量子點窄帶濾光片

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：8

、訪客IP：3.233.215.231

姓名

楊昀融( Yun-Rong Yang) 查詢紙本館藏

畢業系所

光電科學與工程學系

論文名稱

量子點窄帶濾光片
(Narrow band pass filter with the spacer including quantum dots)

相關論文

★ 半導體雷射控制頻率	★ 比較全反射受挫法與反射式干涉光譜法在生物感測上之應用
★ 193nm深紫外光學薄膜之研究	★ 超晶格結構之硬膜研究
★ 交錯傾斜微結構薄膜在深紫外光區之研究	★ 膜堆光學導納量測儀
★ 紅外光學薄膜之研究	★ 成對表面電漿波生物感知器應用在去氧核糖核酸及微型核糖核酸雜交反應檢測
★ 成對表面電漿波生物感測器之研究及其在生醫上的應用	★ 探討硫化鎘緩衝層之離子擴散處理對CIGS薄膜元件效率影響
★ 以反應性射頻磁控濺鍍搭配HMDSO電漿聚合鍍製氧化矽摻碳薄膜阻障層之研究	★ 掃描式白光干涉儀應用在量測薄膜之光學常數
★ 以量測反射係術探測光學薄膜之特性	★ 嵌入式繼光鏡顯微超頻譜影像系統應用在口腔癌切片及活體之設計及研究
★ 軟性電子阻水氣膜之有機層組成研究	★ 聚光型太陽能電池模組接收器之二次光學元件設計與分析

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

至系統瀏覽論文 ( 永不開放)

摘要(中)

本論文主要分為兩個部分，第一部分是以化學水浴法鍍製硫化鎘量子點薄膜，我們以製程時間3分鐘以及氨水濃度1.2 M等參數，分別進行膜層內量子點大小分佈及薄膜結晶性的優化，再以後退火參數300°C─30分鐘處理，最後可以得到晶相單純及粒徑約2.5 nm的CdS量子點。第二部分是量子點窄帶濾光片的鍍製，我們以旋轉塗佈法及離子束濺鍍法成功鍍出pair number = 3、4、5的量子點窄帶濾光片，同時也量測到窄帶濾光片在雷射功率為11.2 mW激發下，中心波長穿透率因為量子點的增益分別提升為152.2 %、418.3 %及534.0 %。最後我們以本研究所寫的模擬程式，擬合在不同雷射功率下每一片窄帶濾光片中心波長之穿透率，並進一步算出spacer的等效消光係數k。

摘要(英)

The thesis is consisted of two parts, the first part is about fabrication of CdS quantum dots by chemical bath deposition (CBD), in which we improve the size distribution of quantum dots, QDs, uniformity of crystalline phase. The optimized parameters are 3 minutes process time, 1.2 M ammonia, and 300?C post-annealing with 30 minutes which results in the quantum dots of 2.5 nm with high performance of crystallization. The second part is about the fabrication of narrow band pass filter, NBPF, with spacers including quantum dots. We successfully fabricate QDs-NBPF with the 3, 4, 5 pair number by Ion-Beam Sputtering Deposition and spin coating. And then with the 325 nm He-Cd laser pumping, the transmission of QDs-NBPF with 3 pairs, 4 pairs and 5 pairs at the center wavelength are 152.2 %, 418.3 % and 534.0 %, respectively. Finally we calculate the equivalent extinction coefficient k of the spacer of the QDs-NBPF by fitting the transmission intensity on the center wavelength.

關鍵字(中)

★ 量子點
★ 窄帶濾光片
★ 硫化鎘

關鍵字(英)

論文目次

目錄
第一章緒論 1
1.1 研究背景 1
1.2 研究動機 3
1.3 本文架構 4
第二章基礎理論 5
2.1 量子點 5
2.2 薄膜理論 10
2.2.1 垂直入射之光學導納定義 10
2.2.2 等效導納與膜矩陣 13
2.2.3 單介面之反射與透射 16
2.2.4 窄帶濾光片穿透率之計算 17
第三章量子點─窄帶濾光片模擬與設計 21
3.1 Matlab模擬方法與其他模擬軟體之比較 21
3.2 Matlab模擬結果 33
第四章實驗與設備 37
4.1 化學水浴法鍍製量子點薄膜 37
4.1.1 化學水浴沉積法介紹 37
4.1.2硫化鎘成核機制 38
4.1.3實驗設備與參數介紹 39
4.1.4後退火製程 41
4.2 旋轉塗佈法鍍製量子點薄膜 42
4.3 鍍製窄帶濾光片 43
4.3.1實驗設備與參數介紹 43
4.3.2 多層膜監控方法 45

第五章量測方法及架構 47
5.1.1 光激發螢光原理 47
5.1.2 螢光光譜量測儀器架構 49
5.2 量子點窄帶濾光片之量測 50
5.2.1 量測儀器架構 50
5.2.2 量測步驟 51
第六章量測結果與分析 52
6.1 化學水浴法─CdS量子點薄膜 53
6.2 旋轉塗佈量子點薄膜 63
6.3 克服spacer脫膜的參數測試 65
6.4 量子點─窄帶濾光片 66
第七章結論與未來工作 78
參考文獻 80

參考文獻

1.S. C. Sullivan, W. Liu, P. Allen, and J. S. Steckel, “Quantum Dots for LED Downconversion in Display Applications”, ECS Journal of Solid State Science and Technology, 2, R3026-R3030 (2013).

2.S. Park, E. Cho, D. Song, G. Conibeer, M. A. Green, “n-Type silicon quantum dots and p-type crystalline silicon heteroface solar cells”, Solar Energy Materials & Solar Cells, 93, 684–690, (2009).

3.S.M. Reda, “Synthesis and optical properties of CdS quantum dots embedded in silica matrix thin films and their applications as luminescent solar concentrator”, Acta Materialia, 56, 259–264, (2008).

4.M. B. Jr., M. Moronne, P. Gin, S. Weiss, and A. P. Alivisatos, “Semiconductor Nanocrystals as Fluorescent Biological Labels”, Science,281,2013~2015,(1998).

5.楊智惠、黃耿迷、王英基、林裕城，"量子點-奈米彩虹標籤"，科學發展，422，46-49，(2008).

6.S. A. Vanalakar, S. S. Mali, M. P. Supryavanshi, P. S. Patil, “Quantum size Effect in Chemosynthesized Nanostructured CdS Thin Films”, Digest Journal of Biostructure, 5, 805-810, (2010).

7.W. W. Yu and X. Peng, “Formation of High-Quality CdS and Other II─VI Semiconductor Nanocrystals in Noncoordinating Solvents：Tunable Reactivity of Monomer”, Angewandte Chemie International Edition, 41, 2368, (2002).

8.M. Thambidurai, N. Muthukumarasamy, N. Murugan, Dhayalan Velauthapillai, S. Agilan, R. Balasundaraprabhu, “A mathematical model to predict the grain size of nanocrystalline CdS thin films based on the deposition condition used in the sol–gel spin coating method ”, Applied Physics A, 104, 1129–1136, (2011).

9.X. W. He, W. F. Liu, C. F. Zhu, G. S. Jiang,” CdS Thin Films Deposited by CBD Method on Glass”, Chinese Journal of Chemical Physics, 24,471, (2011).

10.S. W. Jung, J. H. Kim, H. Kim, C. J. Choi, and K. S. Ahn, “CdS quantum dots grown by in situ chemical bath deposition for quantum dot-sensitized solar cells”, Journal of Applied Physics, 110, 044313 (2011).

11.P.M. Petroff, S.P. DenBaars, “MBE and MOCVD growth and properties of self-assembling quantum dot arrays in III-V semiconductor structures”, Superlattices and Microstructures, 15, 15, (1994).

12.J. A. Adams, J. N. Wang, P. H. Beton, M. Henini, “Quantum Dot Fabrication by Optical Lithography and Selective Etching”, NATO ASI Series, 239, 191-197, (1993).

13.J. Schmid, J. Weis, K. Eberl, K. Klitzing, “A quantum dot in the limit of strong coupling to reservoirs”, Physica B, 256-258, 182-185, (1998).

14.李正中，"薄膜光學與鍍膜技術"，第六版，藝軒圖書出版社，(2009).

15.H. A. Macleod, “Thin-Film Optical Filters”, Fourth Edition, CRC Press,(2010).

16.Y.J. Chang, C. L. Munsee, G. S. Herman, J. F. Wager, P. Mugdur, D.H. Lee, and C.H. Chang, “Growth, characterization and application of CdS thin films deposited by chemical bath deposition”, Surface and Interface Analysis, 37: 398–405, (2005).

17.H. Khallaf, I. O. Oladeji, G. Chai, L. Chow, “Character -ization of CdS thin films grown by chemical bath deposition”, Thin Solid Films, 516, 7306–7312, (2008).

18.Y.J. Chang, C. L. Munsee, G. S. Herman, J. F. Wager, P. Mugdur, D.H. Lee, and C.H. Chang, “Growth, characterization and application of CdS thin films deposited by chemical bath deposition”, Surface and Interface Analysis, 37, 398–405, (2005).

19.張振昌，"化學水浴沉積法成長硫化鎘薄膜之研究"，國立中山大學碩士論文，(2006).

20.H. Metin and R. Esen, “Annealing effects on optical and crystallographic properties of CBD grown CdS films”, Semiconductor Science Technology, 18, 647–654, (2003).

21.H. Metin and R. Esen,” Annealing studies on CBD grown CdS thin films”, Journal of Crystal Growth, 258, 141–148, (2003).

22.C. Cheng, H. Yan, “Bandgap of the core–shell CdSe/ZnS nanocrystal within the temperature range 300–373 K”, Physica E, 41, 828–832, (2009).

23.林子翔，"旋轉塗佈硫化鎘薄膜與回火條件對薄膜影響之探討"，國立成功大學碩士論文，(2007).

24.謝嘉民、賴一帆、林永昌、枋志堯，"光激發螢光量測原理、架構及應用"，奈米通訊，12，28~39，(2005).

25.S. Kumar, P. Sharma, and V. Sharma, ”CdS nanofilms: Synthesis and the role of annealing on structural and optical properties”, Journal Applied Physics, 111, 043519, (2012).

26.C. T. Tsai, D. S. Chuu, G. L. Chen, and S. L. Yang, “Studies of grain size effects in rf sputtered CdS thin films”, Journal Applied Physics, 79, 9105, (1996).

27.楊謹聰，"以貼靶濺鍍法製備含GaN 量子點之?Si?_3 N_4及?SiO?_x N_y奈米複合薄膜之光學性質研究"，國立交通大學碩士論文，(2008).

28.彭羽筠，"以貼靶濺鍍法製備含ZnO 量子點之?Si?_3 N_4及?SiO?_x N_y奈米複合薄膜之光學性質研究"，國立交通大學碩士論文，(2008).

指導教授

李正中

審核日期

2014-1-14

推文