基於D形光纖之拉曼感測器製作與量測

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：19

、訪客IP：18.190.217.134

姓名

張緒國(Hsu-Kuo Chang) 查詢紙本館藏

畢業系所

光電科學與工程學系

論文名稱

基於D形光纖之拉曼感測器製作與量測
(The Fabrication and Characterization of D-fiber Based Raman Sensor)

相關論文

★ 以側磨光纖半塊材耦合器激發微米球型共振腔基模之研究	★ 以氬離子雷射對玻璃材料加工之研究
★ 以裸光纖激發球共振腔之共振譜研究	★ 錐狀平面波導光柵結構與微米小球共振腔之光耦合效率研究
★ 溶膠凝膠法合成以鉭元素為基礎的全固態電致變色元件	★ S型彎曲波導與微米小球共振腔之光耦合效率研究
★ 錐狀光纖與微米球共振腔耦合之研究與應用	★ 以鎖模鈦藍寶石飛秒雷射雙光子聚合製作光波導微結構之研究
★ 利用光子晶體的能隙邊緣移動達成全光開關之研究	★ 利用繞射圖形檢測錐狀光纖的製造與品質
★ 利用雙光子聚合技術製作高耦合效率波導陣列光纖耦合器	★ 光學印刷電路板之製作與特性分析
★ 鈉鉀離子交換波導之製作及其表面消逝波之研究	★ 拉伸式長週期光纖光柵的模態色散現象研究
★ 可調式窄頻液晶濾波器	★ 基於D形光纖之拉曼感測器模擬與設計

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

[檢視]

[下載]

本電子論文使用權限為同意立即開放。
已達開放權限電子全文僅授權使用者為學術研究之目的，進行個人非營利性質之檢索、閱讀、列印。
請遵守中華民國著作權法之相關規定，切勿任意重製、散佈、改作、轉貼、播送，以免觸法。

摘要(中)

本論文理論部分主要在探討側磨光纖之漸逝波的水平波向量與金屬銀膜在不同厚度下之表面電漿波的波向量是否能達到相位匹配，並利用加入光柵結構使漸逝波的水平波向量平移達到與表面電漿波的波向量更佳匹配之相位。
本研究實驗上利用研磨拋光技術與金屬薄膜濺鍍技術製作表面增強拉曼散射之側磨光纖基板。並利用自我組裝技術更進一步增強側磨光纖漸逝波與銀膜表面電漿波的耦合效率，因此可得到更佳的增強係數。在拉曼光譜實驗中可量測到明顯的拉曼訊號並可對應到R6G分子的振動光譜，證明此架構具有良好的分子辨識功能。

摘要(英)

Theoretically, we justify the degree of phase matching between the mode of D-fiber and that of surface plasmon wave at various clad thickness. By employing grating structure, the guide mode can be effectively coupled to the surface plasmon wave.
Experimentally, the D-fiber based surface Raman sensor was realized by side-polish of the fiber, self-assembly of microsphere grating and sputter the silver film. Sequentially, Rhodamine 6G was used as the prototype molecule and six vibrational bands was successfully identified.

關鍵字(中)

★ D形光纖
★ 拉曼感測器
★ 表面增強拉曼散射
★ 表面電漿共振
★ 增強係數

關鍵字(英)

★ D-fiber
★ Raman Sensor
★ Surface Enhanced Raman Scattering
★ Surface Plasmon Resonance
★ Enhancement factor

論文目次

中文摘要 ..................I
Abstract ..................II
致謝..................III
目錄..................i
圖目錄..................iii
表目錄..................vi
第一章緒論..................1
1.1 前言.................. 1
1.2研究背景..................3
1.3研究動機與目的..................7
1.4論文架構概述..................9
第二章研究方法..................10
2.1側磨光纖原理..................10
2.1.1光纖簡介..................10
2.1.2光纖基本原理..................11
2.1.3表面漸逝波基本原理..................12
2.1.4介入損失..................18
2.2金屬物質特性..................27
2.3表面電漿共振..................33
2.4.1表面電漿簡介..................33
2.4.2表面電漿共振原理..................35
2.4增強係數..................45
第三章樣品製作與實驗架構..................47
3.1實驗流程..................47
3.2側磨光纖製作..................48
3.3 銀膜濺鍍..................54
3.4 偏振損耗量測架構..................59
3.5拉曼訊號量測架構 ..................64
第四章實驗結果與討論..................66
4.1拉曼訊號量測結果..................66
4.2增強係數..................74
第五章結論及未來展望..................76
參考文獻..................77

參考文獻

1.C.V. Raman and K.S. Krishnan, "A new type of secondary radiation, Discovery of Raman effect," Nature 121, p.501, 1928.
2.D.W. Hahn, ’’Raman Scattering Theory, ’’ Department of Mechanical and Aerospace Engineering University of Florida, 2007.
3.M. Fleischman, P.J. Hendra, A.J. McQuillan, ’’ Raman spectra of pyridine adsorbed at a silver electrode, ’’ Chem.Phys. Lett. 26, p.163, 1974.
4.D. L. Jeanmaire, R. P. Van Duyne, ’’Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode, ’’ J. Electroanal. Chem. 84, p.1, 1977.
5.M. Moskovits, ’’Surface roughness and the enhanced intensity of Raman scattering by molecules adsorbed on metals, ’’ J. Chem. Phys. 69, p.4159, 1978.
6.J. Billmann, G. Kovacs, A. Otto, ’’ Enhanced Raman Effect from Cyanide Adsorbed on Silver Electrode, ’’ Surface Sci. 92, p.153, 1980.
7.P. Hildebrandt and M. Stockburger, ’’Surface-Enhanced Resonance Raman Spectroscopy of Rhodamine 6G Adsorbed on Colloidal Silver, ’’J. Phys. Chem.88, p.5935, 1984.
8.K. Kneipp, Y. Wang, H. Kneipp, L.T. Perelman, I. Itzkan, R.R. Dasari, and M.S. Feld, ’’Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS), ’’ Phys. Rev. Lett. 78, p.1667, 1997.
9.S. Nie, S. R. Emory, ’’Probing single molecules and single nanoparticles by surface-enhanced Raman scattering, ’’ Sci. 275, p.1102, 1997.
10.R.M. Stockle, Y.D. Suh, V. Deckert, R. Zenobi, ’’ Nanoscale chemical analysis by tip-enhanced Raman spectroscopy, ’’ Chem. Phys. Lett. 318, p.131, 2000.
11.A. Lucotti , G. Zerbi, " Fiber-optic SERS sensor with optimized geometry, " Sens. Actuators, B – Chem. 121, p.356, 2007.
12.H. Bai, Z. Chen, N. Chen, Q. Guo, K. Zhang, F. Pang, T. Wang, " A biconical taper multi-mode fiber SERS sensor, " SPIE 7990, p.799004, 2010.
13.Y. Zhang, C. Gu, A. M. Schwartzberg, and J. Z. Zhang, " Surface-enhanced Raman scattering sensor based on D-shaped fiber, " Appl. Phys. Lett. 87, p.123105, 2005.
14.C.R. Pollock, M. Lipson, ’’ Integrated Photonics,’’ Kluwer Academic Publishing, 2003.
15.Drude, Paul, ’’Zur Elektronentheorie der metalle, ’’ Annalen der Physik. 306, p.566, 1900.
16.M. A. Ordal, R. J. Bell, J. R. W. Alexader, L. L. Long, and M. R. Querry, ’’Optical properties of fourteen metals in the infrared and far infrared: Al, Co, Cu, Au, Fe, Pb, Mo, Ni, Pd, Pt, Ag, Ti, V, and W, ’’ Appl. Opt. 24, P.4493, 1985.
17.A.D. Rakic, A.B. Djurišic, J.M. Elazar, and M.L. Majewski, ’’Optical Properties of Metallic Films for Vertical-Cavity Optoelectronic Devices, Appl. Opt. 37, p. 5271, 1998.
18.M.D. Thoreson, Z. Liu, U. K. Chettiar, P. Nyga, A.V. Kildishev, V.P. Drachev, M.V. Pack and V.M. Shalaev, ’’ Studies on Metal-Dielectric Plasmonic Structures, ’’ Sandia Report printed, 2010.
19.P.B. Johnson and R.W. Christy , ’’Optical Constants of the Noble Metals, ’’ Phys. Rev. B 6, p.4370, 1972.
20.R.W. Wood, ’’On a remarkable case of uneven distribution of light in a diffraction grating spectrum, ’’ Phil. Mag. 4, p.396, 1902.
21.U. Fano, ’’The theory of anomalous diraction gratings and of quasistationary waves on metallic surfaces, ’’ J. Opt. Soc. Am. 31, p.213, 1941.
22.R. H. Ritchie, ’’ Plasma losses by fast electrons in thin films, ’’ Phys. Rev. 106, p.874, 1957.
23.C.J. Powell and J.B. Swan, “Effect of oxidation on the characteristics loss spectra of aluminum and magnesium,” Phys. Rev. 118, p.640, 1960.
24.A. Otto, ’’Excitation of nonradiative surface plasma waves in silver by method of frustrated total reection, ’’ Z. Phys. 216, p.398, 1968.
25.E. Kretschm and H. Raether, ’’Radiative decay of non radiative surface plasmons excited by light, ’’ Z. Naturf. 23A, p.2135, 1968.
26.K.H. Su, S. Durant, J.M. Steele, Y. Xiong, C. Sun, and X. Zhang, ’’ Raman Enhancement Factor of a Single Tunable Nanoplasmonic Resonator, ’’ J. Phys. Chem. B 110, p.3964, 2006.
27.E. C. Le Ru, E. Blackie, M. Meyer, and P.G. Etchegoin , ’’ Surface Enhanced Raman Scattering Enhancement Factors: A Comprehensive Study, ’’ J. Phys. Chem. C 111, p.13794, 2007.
28.S.A. Meyer, E.C. Le Ru, and P.G. Etchegoin, ’’Quantifying Resonant Raman Cross Sections with SERS, ’’ J. Phys. Chem. A 114, p.5515, 2010.
29.Y. Chen, J.J. Jaakola, A. Saynatjoki, A. Tervonen and S. Honkanen, ’’Glass-embedded silver nanoparticle patterns by masked ion-exchange process for surface-enhanced Raman scattering, ’’ J. Raman Spectrosc. 42, p.936, 2011.

指導教授

戴朝義(Chao-Yi Tai)

審核日期

2013-1-28

推文