利用次微米球建構具機械性質之光子晶體薄膜

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姓名

林思吟(Ssu-Yin Lin) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

利用次微米球建構具機械性質之光子晶體薄膜
(The formation of photonic crystals film with mechanical properties by submicrospheres)

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至系統瀏覽論文 ( 永不開放)

摘要(中)

本研究利用無乳化劑乳化聚合法於沸騰環境下，製備均一粒徑之自交聯次微米球，並將此次微米球建構具機械性質之光子晶體薄膜。藉由添加自交聯劑(SCA)於次微米球中，使次微米球上之官能性基團與鄰近球間發生自交聯反應而穩定光子晶體結晶結構，得到具機械性質之光子晶體薄膜。
　　高玻璃轉移溫度之P(St-co-SCA)、P(St-co-MAA)/P(St-co-SCA)次微米球之研究中，由於SAC透過自交聯反應，仍無法提供球與球之間連結作用力，使光子晶體薄膜不具機械性質。
　　另一方面，為了提升光子晶體薄膜之機械性質，製備具低玻璃轉移溫度之P(BMA-co-SCA)、P(BMA-co-MAA)/P(BMA-co-SCA)及P(BA-co-MAA)/P(BA-co-SCA)次微米球。此一系列具低玻璃轉移溫度之次微米球透過自組裝程序，可得到具機械性質之光子晶體薄膜。

摘要(英)

In this study, monodisperse self-crosslinking submicrospheres were prepared by soap-free emulsion polymerization at boiling state. The self-crosslinking submicrospheres were prepared by self-crosslinking agent (SAC) in the submicrospheres.
　　P(St-co-SCA) and P(St-co-MAA) /P(St-co-SCA) submicrospheres were prepared. But photonic crystals film with mechanical property wasn’t obtained by these self-crosslinking submicrospheres.
　　On the other hand, photonic crystals film with the mechanical property were obtained by using P(BMA-co-SCA), P(BMA-co-MAA)/P(BMA-co-SCA) and P(BA-co-MAA)/P(BA-co-SCA) submicrospheres.

關鍵字(中)

★ 光子晶體
★ 機械性質
★ 次微米球
★ 無乳化劑乳化聚合法

關鍵字(英)

論文目次

摘要 I
Abstract II
誌謝 III
目錄 IV
圖目錄 VI
表目錄 X
第一章緒論 1
第二章實驗 6
2.1. 實驗藥品 6
2.2. 實驗儀器 8
2.3. 實驗方法 9
2.3.1. 單體精製 9
2.3.2. 快速製備均一粒徑次微米球 9
2.3.3. 一階段法製備自交聯次微米球 10
2.3.4. 二階段法製備自交聯次微米球 11
2.3.5. 光子晶體之製備 12
2.4. 儀器分析測試條件 12
2.4.1. 傅立葉轉換紅外線光譜儀(FTIR) 12
2.4.2. 掃描式電子顯微鏡(SEM) 12
2.4.3. 動態粒徑分析儀(DLS) 12
2.4.4. 紫外光-可見光光譜儀(UV-Vis Spectroscopy) 13
2.4.5. 微差掃描分析儀(DSC) 13
2.4.6. 萬能拉伸試驗機(United Universal Testing Machine) 13
2.4.7. 鉛筆硬度計(Industrial Pencil Test) 13
2.4.8. 折射率儀(Refractometer) 13
第三章結果與討論 14
3.1. 一階段法製備P(St-co-NMA)次微米球之研究 14
3.1.1. P(St-co-NMA)之製備與鑑定 14
3.1.2. 光子晶體薄膜光學性質之研究 21
3.1.3. 光子晶體薄膜機械性質之研究 24
3.2. 二階段法製備P(St-co-MAA)/P(St-co-NMA)次微米球之研究 27
3.2.1. P(St-co-MAA)/P(St-co-NMA)之製備與鑑定 27
3.2.2. 光子晶體薄膜光學性質之研究 31
3.2.3. 光子晶體機械性質之研究質分析 34
3.3. 一階段法製備P(BMA-co-NMA)次微米球之研究 36
3.3.1 P(BMA-co-NMA)之製備與鑑定 36
3.3.2 光子晶體薄膜結構與光學性質之研究 38
3.3.3 光子晶體薄膜機械性質之研究 55
3.3.4 光子晶體薄膜耐溶劑性質之研究 58
3.4. 二階段法製備P(BMA-co-MAA)/P(BMA-co-NMA)次微米球之研究 63
3.4.1 P(BMA-co-MAA)/P(BMA-co-NMA)之製備與鑑定 63
3.4.2 光子晶體薄膜結構與光學特性之鑑定 65
3.4.3 光子晶體薄膜機械性質之鑑定 84
3.4.4 光子晶體薄膜耐溶劑性質之鑑定 87
3.5. 二階段法製備P(BA-co-MAA)/P(BA-co-NMA)次微米球之研究 91
3.5.1 P(BA-co-MAA)/P(BA-co-NMA)之製備與鑑定 91
3.5.2 光子晶體薄膜結構與光學性質之鑑定 93
3.5.3 光子晶體薄膜機械性質之鑑定 105
3.5.4 光子晶體薄膜耐溶劑性質之鑑定 110
3.5.5 光子晶體薄膜經熱處理後之鑑定 114
第四章結論 119
第五章參考文獻 121

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指導教授

陳暉

審核日期

2015-6-15

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