用奈米壓印方式複製Papilo blumei蝴蝶 表面的疏水性質

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：9

、訪客IP：35.172.111.71

姓名

朱曉彤( Hsiao-tung Chu) 查詢紙本館藏

畢業系所

照明與顯示科技研究所

論文名稱

用奈米壓印方式複製Papilo blumei蝴蝶表面的疏水性質
(Mimic hydrophobic surface of Papilo blumei butterfly by nanoimprint)

相關論文

★ 電激發有機雷射微共振腔研究	★ 半導體雷射控制頻率
★ 比較全反射受挫法與反射式干涉光譜法在生物感測上之應用	★ 193nm深紫外光學薄膜之研究
★ 超晶格結構之硬膜研究	★ 交錯傾斜微結構薄膜在深紫外光區之研究
★ 膜堆光學導納量測儀	★ 紅外光學薄膜之研究
★ 成對表面電漿波生物感知器應用在去氧核糖核酸及微型核糖核酸雜交反應檢測	★ 成對表面電漿波生物感測器之研究及其在生醫上的應用
★ 探討硫化鎘緩衝層之離子擴散處理對CIGS薄膜元件效率影響	★ 以反應性射頻磁控濺鍍搭配HMDSO電漿聚合鍍製氧化矽摻碳薄膜阻障層之研究
★ 掃描式白光干涉儀應用在量測薄膜之光學常數	★ 量子點窄帶濾光片
★ 以量測反射係術探測光學薄膜之特性	★ 嵌入式繼光鏡顯微超頻譜影像系統應用在口腔癌切片及活體之設計及研究

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

至系統瀏覽論文 ( 永不開放)

摘要(中)

本論文主要探討自然界中Papilio blumei蝴蝶其翅膀上綠色部位之疏水性，造成疏水性的原因，是因為表面的孔洞由微米等級造成水滴不易與表面接觸，本文利用奈米壓印法複製蝴蝶表面凹洞，使薄膜也具有疏水性。
首先，利用聚二甲基矽氧烷(PDMS)複製蝴蝶表面凹洞，此時PDMS 是負結構；再來塗佈一層薄膜；最後是把負結構的PDMS壓印製薄膜上，使之為正結構。
而最後的薄膜壓印上結構後，接觸角從原本的75.03o增加至102.99o，亦即薄膜由屬於親水性轉變為疏水性。

摘要(英)

In this study, we studied the hydrophobic characteristic of Papilio blumei butterfly scale, especially in green part on the butterfly wing. The reason for hydrophobic characteristic of this butterfly wing is that the surface is composed of concaves with few micrometer which a drop of water can’t contact the surface easily. Nanoimprint technology has been applied to reproduce the surface structure (concaves) of butterfly wing so that the thin film is hydrophobic.
The first step in the process, we use PDMS to mimic the surface of butterfly wing (concaves). The PDMS is a negative structure. In the second step, we make the thin film by spin coating. The last step is that use PDMS to imprint a thin film, let the thin film is with positive structure.
Owing to the surface of thin film with concave structure, contact angle of structure-thin film is increased from 75.03o to 102.99o.

關鍵字(中)

★ 蝴蝶
★ 奈米壓印
★ 疏水性

關鍵字(英)

論文目次

第一章緒論 1
1-1前言 1
1-2 蝴蝶介紹 3
1-3文獻回顧 6
1-3-1 仿生文獻回顧 6
1-3-2奈米壓印文獻回顧 8
1-4研究目的 11
1-5 論文架構 12
第二章理論與技術 13
2-1奈米壓印技術 13
2-1-1熱奈米壓印(Thermal Nanoimprint Lithoraphy,T-NIL) 13
2-1-2 紫外光固化奈米壓印技術(UV-Cured Nanoimprint Lithography) 15
2-1-3溶劑蒸氣輔助式奈米壓印(Solvent-Vapor-Assisted Nanoimprint Lithography,SANIL) 16
2-2 親疏水性質 17
2-2-1 親疏水性簡介 17
2-2-2 影響接觸角的變因 18
2-2-3 接觸角的氣液固三相系統 18
第三章儀器介紹 23
3-1 光學顯微鏡 23
3-2掃描式電子顯微鏡 25
3-3原子力顯微鏡 26
3-4奈米壓印機 29
3-5膜厚測量儀 30
第四章量測結果 31
4-1蝴蝶外觀 31
4-2 蝴蝶凹洞剖面圖 32
第五章實驗流程 34
5-1 實驗目的 34
5-2實驗流程 35
5-3 材料介紹 37
5-3-1聚二甲基矽氧烷(polydimethyl siloxane) 37
5-3-2 Spin Coating材料 40
5-4 壓印參數 42
第六章結果與分析 45
6-1 壓印結果分析 45
6-1-1 光學顯微鏡觀察表面 45
6-1-2 原子力顯微鏡量測深度 46
6-2 接觸角分析 47
第七章結果與未來工作 50
參考文獻 52

參考文獻

[1] Pete Vukusic and J. Roy Sambles , Photonic structures in biology, Nature , Volume 424, pp.852-855, 2003.
[2] W. Barthlott, C. Neinhuis , Purity of the sacred lotus, or escape from contamination in biological surfaces, Planta, Volume 202, pp.1-8,1997.
[3] http://butterflywebsite.com/faq.cfm#q14
[4] Kertesz K, Balint Z, Vertesy Z, Mark GI, Lousse V, Vigneron JP, Rassart M, Biro LP. , Gleaming and dull surface textures from photonic-crystal-type nanostructures in the butterfly Cyanophrys remus , Physical Review E, Volume 74, pp. 021922-1~15, 2006.
[5] Darrell J. Kemp , Female mating biases for bright ultraviolet iridescence in the butterfly Eurema hecabe(Pieridae), Behavioral Ecology , Volume 19, pp. 1-8, 2007.
[6] Martin Olofsson, Adrian Vallin, Sven Jakobsson, Christer Wiklund , Adrian Vallin , Sven Jakobsson , Christer Wiklund , Marginal Eyespots on butterfly wings deflect bird attacks under low light intensities with UV wavelengths, PLoS ONE, Volume 5, pp.1-6, 2010.
[7] Stephen Y. Chou, Peter R. Krauss and Preston J. Renstrom, Imprint of sub-25 nm vias and trenches in polymers, Applied Physics Letters, Volume 67, pp.3114-3116, 1995.
[8] M. Bender, M. Otto, B. Hadam, B. Vratzov, B. Spangenberg, H. Kurz, Fabrication of nanostructures using a UV-based imprint technique, Microelectronic Engineering, Volume 53, pp.233–236, 2000.
[9] Nicoleta E. Voicu, Sabine Ludwigs, Edward J. W. Crossland,Piers Andrew, and Ullrich Steiner, Solvent-Vapor-Assisted Imprint Lithography, Advanced Materials, Volume 19, pp.757–761, 2007.
[10] Nathan I Morehouse, Peter Vukusic, and Ron Rutowski, Pterin pigment granules are responsible for both broadband light scattering and wavelength selective absorption in the wing scales of pierid butterflies, Proceedings of the Royal Society, Volume 274, pp.359-366, 2007.
[11] Akira Saito, Shinya Yoshioka d, Shuichi Kinoshita, Reproduction of the Morpho butterfly's blue: arbitration of contradicting factors, Proceedings of SPIE, Volume 5526, pp.188-194, 2004.
[12] Mathias Kolle, Pedro M. Salgard-Cunha, Maik R. J. Scherer, Fumin Huang, Pete Vukusic,Sumeet Mahajan, Jeremy J. Baumberg and Ullrich Steiner, Mimicking the colourful wing scale structure of the Papilio blumei butterfly, Nature Nanotechnology, Volume 5, pp.511–515, 2010.
[13] Guoming Zhang, Jin Zhang, Guoyong Xie, Zhongfan Liu, and Huibo Shao, Cicada Wings : A Stamp from Nature for Nanoimprint Lithography, small, Volume 2, pp.1440 – 1443, 2006.
[14] Ding Y, Xu S, Zhang Y, Wang AC, Wang MH, Xiu Y, Wong CP and Wang ZL., Modifying the anti-wetting property of butterfly wings and water strider legs by atomic layer deposition coating: surface materials versus geometry, Nanotechnology,Volume 3, pp.1-7, 2008.
[15] S. Herminghaus, Roughness-induced non-wetting, Europhysics Letters, Volume 52 , pp.165–170, 2000.
[16] J. Bico, C. Marzolin and D. Quere , Pearl drops, Europhysics Letters., Volume 47, pp.220-226, 1999.
[17] N. K. ADAM, Use of the Term ‘Young's Equation’ for Contact Angles, Nature, Volume180, pp.809 – 810, 1957.
[18] Tamar Saison a, Christophe Peroz a, Vanessa Chauveaua, Serge Berthierb, Elin Sondergarda, and Herve Arribarta, Replication of butterfly wing and natural lotus leaf nanostructures by nanoimprint on Silica Sol-gel films, Bioinspiration and Biomimetics , Volume 3, pp.1-5, 2008.

指導教授

李正中(Cheng-Chung Lee)

審核日期

2014-1-27

推文