| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 謝易達 | zh_TW |
| DC.creator | Yih-Dar Hsieh | en_US |
| dc.date.accessioned | 2005-7-22T07:39:07Z | |
| dc.date.available | 2005-7-22T07:39:07Z | |
| dc.date.issued | 2005 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=92223048 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 中 文 摘 要
氮取代之異吲哚啉可在鈀金屬催化下還原氫化為四氫異吲哚，並且有不錯的產率。藉由氫之同位素標定來探究其反應機制，同時也發現有氫/氘交換的反應產生，並且驗證芳香性在此反應中是必要的。吲哚啉也可在鈀金屬催化下轉換為吲哚。 | zh_TW |
| dc.description.abstract | Abstract
The high-yield syntheses of 4,5,6,7-tetrahydro-isoindoles from N-substituted isoindolines under palladium catalyzed hydrogenation conditions are reported. Mechanistic study with deuterated and saturated substrates shows extensive H/D exchange and the essence of aromaticity in this transformation. Indolines can also transform to indoles under palladium catalyzed hydrogenation conditions. | en_US |
| DC.subject | 4，5，6，7-四氫異吲哚 | zh_TW |
| DC.subject | 4，5，6， 7-tetrahydroisoindoles | en_US |
| DC.title | 藉由芳香環轉換來合成4,5,6,7-四氫異吲哚 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Forming 4,5,6,7-tetrahydroisoindoles through aromaticity | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |