| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 陳祖丘 | zh_TW |
| DC.creator | Zu-Ciou Chen | en_US |
| dc.date.accessioned | 2010-7-22T07:39:07Z | |
| dc.date.available | 2010-7-22T07:39:07Z | |
| dc.date.issued | 2010 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=972203036 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 利用具溶解度之三併環噻吩分別與二併環、三併環、四併環噻吩和其本身進行聚合反應，開發出 Polymer (1) ~ (4) 四種有機高分子半導體材料，期能藉由高共振系統的架構，得到較好的分子排列情形，提升元件之載子移動率。其中 Polymer (3) 利用溶液製程所得之載子移動率最高可達 7.2 x 10-4 cm2/Vs。
此外亦開發出外掛兩硫醚烷基之聯噻吩，以此為單體分別與二併環、三併環和四併環噻吩進行聚合，製備出 Polymer (5) ~ (7)。其中 Polymer (5) 以溶液製程所得之載子移動率最高可達 1.2 x 10-2 cm2/Vs 為本研究中所開發之電性表現最佳之高分子。而 Polymer (6)正進行電性之量測，期望能有不錯的電性表現。
| zh_TW |
| dc.description.abstract | Three polymers (1) ~ (3) based on a well-soluble DTT unit were synthesized. In addition, polymer (4) was prepared via oxidative polymerization. Via solution process, polymer (3) exhibited p-type field-effect performance with mobility of 7.2 x 10-4 cm2/Vs.
Furthermore, Polymer (5) ~ (7) based on a soluble bithiophene were developed via the Stille coupling. Via solution process, polymer (5) exhibited p-type field-effect performance with mobility of 1.2 x 10-2 cm2/Vs.
| en_US |
| DC.subject | 併環噻吩 | zh_TW |
| DC.subject | 載子移動率 | zh_TW |
| DC.subject | 有機薄膜電晶體 | zh_TW |
| DC.subject | 導電高分子材料 | zh_TW |
| DC.subject | Conducting polymer | en_US |
| DC.subject | OTFT | en_US |
| DC.subject | Fused-thiophene | en_US |
| DC.subject | mobility | en_US |
| DC.title | 有機薄膜電晶體高分子材料併環噻吩系列之開發 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |