摘要(英) |
In this experiment, Prussian blue of K-Fe-Fe phase was prepared by reactive precipitation method. The samples of cubic or monoclinic were prepared by changing the concentration of chelate. The prepared samples will study their crystal structure, magnetic behavior, raman scattering and assembly of lithium-ion batteries.
After the completion of the assembly of the battery into the tester charge and discharge, and observe the structural changes on the impact of charge and discharge, Cubic structure of the sample has a good starting capacity, and monoclinic structure is to have a better charge discharging cycle life. |
參考文獻 |
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[2] Eugenio Coronado, Mari Carmen Gime´nez-Lo´pez, Georgiy Levchenko, Francisco M. Romero,Valentı´n Garcı´a-Baonza,Alla Milner,and Moshe Paz-Pasternak ”Pressure-Tuning of Magnetism and Linkage Isomerism in Iron(II)Hexacyanochromate”, J. AM. CHEM. SOC., VOL.127, NO. 13, 4580, (2005)
[3] Eugenio Coronado, M. Carmen Gime´nez-Lo´pez, Tomasz Korzeniak, Georgiy Levchenko, Francisco M. Romero, Alfredo Segura,Valentı´n Garcı´a-Baonza, Julio C. Cezar, Frank M. F. de Groot, Alla Milner, and Moshe Paz-Pasternak”Pressure-Induced Magnetic Switching and Linkage Isomerismin K0.4Fe4[Cr(CN)6]2.8 ·16H2O: X-ray Absorption and Magnetic Circular Dichroism Studies” J. AM. CHEM. SOC., VOL.130, NO. 46,15519, (2008)
[1]蔡孟宏,o-LiMnO2和LiMn1-xMxO2(M=Cr,Fe,Al,Mg)正極材料的製備及特性研究,大同大學碩士論文 (2007)
[2]Lian Shen, Zhaoxiang Wang,* and Liquan Chen “Prussian Blues as a Cathode Material for Lithium Ion Batteries” Chem. Eur. J. 2014, 20, 12559 – 12562 |