鉬氧化物/銀多層薄膜結構應用於平面微型固態超級電容器

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：30

、訪客IP：3.145.156.250

姓名

鄧格(Ke Teng) 查詢紙本館藏

畢業系所

材料科學與工程研究所

論文名稱

鉬氧化物/銀多層薄膜結構應用於平面微型固態超級電容器
(All-Solid-State Planar Micro-Supercapacitors Based on MoOx/Ag Multilayers)

相關論文

★ 鋅空氣電池之電解質開發	★ 添加石墨烯助導劑對活性碳超高電容電極性質的影響
★ 耐高壓離子液體電解質	★ 熱裂解法製備RuO2-Ta2O5/Ti電極應用於離子液體電解液
★ 碳系超級電容器用耐高壓電解液研發	★ 離子液體與碸類溶劑混合型電解液應用於鋰離子電池矽負極材料
★ 三元素摻雜LLTO混LLZO應用鋰離子電池	★ 以濕蝕刻法於可撓性聚亞醯胺基板製作微通孔之研究
★ 以二氧化釩奈米粒子調變矽化鎂熱電材料之性能	★ 可充電式鋁電池的 4-ethylpyridine–AlCl3電解液、規則中孔碳正極材料以及自放電特性研究
★ 釹摻雜鑭鍶鈷鐵奈米纖維應用於質子傳輸型陶瓷電化學電池空氣電極	★ 於丁二腈電解質添加碳酸乙烯酯對鋰離子電池性能之影響
★ 多孔鎳集電層應用於三維微型固態超級電容器	★ 二氧化錳/銀修飾奈米碳纖維應用於超級電容器
★ 氧化鎳-鑭鍶鈷鐵奈米纖維陰極電極應用於質子傳導型固態氧化物電化學電池	★ 應用丁二腈基離子導體修飾PVDF-HFP 複合聚合物電解質與鋰電極界面之高穩定鋰離子電池

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

[檢視]

[下載]

本電子論文使用權限為同意立即開放。
已達開放權限電子全文僅授權使用者為學術研究之目的，進行個人非營利性質之檢索、閱讀、列印。
請遵守中華民國著作權法之相關規定，切勿任意重製、散佈、改作、轉貼、播送，以免觸法。

摘要(中)

隨著科技快速進步，使得全球對環境與能源日益重視，依賴程度也與日俱增；然而我們所生活的社會正面臨著污染、化石燃料不足、全球暖化等環境與能源危機。為了克服這些問題，迫切需要清潔和可再生能源材料及其裝置。超級電容器不僅擁有優異的功率密度與儲電能力，其亦能提供高速充放電速率及長的循環壽命，且操作安全、具環境友好性，其中微型超級電容器由於可進一步與MEMS和CMOS集成，近年來引起了廣泛的研究興趣。
本研究以濺鍍之MoOx薄膜為活性物質製備指叉式微型固態超級電容器，探討具有不同指叉結構組態(指叉總數、間隙、寬度及長度)的平面微型超級電容器，其幾何構型對電化學性質的影響。此外，本研究引入了基於MoOx/Ag多層薄膜結構之指叉式微型固態超級電容器的新概念。電化學交流阻抗分析證實了由於銀薄膜的摻入，MoOx金屬氧化物之低導電率的缺陷得到有效的改善，使得其體積比電容與能量和功率密度遠高於基於MoOx單層薄膜結構的指叉式微型固態超級電容器，且其體積比電容隨著銀摻入的量增而逐漸增加；但加入過量的銀，比電容在連續充放電後的保持率並不會隨此增加，每層銀厚度為1.5 nm的MoOx/Ag多層薄膜結構經過10000次之大數量的循環次數之後，表現出最優異的循環穩定性和最高的體積比電容。
活性材料的高導電性對基於金屬氧化物的擬電容實現高的比電容以及功率和能量密度至關重要。本研究基於單層MoOx與多層MoOx/Ag薄膜結構之指叉式微型固態超級電容器皆展現相當優異的電化學性能，其結果表明所使用之方法和設計對微型儲能系統的應用表現出巨大的前景。

摘要(英)

With the scientific and technological advancements, the society which we live is facing the energy and environmental related problems such as pollution, deficiency of fossil fuels, and global warming. In order to resolve these issues, green-energy and renewable materials as well as their devices are demanded. Supercapacitors (SCs) exhibit high specific capacitance and power density, fast charge-discharge rate, and long cycle life. In addition, they are safe in operation and environmental friendly. Recently, micro-supercapacitors (MSCs) have attracted much interests since they can be further integrated into MEMS and CMOS.
In this work, we introduce planar interdigitated electrode structure based on MoOx thin film electrode materials, which can be further fabricated to on-chip and all-solid-state MSC. This study investigated the influence of the geometric configuration of planar interdigitated MSCs with different interdigitated patterns (varying the interspace, width, length and number of interdigitated fingers) on their electrochemical properties. Furthermore, we introduce a new concept to fabricate MSC based on MoOx/Ag multilayers, with which the volumetric capacitance is much higher than that of the bare MoOx-based MSC. MoOx/Ag multilayer MSC also demonstrates higher energy density and power density. Electrochemical impedance spectroscopy (EIS) confirmed that the electrical conductivity of MoOx was significantly improved due to the incorporation of silver. The corresponding volumetric capacitance increases as the the silver thickness increases. But with the excess silver, the capacitance retention rate was found to be degraded. MoOx/Ag multilayers MSC with a thickness of 1.5 nm for each Ag layer exhibits most excellent cycle stability and highest volumetric capacitance after a large cycling number of 10000 times.
This work indicates that high electronic conductivity of the electrode material is crucial to achieving high specific capacity as well as power and energy density for pseudocapacitors. These excellent electrochemical performance of results suggest that our method and design show great promise for applications in integrated energy storage for all solid-state microsystems technologies.

關鍵字(中)

★ 超級電容器
★ 擬電容
★ 金屬氧化物
★ 微結構
★ 電化學
★ 儲能元件

關鍵字(英)

★ Supercapacitor
★ Pseudocapacitor
★ Metal oxide
★ Microstructure
★ Electrochemistry
★ Energy storage device

論文目次

摘要 I
Abstract II
致謝 IV
目錄 VI
圖目錄 X
表目錄 XIV
第一章緒論 1
1.1 前言 1
1.2 基本原理與文獻回顧 3
1.2.1 超級電容器簡介 3
1.2.2 超級電容器之儲能機制 4
1.2.2.1 電雙層電容器 4
1.2.2.2 擬電容器 7
1.2.2.3 混合電容器 8
1.2.3 超級電容器之電極材料 9
1.2.3.1 碳系材料 9
1.2.3.2 金屬氧化物 10
1.2.3.3 導電高分子 11
1.2.4 超級電容器之電解質 12
1.2.5 超級電容器之電化學原理與技術 14
1.2.5.1 循環伏安法 14
1.2.5.2 恆電流充放電法 16
1.2.5.3 電化學交流阻抗分析 17
1.2.6 微型超級電容器 18
1.3 研究動機與目的 21
第二章實驗程序與方法 23
2.1 實驗藥品 23
2.2 製程與分析儀器 24
2.2.1 雷射光罩製作系統(Laser Direct Write Image System) 24
2.2.2 光罩對準曝光機(Mask Aligner) 24
2.2.3 旋轉塗佈機(Spin Coater) 24
2.2.4 電漿輔助化學氣相沉積系統(Plasma Enhanced Chemical Vapor Deposition, PECVD) 25
2.2.5 高真空電子束暨熱阻式蒸鍍系統(E-gun & Thermal Evaporation System) 25
2.2.6 射頻與直流磁控濺鍍機(RF&DC Magnetron Sputtering) 26
2.2.7 紫外光臭氧清洗機(UV-Ozone Stripper) 26
2.2.8 恆電位儀(Potentiostat) 27
2.2.9 X射線光電子能譜(X-Ray Photoelectron spectroscopy, XPS) 27
2.2.10 掃描式電子顯微鏡(Scanning Electron Microscopy, SEM) 28
2.2.11 掃描穿透式電子顯微鏡(Scanning Transmission Electron Microscopy, STEM) 28
2.2.12 雙束型聚焦離子束顯微鏡(Dual Beam Focus Ion Beam, DB-FIB) 29
2.2.13 原子力顯微鏡(Atomic Force Microscope, AFM) 29
2.3 實驗流程 30
2.4 實驗製程 31
2.4.1 指叉圖形結構與組態之設計 31
2.4.2 製備SiO2/Si基板 33
2.4.3 黃光微影 33
2.4.4 製備集電極 33
2.4.5 製備活性物質 34
2.4.6 掀離製程 35
2.4.7 製備固態電解質 35
2.4.8 製備指叉式微型固態超級電容器 35
第三章實驗結果與討論 37
3.1 材料分析 37
3.1.1穿透式電子顯微鏡分析(TEM) 37
3.1.2掃描電子顯微鏡分析(SEM) 42
3.1.3 原子力顯微鏡分析(AFM) 42
3.1.4 X射線光電子能譜分析(XPS) 45
3.2 不同結構組態之MoOx指叉式微型固態超級電容器特性分析 47
3.2.1 循環伏安與恆電流充放電分析 47
3.2.2 電化學交流阻抗分析 52
3.3 MoOx與MoOx/Ag指叉式微型固態超級電容器特性分析 55
3.3.1 循環伏安與恆電流充放電分析 55
3.2.2 電化學交流阻抗分析 60
3.2.3 循環穩定性分析 61
3.2.4 頻率響應分析 64
第四章結論 67
第五章參考文獻 69

參考文獻

1. M. Jayalashmi and K. Balasubramanian, “Simple capacitors to supercapacitors - an overview,” Int. J. Electrochem. Sci. 3, 1196-1217 (2008).
2. D. P. Dubal, P. Gomez-Romero, B. R. Sankapal and R. Holze, “Nickel Cobaltite as an Emerging Material for Supercapacitors: An Overview,” Nano Energy 11, 377-399(2015).
3. P. Simon and Y. Gogotsi, “Materials for electrochemical capacitors,” Nat. Mater. 7, 845-854(2008).
4. A. González, E. Goikolea, J. A. Barrena and R. Mysyk, “Review on supercapacitors: technologies and materials, ” Renew Sustain Energy Rev. 58, 1189-1206(2016).
5. Z. Yang, J. Zhang, M. C. W. Kintner-Meyer, X. Lu, D. Choi, J. P. Lemmon and J. Liu, “Electrochemical Energy Storage for Green Grid,” Chem. Rev. 111, 3577-3613(2011).
6. Y. Wang, J. Guo, T. Wang, J. Shao, D. Wang and Y.-W. Yang, “Mesoporous Transition Metal Oxides for Supercapacitors,” Nanomaterials 5, 1667-1689(2015).
7. W.-C. Hung, C.-L. Chang and Y.-P. Wang, “石墨烯於超級電容之應用研究,” 新新季刊第四十二卷第一期, 35-43(2014).
8. R. F. Service, “New ‘supercapacitor’ promises to pack more electrical punch,” Science 313, 902-905(2006).
9. A. K. Shukla, S. Sampath and K. Vijayamohanan, “Electrochemical supercapacitors: Energy storage beyond batteries,” Curr. Sci. 79, 1656-1661(2000).
10. C. D. Lokhande, D. P. Dubal and O. S. Joo, ” Metal oxide thin film based supercapacitors,” Curr. Appl. Phys. 11, 255-270(2011).
11. A. G. Pandolfo and A. F. Hollenkamp, “Carbon properties and their role in supercapacitors,” J. Power Sources 157, 11-27(2006).
12. M. Vangari, T. Pryor and L. Jiang, “Supercapacitors: Review of Materials and Fabrication Methods,” J. Energy Eng. 139, 72-79(2013).
13. R. Kötz and M. Carlen, “Principles and applications of electrochemical capacitors,” Electrochim. Acta 45, 2483-2498(2000).
14. G. Wang, L. Zhang and J. Zhang, “A Review of Electrode Materials for Electrochemical Supercapacitors,” Chem. Soc. Rev. 41, 797-828(2012).
15. L. L. Zhang and X. S. Zhao, “Carbon-based Materials as Supercapacitor Electrodes,” Chem. Soc. Rev. 38, 2520-2531(2009).
16. M. S. Kolathodi, M. Palei and T. S. Natarajan, “Electrospun NiO nanofibers as cathode materials for high performance asymmetric supercapacitors,” J. Mater. Chem. A 3, 7513-7522(2015).
17. J. Q. Xiao, Q. Lu, and J. G. Chen, “Nanostructured Electrodes for High-performance Pseudocapacitors,” Angew. Chem. Int. Ed. 52, 1882-1889(2013).
18. V. Augustyn, P. Simon and B. Dunn, “Pseudocapacitive Oxide Materials for High-rate Electrochemical Energy Storage,” Energy Environ. Sci. 7, 1597-1614(2014).
19. H. Zhao, W. Han, W. Lan, J. Zhou, Z. Zhang, W. Fu and E. Xie, “Bubble Carbon-nanofibers Decorated with MnO2 Nanosheets as High-Performance Supercapacitor Electrode,” Electrochim. Acta 222, 1931-1939(2016).
20. H. Wang, H. S. Casalongue, Y. Liang and H. Dai, “Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials,” J. Am. Chem. Soc. 132, 7472-7477(2010).
21. S. C. Lee, U. M. Patil, S. J. Kim, S. Ahn, S.-W. Kang and S. C. Jun, “All-solid-state flexible asymmetric micro supercapacitors based on cobalt hydroxide and reduced graphene oxide electrodes,” RSC Adv. 6, 43844-43854(2016).
22. C. W. Shen, X. H. Wang, S. W. Li, J. G. Wang, W. F. Zhang and F. Y. Kang, “A high-energy-density micro supercapacitor of asymmetric MnO2-carbon configuration by using micro-fabrication technologies,” J. Power Sources 234, 302-309(2013).
23. Y. Zhang, H. Feng, X. Wu, L. Wang, A. Zhang, T. Xia, H. Dong, X. Li and L. Zhang, “Progress of electrochemical capacitor electrode materials: A review,” Int. J. Hydrogen Energy 34, 4889-4899(2009).
24. S.-M. Chen, R. Ramachandran, V. Mani and R. Saraswathi, “Recent Advancements in Electrode Materials for the High-performance Electrochemical Supercapacitors: A Review,” Int. J. Electrochem. Sci. 9, 4072-4085(2014).
25. T. Zhai, X. Lu, F. Wang, H. Xia and Y. Tong, “MnO2 nanomaterials for flexible supercapacitors: performance enhancement via intrinsic and extrinsic modification,” Nanoscale Horiz. 1, 109-124(2016).
26. G. Salitra, A. Soffer, L. Eliad, Y. Cohen and D. Aurbach, “Carbon Electrodes for Double‐Layer Capacitors I. Relations Between Ion and Pore Dimensions,” J. Electrochem. Soc. 147, 2486-2493(2000).
27. O. Barbieri, M. Hahn, A. Herzog and R. Kotz, “Capacitance limits of high surface area activated carbons for double layer capacitors,” Carbon 43, 1303-1310(2005).
28. D. Qu and H. Shi, “Studies of activated carbons used in double-layer capacitors,” J. Power Sources 74, 99-107(1998).
29. M. Endo, T. Maeda, T. Takeda, Y. J. Kim, K. Koshiba, H. Hara and M. S. Dresselhaus, “Capacitance and Pore-Size Distribution in Aqueous and Nonaqueous Electrolytes Using Various Activated Carbon Electrodes,” J. Electrochem. Soc. 148, A910-A914(2001).
30. J. N. Barisci, G. G. Wallace and R. H. Baughman, “Electrochemical Characterization of Single-Walled Carbon Nanotube Electrodes,” J. Electrochem. Soc. 147, 4580-4583(2000).
31. S. Shiraishi, H. Kurihara, K. Okabe, D. Hulicova and A. Oya, “Electric double layer capacitance of highly pure single-walled carbon nanotubes (HiPcoTM BuckytubesTM) in propylene carbonate electrolytes,” Electrochem. Commun. 4, 593-598(2002).
32. C. Kim, “Electrochemical characterization of electrospun active carbon nanofiber as an electrode in supercapacitor,” J. Power Sources 142, 382-388(2005).
33. Z. Fan, J. Yan, L. Zhi, Q. Zhang, T. Wei, J. Feng, M. Zhang, W. Qian and F. Wei, “A three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors,” Adv Mater 22, 3723-3728(2010).
34. Y. Song, J.-L. Xu and X.-X. Liu, “Electrochemical anchoring of dual doping polypyrrole on graphene sheets partially exfoliated from graphite foil for high-performance supercapacitor electrode,” J Power Sources 249, 48-58(2014).
35. C. C. Hu, K. H. Chang, M.C. Lin and Y. T. Wu, “Design and Tailoring of the Nanotublar Arrayed Architecture of Hydrous RuO2 for Next Generation Supercapacitors,” Nano Lett. 6, 2690-2695(2006).
36. S. Devaraj and N. Munichandraiah, “Effect of Crystallographic Structure of MnO2 on its Electrochemical Capacitance Properties,” J. Phys. Chem. C 112, 4406-4417(2008).
37. J. G. Wang, Y. Yang, Z. H. Huang and F. Kang, “Effect of Fe3+ on the Synthesis and Electrochemical Performance of Nanostructured MnO2,” Mater. Chem. Phys. 133, 437-444(2012).
38. L. Lu, H. Xia, J. Feng, H. Wang and M. O. Lai, “MnO2 Nanotube and Nanowire Arrays by Electrochemical Deposition for Supercapacitors,” J. Power Sources 195, 4410-4413 (2010).
39. A. Bahloul, B. Nessark, E. Briot, H. Groult, A. Mauger, K. Zaghib and C. M. Julien, “Polypyrrole-covered MnO2 as Electrode Material for Supercapacitor,” J. Power Sources 240, 267-272(2013).
40. J. Wang, B. Ren, M. Fan, Q. Liu, D. Song and X. Bai, “Hollow NiO Nanofibers Modified by Citric Acid and the Performance as Supercapacitor Electrode,” Electrochim. Acta 92, 197-204(2013).
41. X. Yan, X. Tong, J. Wang, C. Gong, M. Zhang and L. Liang, “Synthesis of Mesoporous NiO Nanoflake Array and its Enhanced Electrochemical Performance for Supercapacitor Applications,” J. Alloys and Compounds 593, 184-189(2014).
42. C. Z. Yuan, L. Yang, L. R. Hou, L. F. Shen, F. Zhang, D. K. Li, X. G. Zhang, “Large-scale Co3O4 nanoparticles growing on nickel sheets via a one-step strategy and their ultra-highly reversible redox reaction toward supercapacitors,” J. Mater. Chem. 21, 18183-18185(2011).
43. K. S. Ryu, K. M. Kim, N.-G. Park, Y. J. Park and S. H. Chang, ” Symmetric redox supercapacitor with conducting polyaniline electrodes,” J. Power Sources 103, 305-309(2002).
44. A. Clémente, S. Panero, E. Spila and B. Scrosati, “Solid-state, polymer-based, redox capacitors,” Solid State Ionics 85, 273-277(1996).
45. A. Laforgue, P. Simon, C. Sarrazin and J.-F. Fauvarque, “Polythiophene-based supercapacitors,” J. Power Sources 80, 142(1999).
46. F. Selampinar, U. Akbulut and L. Toppare, “Conducting polymer composites of polypyrrole and polyimide,” Synth. Met. 84, 185-186(1997).
47. C. Zhong, Y. Deng, W. Hu, J. Qiao, L. Zhang and J. J. Zhang, “A review of electrolyte materials and compositions for electrochemical supercapacitors,” Chem. Soc. Rev. 44, 7484-7539(2015).
48. H. Gao and K. Lian, “Proton-conducting polymer electrolytes and their applications in solid supercapacitors: a review,” RSC Adv. 4, 33091-33113(2014).
49. 胡啟章, “電化學原理與方法(二版),” 五南圖書出版, (2002).
50. Francois Beguin(著), Elzbieta Frackowiak(著), 張治安(譯), “超級電容器：材料、系統及應用,” 機械工業出版, (2014).
51. D. S. Yu, K. Goh, H. Wang, L. Wei, W. C. Jiang, Q. Zhang, L. M. Dai and Y. Chen, “Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage,” Nat. Nanotech. 9, 555-562(2014).
52. W. Zaidi, A. Boisset, J. Jacquemin, L. Timperman and M. Anouti, “Deep Eutectic Solvents Based on N-Methylacetamide and a Lithium Salt as Electrolytes at Elevated Temperature for Activated Carbon-Based Supercapacitors,” J. Phys. Chem. C 118, 4033-4042(2014).
53. X.-M. Liu, R. Zhang, L. Zhan, D.-H. Long, W.-M. Qiao, J.-H. Yang and L.-C. Ling, “Impedance of carbon aerogel/activated carbon composites as electrodes of electrochemical capacitors in aprotic electrolyte,” New Carbon Mater 22, 153-1588(2007).
54. D. Pech, M. Brunet, T. M. Dinh, K. Armstrong, J. Gaudet and D. Guay, “Influence of the configuration in planar interdigitated electrochemical micro-capacitors,” J. Power Sources 230 , 230-235(2013).
55. B. Huang, X.-Z. Sun, X. Zhang, D.-C. Zhang and Y.-W. Ma, “活性炭基軟包裝超級電容器用有機電解液,” Acta Phys.-Chim. Sin. 29, 1998-2004(2013).
56. M. Beidaghi and Y. Gogots, “Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of microsupercapacitors,” Energy Environ. Sci. 7, 867-884(2014).
57. C. W. Shen, X. H. Wang, W. F. Zhang and F. Y. Kang, “A high-performance three-dimensional micro supercapacitor based on self-supporting composite materials,” J. Power Sources 196, 10465-10471 (2011).
58. D. Pech, M. Brunet, H. Durou, P. Huang, V. Mochalin, Y. Gogotsi, P.-L. Taberna and P. Simon, “Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon,” Nature Nanotech. 5, 651-654 (2010).
59. Z. Zeng, X. Long, H. Zhou, E. Guo, X. Wang and Z. Hu, “On-chip interdigitated supercapacitor based on nano-porous gold/manganese oxide nanowires hybrid electrode,” Electrochim. Acta 163, 107-115(2015).
60. M. Beidaghi and C. Wang, “Micro-Supercapacitors Based on Interdigital Electrodes of Reduced Graphene Oxide and Carbon Nanotube Composites with Ultrahigh Power Handling Performance,” Adv. Funct. Mater. 22, 4501-4510(2012).
61. W. Si, C. Yan, Y. Chen, S. Oswald, L. Han and O.G. Schmidt, “On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers,” Energy Environ. Sci. 6, 3218-3223(2013).
62. K. Wang, W. J. Zou, B. Quan, A. F. Yu, H. P. Wu, P. Jiang and Z. X. Wei, “An All-Solid-State Flexible Micro-supercapacitor on a Chip,” Adv. Energy Mater. 1, 1068-1072(2011).
63. E. Eustache, C. Douard, R. Retoux, C. Lethien and T. Brousse, “MnO2 Thin Films on 3D Scaffold: Microsupercapacitor Electrodes Competing with “Bulk” Carbon Electrodes,” Adv. Energy Mater., 1500680(2015).
64. Y. D. Zhang, B. P. Lin, Y. Sun, P. Han, J. C. Wang, X. J. Ding, X. Q. Zhang and H. Yang, “MoO2@Cu@C Composites Prepared by Using Polyoxometalates@Metal-Organic Frameworks as Template for All-Solid-State Flexible Supercapacitor,” Electrochim. Acta, 188, 490-498(2016).
65. X. H. Lu, T. Zhai, X. H. Zhang, Y. Q. Shen, L. Y. Yuan, B. Hu, L. Gong, J. Chen, Y. H. Gao, J. Zhou, Y. X. Tong and Z. L. Wang, “WO3-x@Au@MnO2 Core-Shell Nanowires on Carbon Fabric for High-Performance Flexible Supercapacitors,” Adv. Mater. 24, 938-944(2012).
66. J. Zhou, J. Lian, L. Hou, J. Zhang, H. Gou, M. Xia, Y. Zhao, T. A. Strobel, L. Tao and F. Gao, “Ultrahigh volumetric capacitance and cyclic stability of fluorine and nitrogen co-doped carbon microspheres,” Nat. Commun. 6, 8503(2015).
67. T. Qiu, B. Luo, M. Giersig, E. M. Akinoglu, L. Hao, X. Wang, L. Shi, M. Jin and L. Zhi, “Au@MnO2 Core-Shell Nanomesh Electrodes for Transparent Flexible Supercapacitors,” Small 10, 4136-4141(2014).
68. C. Y. Yang, J. L. Shen, C. Y. Wang, H. J. Fei, H. Bao and G. C. Wang, “All-solid-state asymmetric supercapacitor based on reduced graphene oxide/carbon nanotube and carbon fiber paper/polypyrrole electrodes,” J. Mater. Chem. A 2, 1458-1464(2014).

指導教授

李勝偉(Sheng-Wei Lee)

審核日期

2017-8-7

推文