| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 王世忠 | zh_TW |
| DC.creator | Shih-Chung Wang | en_US |
| dc.date.accessioned | 2006-1-12T07:39:07Z | |
| dc.date.available | 2006-1-12T07:39:07Z | |
| dc.date.issued | 2006 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=92223017 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 本論文是以合成cycloiptycene分子1為目標，並希望利用化合物1的羥基形成分子間氫鍵來進行分子自我組裝，以形成有機奈米管。
我們設計出四種合成cycloiptycene分子1前驅物化合物4a的可能方法。方法一易產生其他異構物且純化的難度較高。方法二根據文獻必須在封管下反應方能進行，執行上較不易。所以本論文試圖以方法三及方法四合成化合物4a
方法三以化合物6與化合物12為起始物進行反應，我們成功的合成出化合物22a，但化合物22a與正丁基鋰及呋喃反應時沒有產生預期之化合物23a。可能原因是正丁基鋰與化合物22a上的酮基進行加成反應。
方法四以化合物6與化合物14為起始物進行反應，成功的合成出化合物29a，化合物29a與甲苯、過氯酸及乙醇反應後沒產生預期的化合物4a。 | zh_TW |
| dc.description.abstract | In this thesis, we take advantage of compound 1 to design organic nanotube. We would like to use the intermolecular hydrogen bonding to treat molecular self-assembled. Target compounds were prepared based on the Deils-Alder reaction.
We have designed four kinds of strategy for synthesizing compound 4a. Method Ⅰis more difficult purification and easily produces isomers. Method Ⅱ must be in hard condition. So we use method Ⅲ and Ⅳ to synthesize compound 4a.
We synthesize the compound 22a successfully in method Ⅲ. But we don’t get compound 23a by compound 22a reacting with n-butyl lithium and furan.
We synthesize the compound 29a successfully in method Ⅳ. But we don’t get compound 4a by compound 29a reacting with perchloric acid, toluene and ethanol. | en_US |
| DC.subject | 分子自組裝行為 | zh_TW |
| DC.subject | self-assemble | en_US |
| DC.subject | Cycloiptycene | en_US |
| DC.title | Cycloiptycene分子之合成與自組裝行為之研究 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Studies on the cycloiptycene synthes is and self-assemble behavior | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |