博碩士論文 88321031 完整後設資料紀錄

DC 欄位 語言
DC.contributor化學工程與材料工程學系zh_TW
DC.creator鄭仲宏zh_TW
DC.creatorJuen-Hung Jengen_US
dc.date.accessioned2001-6-26T07:39:07Z
dc.date.available2001-6-26T07:39:07Z
dc.date.issued2001
dc.identifier.urihttp://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN= 88321031
dc.contributor.department化學工程與材料工程學系zh_TW
DC.description國立中央大學zh_TW
DC.descriptionNational Central Universityen_US
dc.description.abstract2-甲基zh_TW
dc.description.abstractAlkyl halides undergo nucleophilic substitution with heterocylic compounds such as 2-methylquinoline and 4-methylquinoline, and form the stabile quaternary ammonium salt. Because of strong withdrawal electrons effects at the nitrogen atom on quaternary ammonium salt, the methyl group out of aromatic ring becomes an active nucleophile, witch can react with aromatic aldehydes to form cyanine compounds. The blue dye “cyanine”was first prepared by Greville Williams in 1856, in which two heterocyclic nuclei containing nitrogen are linked through an odd numbered methane chain in such a way that resonance occurs through the conjugated system between tertiary and quaternary nitrogen atoms, that make the red shift of ultraviolet-visible spectra of the cyanine compounds. The study takes 2-methylpyridine to be the reactant and synthesizes cyanine compounds with aromatic aldehydes. By changing the number of methane chain, we hope to synthesize the compounds which have the maximum absorbance of ultraviolet-visible spectra more than 600nm, and study on the property of ultraviolet-visible and infrared spectra.en_US
DC.subject縮合反應zh_TW
DC.subject芳香醛zh_TW
DC.subject花青染料zh_TW
DC.subject2-甲基zh_TW
DC.subject塞安寧zh_TW
DC.subjectaromatic aldehydesen_US
DC.subject2-methylpyridineen_US
DC.subjectcyaninen_US
DC.title 2-甲基zh_TW
dc.language.isozh-TWzh-TW
DC.title Study on the synthesis of 2-methylpyridine cyanice compoundsen_US
DC.type博碩士論文zh_TW
DC.typethesisen_US
DC.publisherNational Central Universityen_US

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