| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 文雅如 | zh_TW |
| DC.creator | Ya-Ju Wen | en_US |
| dc.date.accessioned | 2007-7-19T07:39:07Z | |
| dc.date.available | 2007-7-19T07:39:07Z | |
| dc.date.issued | 2007 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=93223047 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 本論文設計合成一系列以笏(fluorene)衍生物做為主體的有機發
光二極體材料，利用在9,9¢-位置接上苯環成咔哚(cardo)或9,9¢-位置接
上另一笏取代，形成螺旋雙笏(spirobifluorene)結構，且藉由中心元素
9 位置碳、矽元素的不同，了解結構上碳和矽元素的差異對光電特性
的影響，並以熱重量分析儀(TGA)及微差熱掃描卡計(DSC)量測化合
物熱性質；紫外/可見光光譜儀、螢光光譜儀、光電子光譜儀、積分
球了解化合物的光物理性質。最後，其中碳、矽兩組的四個化合物做
成元件，探討其元件效率及亮度等電激發光性質。 | zh_TW |
| dc.description.abstract | The present thesis designed and synthesized a series of
fluorene-based materials for organic light-emitting diodes (OLEDs).
Particulaly, 9,9-diphenyl-substituted fluorene (cardo),
9,9-spirobifluorene, and their silicon derivatives (silacardo and
spirosilabifluorene) bearing electronic donor-acceptor substituent on 2
and 7 position are characterized for photoelectronic characteristics. The
influence of the difference from the central carbon and silicon elements
were investigated by thermogravimetric analyzer, differential scanning
calorimeter, UV/Visible spectrophotometer, fluorescence
spectrophotometer, photoelectron spectrometer, integrating-sphere for
solid-state fluorescence quantum yield, and OLEDs. | en_US |
| DC.subject | 咔哚 | zh_TW |
| DC.subject | 有機發光二極體材料 | zh_TW |
| DC.subject | 螺旋雙笏 | zh_TW |
| DC.subject | cardo | en_US |
| DC.subject | OLEDs | en_US |
| DC.subject | spirobifluorene | en_US |
| DC.subject | silacardo | en_US |
| DC.subject | spirosilabifluorene | en_US |
| DC.title | 矽咔哚與矽螺旋雙笏物質之放光性質研究 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Synthesis and Luminescence Studies of Silicon Cardo and Spirosilabifluorene Derivatives | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |