| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學工程與材料工程學系 | zh_TW |
| DC.creator | 黃柏輔 | zh_TW |
| DC.creator | Bo-Fu Hwang | en_US |
| dc.date.accessioned | 2003-7-10T07:39:07Z | |
| dc.date.available | 2003-7-10T07:39:07Z | |
| dc.date.issued | 2003 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=90324048 | |
| dc.contributor.department | 化學工程與材料工程學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 論文中實驗分為兩部份：第一部份是以氯化鋁（AlCl3）、硫酸鋁
[Al2(SO4)3．18H2O]、明礬（Al2(SO4)3．K2SO4．24H2O）等含鋁金屬化
合物與8-羥基(8-hydroxyquinoline)合成tris(quinoline-8-hydroxyl-
ate)-aluminium(以下簡稱AlQ3)。視其相對於氯化鋁之替代性。又由於
原料成本相差數倍，亦是主要比較之因素。
第二部分：由文獻中（1）得知一Al(OR)3 類化合物之合成，方法如
下：先以2-胺基苯酚(2-aminophenol)與水楊醛(salicylaldehyde)在乙醇溶
液中行脫水反應，再將獲得產物與氯化鋁(aluminium chloride)、8-羥基
(8-hydroxyquinoline)在乙醇溶液中反應，形成一個高熱穩定性且具
螢光性質之螯化物。再以此化合物為基礎架構加以延伸，合成其它種
化合物以紅外光吸收光譜圖、熔點測定等結果判別反應之完成
度，觀察可見光範圍最大吸收波長、及其螢光性質之變化，並與AlQ3
準品比較其中差異。 | zh_TW |
| dc.description.abstract | The first part：we used AlCl3、[Al2(SO4)3．18H2O]、[Al2(SO4)3
．K2SO4．24H2O] to synthesize AlQ3, and compared the effect.Otherwise,
the price of row materials was a factor of compared.
The second part：From a literature（1）, we found a method about
synthesized a new complex which the chemistry was like AlQ3.
The method was as follows: 2-amino-phenol and salicylaldehyde dehydrated
in EtOH(aq).Then the synthesis reacted with AlCl3 and 8-hydroxyquinoline
to synthesize a material,(salicylidene-2-aminophenolato)-(
8-quindinoato)aluminium (Al(Saph-q)), which has good thermal
stability and stable light-emitting. (Al(Saph-q)) was a basis and synthesized
other compounds similarly.
The figure of FT-IR and melt point analysed used to think the
extent of synthesized. Observed the change of UVλmax and light-
emitting properties.Then compared with standard AlQ3. | en_US |
| DC.subject | 發光二極體材料 | zh_TW |
| DC.subject | OLED | en_US |
| DC.title | AlQ3及Al(OR)3類化合物之合成與性質之分析 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |