與羅丹寧作為末端拉電子基團，分別與噻吩、苯環以及多稠環噻吩衍生物之核心共軛單元耦合，開發出十三個新的有機化合物，依分類可歸納出以下幾種，可溶性單環系列：DTPRT (1)、DTPRT-b8 (3)、DTPRP-b8 (4)，可溶性雙環系列：DTPRTT-b8 (5)、DTPRbT-b8 (6)，可溶性多環系列：DTPRBDT-b8 (11)、DTPRIDT-b8 (12)、DTPRIDTT-b8 (13)，以及溶解度不佳的化合物：DTPRbT (2)、DTPRDTT-b8 (7)、DTPR3T-b8 (8)、DTPRffBT-b8 (9)、DTPRSF-b8 (10)。 利用 UV-vis 與 DPV 探討所開發分子的 HOMO 與 LUMO 能階，藉由 TGA 探討這些新開發材料之熱穩定性。目前，化合物 DTPRBDT-b8 (11) 和 DTPRIDT-b8 (12) 的溶液放光約在 850 nm，而在 650 nm 波長的固態放射激發，可達到 1100 nm 的近紅外光區，DTPRBDT-b8 (11) 在甲苯溶劑中之量子產率為 7.6%，DTPRIDT-b8 (12) 在環己烷溶劑中之量子產率為 8.4%，其餘材料之 OTFTs 和 OPVs 元件性質仍在待測中。 zh_TW dc.description.abstract A series of new organic optoelectronic materials were synthesized and characterized for organic thin film transistors (OTFTs), organic photovoltaic cells (OPVs) and organic light emitting diodes (OLEDs). Thiophenyl, phenyl, and fused thiophene units were served as a central cores and were end-capped with electron withdrawing groups, such as thienopyrrole with β- substituted alkyl side chains or rhodanine. Via Stille coupling, thirteen new materials, DTPRT (1), DTPRbT (2), DTPRT-b8 (3), DTPRP-b8 (4), DTPRTT-b8 (5), DTPRbT-b8 (6), DTPRDTT-b8 (7), DTPR3T-b8 (8), DTPRffBT-b8 (9), DTPRSF-b8 (10), DTPRBDT-b8 (11), DTPRIDT-b8 (12) and DTPRIDTT-b8 (13) were prepared. The optical and electrochemical properties (HOMO and LUMO) of these materials were characterized by UV-vis and DPV. Thermal properties were investigated by TGA. Currently, the emission spectra of DTPRBDT-b8 (11) and DTPRIDT-b8 (12) in solution exhibit peak at about 850 nm. In particular, the emission spectra of these two molecules in solid-state could reach 1100 nm near-infrared region, excited at 650 nm. The quantum yield of DTPRBDT-b8 (11) in toluene and DTPRIDT-b8 (12) in cyclohexane are 7.6% and 8.4%, respectively. These newly developed materials OTFTs, OPVs or OLEDs device studies are under progress. en_US DC.subject 有機光電材料 zh_TW DC.subject 有機薄膜電晶體 zh_TW DC.subject 有機太陽能電池 zh_TW DC.subject 有機發光二極體 zh_TW DC.subject 近紅外光 zh_TW DC.subject Optoelectronic en_US DC.subject OTFT en_US DC.subject OPV en_US DC.subject OLED en_US DC.subject near IR en_US DC.title 可溶性噻吩並吡咯酮衍生物有機光電材料之開發 zh_TW dc.language.iso zh-TW zh-TW DC.title Development of Soluble Thienopyrroledione(TP) Derivatives for Organic Optoelectronic Applications en_US DC.type 博碩士論文 zh_TW DC.type thesis en_US DC.publisher National Central University en_US