光激發有機極化子元件之製作與量測

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姓名

許書元(Shu-yuan Hsu) 查詢紙本館藏

畢業系所

光電科學與工程學系

論文名稱

光激發有機極化子元件之製作與量測
(Manufacturing and measuring of optically pumped organic polariton device)

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摘要(中)

本論文以有機染料分子DEDOC作為強耦合材料，利用旋轉塗佈製作J-aggregate排列之高吸收DEDOC有機薄膜置入金屬-介電質反射鏡共振腔中，研究微共振腔內激子與光子的強耦合發光機制。本論文設計三種不同腔長的共振腔，透過改變空間層的厚度調整共振腔光子模態能量與激子能量於零度角的偏離量(detuning)。由量測三種元件的多角度反射頻譜與光致發光頻譜，證實了偏極子能態的產生與共振腔內強耦合的機制，並量測到與預期相符的偏極子能態之光強分布。

摘要(英)

We use organic dyes DEDOC to be the material of strongly coupling, and spin the high-absorption organic thin film DEDOC with J-aggregate type in a metal-dielectric microcavity to study the mechanism of strong photon-exction coupling.
We design three microcavity with different thickness of space layer to control the detuning. By measuring the reflective spectrum and photoluminescence spectrum, we prove the mechanism of strong photon-exction coupling in microcavity, and confirm the polariton intensity distribution are in line with expectations.

關鍵字(中)

★ 有機
★ 極化子
★ 微共振腔

關鍵字(英)

★ organic
★ polariton
★ microcavity

論文目次

目錄
摘要 iv
Abstract v
致謝 vi
第一章緒論 1
1-1研究背景 1
1-2有機材料的近期發展 5
1-3研究動機 8
第二章理論分析 10
2-1薄膜理論 10
2-1-1單介面之穿透與反射 10
2-1-2.單層膜之穿透與反射 12
2-1-3多層膜之穿透與反射 16
2-1-4斜向入射 17
2-1-5導納軌跡圖與電場分布 18
2-2微共振腔中的色散關係 23
2-3微共振腔的強耦合作用 26
2-4 J-aggrgate排列 29
第三章實驗架構 31
3-1 製程儀器 31
3-1-1雙電子槍蒸鍍機 31
3-1-2 UV/ozone 33
3-1-3 旋轉塗佈機 34
3-2有機膜製備 34
3-2-1 Layer-by-Layer原理 34
3-2-2 PDAC/DEDOC薄膜製備 36
3-3量測儀器 38
3-3-1 紫外光/可見光光譜儀 38
3-3-2積分球光譜儀 40
3-3-3光致發光量測系統 41
第四章結果與討論 42
4-1高吸收有機材料DEDOC 42
4-2微共振腔元件之設計 43
4-2-1元件架構 43
4-2-2電場分布與色散頻譜模擬 45
4-3實驗結果與討論 47
第五章結論與未來展望 53
參考文獻 55

參考文獻

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指導教授

李正中、張瑞芬(Cheng-Chung? Lee Jui-Fen Chang)

審核日期

2017-1-25

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