不同製程對鋯基非晶質合金破裂韌性影響之研究

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：12

、訪客IP：18.218.169.50

姓名

張永憲(Yung-hsien Chang) 查詢紙本館藏

畢業系所

機械工程學系

論文名稱

不同製程對鋯基非晶質合金破裂韌性影響之研究
(Study of the cast process effect on the fracture toughness of Zr based bulk amorphous alloys)

相關論文

★ 鋯基與鋯銅基金屬玻璃薄膜應用於7075-T6航空用鋁合金疲勞性質提升之研究	★ 非晶質合金手術刀與非晶質合金鍍膜手術刀之銳利度研究
★ 以急冷旋鑄法及機械冶金法製備Zn4Sb3熱電塊材及其熱電性質之研究	★ 添加Ti顆粒對MgZnCa非晶質合金之機械性質研究
★ 硼碳元素對鐵基非晶質鋼材玻璃形成能力、熱性質及切削性質影響之研究	★ 鋯銅基塊狀金屬玻璃複材和鋯基塊狀金屬多孔材之製作及其性質分析之研究
★ 添加鉭顆粒與球狀鈦合金對鎂鋅鈣非晶質合金機械性質影響之研究	★ 高速火焰熔射製備鐵基非晶質合金塗層及其耐磨耗性與抗腐蝕性之研究
★ 不同製程對鋯-銅-鋁非晶質合金內析出ZrCu B2相分布及其機械性質影響之研究	★ 以塊狀金屬玻璃和其複材製作骨科鑽頭及其鑽孔能力之研究
★ 鋯基塊狀金屬玻璃與金屬玻璃鍍膜手術刀切削耐久度之研究	★ 利用急冷旋鑄及真空熱壓製備β-Zn4Sb3 奈米/微米晶塊材之熱電性質探討
★ 無鎳鋯基及鈦基金屬玻璃生物相容性之研究	★ 以鐵基金屬玻璃複材或金屬玻璃鍍膜製作手術用取皮刀並進行模擬切削性能之研究
★ 探討不同結晶率對鋯鋁鈷塊狀非晶質合金機械性質之影響	★ 鈦基非晶填料應用於Ti-6Al-4V合金硬焊之微結構及機械性能研究

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

至系統瀏覽論文 ( 永不開放)

摘要(中)

近幾年來，由於工業快速發展，使得材料的耐用度成為很重要一門課題，因而衍生出利用三點彎曲來測試評估材料對於裂縫抵抗能力，做為材料在結構設計上之依據。
由於鋯基非晶質合金具有良好的玻璃形成能力及抗壓縮機械性質，且因添加矽元素於鋯基非晶質合金系統中可提升玻璃形成能力與其熱穩定性，因此本研究選用無矽及含矽之鋯基非晶質合金作為主要基材，同時本研究藉由傾倒式鑄造(Tilt-casting)及墜落式鑄造(Suction-casting)製程來製作Zr53Cu30Ni9Al8、Zr48Cu36Al8Ag8、(Zr53Cu30Ni9Al8)99.25Si0.75與(Zr48Cu36Al8Ag8)99.25Si0.75等鋯基系列塊狀合金，並依據ASTM E399規範之三點彎曲測試，來探討該系列合金之破裂韌性。
以傾倒式鑄造製備之非晶質試片，其破裂韌性較墜落式鑄造製備的試片來的高，若以鋯基與添加矽之鋯基非晶質合金來看，鋯基(Zr53Cu30Ni9Al8)合金具有最佳破裂韌性，其值約120 MPa•√m，相對另一鋯基(Zr48Cu36Al8Ag8)合金其值則降為68 MPa•√m。另外添加Si元素之鋯基，非晶質合金其破裂韌性值均較未添加Si的非晶質合金來的低， (Zr53Cu30Ni9Al8)99.25Si0.75) 及((Zr48Cu36Al8Ag8)99.25Si0.75)非晶質合金之破裂韌性值分別為107 MPa•√m及34.4 MPa•√m；本研究同時也探討塊狀金屬玻璃之破裂能量(Rupture energy)與浦松比(Poissionʼs ratio)、剪切模數(Shear modulus)及對應溫度之關係。其中Zr53Cu30Ni9Al8具有較高破裂韌性(K1C)、破裂能量(J)、浦松比(ʋ，Poissionʼs ratio)、較低剪切模數(μ，Shear modulus)及彈性係數，其值分別為:120 MPa√m、155 kJm-2、0.373、30 GPa、83 GPa。

摘要(英)

In recent years, due to the rapid development of industry, the endurance of materials becomes a major issue on each kinds of industrial product. Therefore, the evaluation of crack resistance ability by three-point bending test is applied as the reference of structure design.
Zr-based bulk amorphous alloys (BAA) possess good engineering properties and its glass forming ability can be adjusted via minor-alloying of silicon element. Therefore, these two Zr53Cu30Ni9Al8 and Zr48Cu36Al8Ag8 Zr-based amorphous alloys are selected for this study. Both bulk amorphous alloys (BAA) plates were fabricated by tilt-casting and suction-casting. Then these bulk amorphous alloys (BAA) plates were followed ASTM E399 to machine into the three-point bending specimens for investigate their fracture toughness.
Experimental results revealed that tilt-casting (Zr53Cu30Ni9Al8) specimen possess the best fracture toughness among all specimens in this study and reaches value about 120 MPa√m. On the other hand, the calculate fracture energy and Poisson’s ratio show same trend to prove tilt-casting Zr-53 owns the best mechanical properties.

關鍵字(中)

★ 三點彎曲
★ 破裂韌性
★ 非晶質合金

關鍵字(英)

★ Three point bending
★ Fracture toughness
★ Amorphous alloy

論文目次

中文摘要I
英文摘要III
致謝IV
總目錄VI
表目錄IX
圖目錄X
第一章研究背景1
1-1前言1
1-2 研究動機2
第二章理論基礎3
2-1 非晶質合金概述3
2-2非晶質合金的發展歷程4
2-3 實驗歸納法則8
2-4 非晶質製造方法9
2-5 非晶質特性11
2-5-1 機械性質12
2-5-2 強度韌性13
2-5-3 耐腐蝕性13
2-6非晶質熱力學14
2-6-1非晶質平衡介穩態14
2-6-2 玻璃轉換溫度(Tg)16
2-6-3 玻璃形成能力指標(GFA)17
2-6-3-1 簡化玻璃溫度17
2-6-3-2 γ值及γm值17
2-7破裂韌性18
第三章實驗步驟27
3-1 實驗目的27
3-2 合金配置28
3-3合金熔煉28
3-3-1 電弧熔煉28
3-3-2 板材製作29
3-4 熱性質分析29
3-5 微觀組織分析30
3-5-1 X光繞射儀30
3-5-2 掃描式電子顯微鏡(SEM)30
3-6 機械性質測試31
3-6-1 破裂韌性量測(三點彎曲測試)31
3-6-2 非破壞性檢測(超音波測試)32
3-6-3硬度測試33
第四章結果與討論42
4-1 為結構分析42
4-1-1結晶結構分析42
4-2 熱性質分析43
4-3 機械性質分析45
4-3-1 微硬度分析45
4-3-2 缺陷分析(孔隙率)46
4-3-3 超音波測試(Ultrasonic testing)47
4-3-4 破裂韌性(KQ)48
4-3-5 破裂能量(J)49
4-4 SEM破斷面與Notch觀察50
4-4-1 開口(Notch)端剪切帶之觀察51
4-4-2 破斷面(cross section)之觀察52
第五章結論82
第六章參考文獻84

參考文獻

[1].A. Inoue, K. Ohtera and K. Kita, T. Masumoto, “New Amorphous Mg-Ce-Ni Alloy with High Strength and Good Ductility”, J. Appl.Phys., vol.27, 1998, p.2248.
[2].A. Inoue, “Bulk Amorphous Alloys”, Trans. Tech. Pub., Zurich,vol.2,1998, p.28.
[3].H. W. Kui, A. L. Greer and D. Turnbull, “Formation of Bulk Metallic-Glassy by Fluxing”, Appl. Phys. Letter,vol.45, 1984, p.615.
[4].A. Peker and W. L. Johnson, “A highly process able metallic glass:Zr41.2Ti13.8Cu12.5Ni10Be22.5 ”, Appl. Phys. Letter, vol.63, 1993, p.2342.
[5].A. Inoue, A. Kato, T. Zhang, S. G. Kim and T. Masumoto, “Mg-Cu-Y Amorphous Alloys with High Mechanical Strengths Produced by a Metallic Mold Casting Method”, Mater. Trans. JIM, vol.32, no.7,1991. P.609.
[6].A.Inoue, T. Nakamura, N. Nishiyama and T. Masumoto, “Mg-Cu-Y Bulk Amorphous Alloy with Tensile Strength Produced by a High-Pressure Die Casting Method”, Mater. Trans. JIM, vol.33, no .10, 1992, p.937.
[7].A. Kato, A. Inoue and H. Horikiri, “Production of Bulk Amorphous Mg85Y10Cu5 Alloy by Extrusion of Atomized Amorphous Powder”, Mater. Trans. JIM, vol.35, no.2, 1994,p.125.
[8].A. Inoue, “Stabilization of Metallic Super Cooled Liquid and Bulk amorphous Alloys ”, Acta Mater, vol.48, 2000, p.279-306.
[9].A. Inoue, M. Koshiba, T. Zhang, and T. Masumoto, Appl. Phys., vol.83,1998, pp.1976-1972.
[10].V. Schroeder. C. Gilbert and R. Ritchie, Scripta Mater., vol.38, 1998, p.1481.
[11].A. Inoue, Mater. Sci. Eng., vol.304-306, 2001, p.1.
[12].吳學陞著作，新興材料-塊狀非晶質金屬材料，工業材料，第149期，1999年，pp.154-159。
[13].戴道生、韓汝琪等編著，非晶態物理，高等學校教學用書，電子業出版社，1984年。
[14].Brenner, A, Couch, D. E. and Williams, E. K, J. Res, natn. Bur. Stand, vol.44, 1950, p.109.
[15].陳力俊、張立、梁鉅銘、林文台、楊哲人、鄭晃忠等著，材料電子顯微鏡學，國科會精儀中心，1990年，p.268。
[16].J. Kramer, “Produced the first amorphous metals through vapor deposition”, Annln Phys., vol.19, 1934, p.37.
[17].P. Duwez and S. C. H. Lin, “Amorphous Ferromagnetic Phase in Iron-Carbon-Phosphorus Alloys”, J. Appl. Phys., vol.38, 1967, p.4096.
[18]. W. Klement, R. H. Wilens and P. Duwes, “Thermophysical properties of bulk metallic glass-forming liquids”, Nature, vol.187, 1960, p.869.
[19].X. M. Wang, I. Yoshii, A. Inoue, Y-H. Kim and I-B. Kim, “ Bulk Amorphous Ni75-xNb5MxP20-yBy(M=Cr, Mo) Alloys with Large Supercooling and High Strength”, Mater. Trans., JIM, vol.40, 1999, pp.1130-1136.
[20].A. Peker and W. L. Johnson, “A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5”, Appl. Phys. Letter, vol.63, 1993, p.2342.
[21].K. L. Chapre, Thin Film Phenomena, McGraw-Hill, New York , 1969.
[22].H. S. Chen, “Glassy metals”, Rep. Prog. Phys., vol.43, 1980, pp.353-356.
[23].A. L. Drehman, A. L. Greer and D. Turnbull, “Bulk formation of a metallic glass: Pd40Ni40P20”, Appl. Phys. Letter, vol.41, 1982, p.716.
[24].W. H. Wang, C. Dong and C. H. Shek, “Bulk metallic glasses”, Materials Science and Engineering R., vol.44, 2004, pp.45-89.
[25].A. Inoue and K. Hashimoto, Amorphous and Nanocrystalline Materials, Springer, 1995, p.7.
[26].A. Inoue, “Bulk amorphous alloys with soft and hard magnetic properties”, Mater. Sci. Eng. A, vol.226-228, 1997, pp.357-363.
[27].S. J. Poon, G. J. Shiflet, V. Ponnambalam, V. M. Keppens, R. Taylor and G. Petculescu, “Synthesis of iron-based bulk metallic glasses as nonferromagnetic amorphous steel alloys”, Appl. Phys. Letter, vol.83, 2003, p.1131.
[28].W. L. Johnson, “Bulk glass-forming metallic alloys: science and technology”, MRS Bull., vol.24, 1999, pp.42-56.
[29].A. Inoue, A. Kato, T. Zhang, S. G. Kim and T. Masumoto, “Mg-Cu-Y Amorphous Alloys with High Mechanical Strengths Produced by a Metallic Mold Casting Method”, Mater. Trans. JIM, vol.32, no.7, 1991, p.609.
[30].A. Inoue, “Structural Studies of New Metallic Amorphous Alloys with Wide Supercooled Liquid Region”, Mater. Trans., JIM, vol.36-7, 1995, p.883.
[31].A. Inoue, T, Zhang and A. Takeuchi, “Ferrous and Nonferrous Bulk Amorphous Alloys”, Mater. Sci. Forum, vol.269-272, 1998, p.855.
[32].A. Inoue, A. Takeuchi and T. Zhang, “Ferromagnetic Bulk Amorphous Alloys”, Metall. Mater. Trans., vol.29, 1998, p.1779.
[33].W. Zhang, S. Ishihara, A. Inoue, “Synthesis and Mechanical Properties of Cu-Based Cu-Zr-Ti Bulk Glassy Alloys Containing ZrC Particles”,Mater. Trans., vol.43, 2002, p.1767. G. S. Choi, Y. H. Kim, H.K. Cho,A.Inoue, T. Masumoto, “Ultrahigh tensile Strength of amorphous Al-
Ni-(Nd,Gd)-Fe alloy containing nanocrystalline Al particles”, Scripta Mater., vol.33, 1995,p.1301.
[34].L. I. Naissel and R. Glanz, Handbook of Thin Film Technology, McGraw-Hill, New York, 1970.
[35].G. N. Jackson, Thin Solid Films, Champman and Hall, 1970, p.209.
[36].L. Holland, Vacuum Deposition of Thin Films, John Wiley and Sons Inc. New York, 1958.
[37].Y. Saito, H. Utsunomiya, N. Tsuji and T. Sakai, Acta Mater., vol. 47,1999, p.579.
[38].Z. P. Xing, S. B. Kang and H. W. Kim, Metall. Mater. Trans., vol.33, 2002, p.1521.
[39].C. C. Koch, O. B. Kavin, C. G. Mckamey and J. O. Scarbrough, Appl. Phys. Lett., vol.43, 1983, p.1017.
[40].J. Lee, F. Zhou, K. H. Chung, N. J. Kim and E. J. Lavernia, Metall. Mater. Trans., vol.32, 2001, p. 3109.
[41].M. S. El-Eskandarany and A. Inoue, Metall. Mater. Trans., vol.33, 2002, p.135.
[42].A. Sagel, H. Sieber, H-J. Fecht and J. H. Perepezko, Acta Mater., vol. 46, 1998, p. 4233.
[43].A. Inoue, Bulk Amorphous Alloys Practical Characteristics and Applications Institute for Material Research, Tohoku University Katahira 2-1-1, Sendai no.980-8577.
[44].鄭振東編譯，非晶質金屬漫談，建宏出版社，p.39， 1990。
[45].A. Inoue, K. Nakazato, Y. Kawamura, A. P. Tsai and T. Masumoto,Mater. Trans., JIM, vol.35, 1994, p.95.
[46].H. S. Chen：Glass metals. Rep. Prog. Phys., vol.43, pp.353-356, 1980.
[47].X. H. Du, C. Haung, C. T. Liu, Z. P. Liu,“New Criterion of GlassForming Ability for Bulk Metallic Glasses”, J. Appl. Phys., vol.101, 2007, pp.88-108.
[48].David Broek, The Practical Use of Fracture Mechanics, Kluwer Academic Publishers, (1988),pp. 48-86.
[49].G. R. Irwin, Fracture Dynamics in Fracturing Of Metals, American Society of Metals, Cleveland, (1984).
[50].ASTM E399-09, Annual Book of ASTM Standard. Vols.03.01.
[51].ASTM E1820-01, Annual Book of ASTM Standard. Vols.03.01.
[52].N. Y. Wu, C.J. Hsien, Jason S. C. Jang, S. R Jian, Y.T. Chen“Thermal and mechanical properties of the (Cu36Zr48Al8Ag8)100-xSix (x=0-1) amorphous alloys”. Vol. 638-642, p.1627-1631.
[53].Jason S.C. Jang, S.R. Jian, C.F. Chang, L.J. Chang, Y.C. Huang, T.H. Li, J.C. Huang, C.T. Liu. “ Thermal and mechanical properties of the Zr53Cu30Ni9Al8 based bulk metallic glass microalloyed with silicon” ,(2009),pp.215-219.
[54].A. Slipenyuk, J. Eckert. “Correlation between enthalpy chang and free volume reduction during structural relaxation of Zr55Cu30Al10Ni5 metallic glass ”,(2004), pp.39-44.
[55].Qiang He, Yong-Qiang Cheng, Evan Ma, Jian Xu, “ Locating bulk metallic glasses with high fracture toughness: Chemical effects and composition optimization”, Acta Materialia, (2011), pp, 202-215.
[56].Parag Tandaiya, R. Narasimhan, U. Ramamurty. “ On the mechanism and the length scales involved in the ductile fracture of a bulk metallic glass”, Acta Materialia .

指導教授

鄭憲清(Jason Shian-Ching Jang)

審核日期

2013-7-25

推文