| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 詹詠翔 | zh_TW |
| DC.creator | Yung-Hsiang Chan | en_US |
| dc.date.accessioned | 2017-8-23T07:39:07Z | |
| dc.date.available | 2017-8-23T07:39:07Z | |
| dc.date.issued | 2017 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=104223055 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 我們成功以鈀金屬催化含氮炔類化合物進行分子內合環形成環戊
烷取代吡咯衍生物，且使用微波反應器輔助可以有效提升產率，最高可
達92%。此方法可應用於合成藥物Ramipril 中的重要結構。 | zh_TW |
| dc.description.abstract | Hydroamination of N-(2-ethynylcyclopentyl)sulfonamide to
give non-aromatic 2,3-dihydropyrroles was achieved by using
PdCl2 as the catalyst. With microwave-assisted heating, up to 92%
isolated yield was obtained from this intramolecular 5-endodig
cyclization. The cyclopentane-fused 2,3-dihydropyrroles were
transformed into the corresponding N-tosyl-pyrrolidine-2-
carboxylic acids. | en_US |
| DC.subject | 鈀金屬催化含氮炔類的合環反應之探討 | zh_TW |
| DC.title | 鈀金屬催化含氮炔類的合環反應之探討 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Palladium catalyzed intramolecular cyclization of N-(2-ethynylcyclopentyl)sulfonamide | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |