耐高壓離子液體電解質

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姓名

王怡雯(Yi-Wun Wang) 查詢紙本館藏

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材料科學與工程研究所

論文名稱

耐高壓離子液體電解質
(The Ionic Liquid Electrolytes for High Voltage Lithium Ion Batteries.)

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摘要(中)

本研究的第一部分，首先比較離子液體0.8 m LiFSI/PMP-FSI與傳統碳酸酯類電解質1 M LiPF6/EC-DEC應用在高電壓LiNi0.5Mn1.5O4/Li半電池中。0.8 m LiFSI/PMP-FSI電解質在熱穩定性及浸泡實驗中皆能得到較1 M LiPF6/EC-DEC好的表現；但是，在高電壓環境下0.8 m LiFSI/PMP-FSI會發生鋁腐蝕的問題，使其無法應用於LiNi0.5Mn1.5O4的材料中。
延續第一部分的結果，在第二部分針對0.8 m LiFSI/PMP-FSI改質。首先提高鋰鹽濃度來嘗試抑制鋁腐蝕反應。發現鋰鹽濃度愈高，愈能抑制鋁腐蝕反應，但3.2 m LiFSI/PMP-FSI為最大溶解濃度也無法完全抑制鋁腐蝕，故需需要尋找其他方法解決鋁腐蝕問題。
在第二部分發現提高鋰鹽濃度確實能改善鋁腐蝕問題，但仍無法完全抑制。故在第三部分加入TFSI陰離子期望能得到更好的結果，相比純FSI-based離子液體，加入TFSI陰離子後的鋁腐蝕反應明顯降低，在0.8 m LiFSI/FT 13的條件下可解決鋁腐蝕問題。但發現其在高速充放電及graphite負極中電性表現較純FSI-based離子液體來的差，故本研究期望能在改善配方已得到最佳的電性表現。
在第四部分，結合第二及第三部分的研究，同時提高Li及TFSI濃度，發現在TFSI比例較低的配方下即可抑制鋁腐蝕問題，其中2.4 m LiTFSI/PMP-FSI雖然在抑制鋁腐蝕方面略遜於0.8 m LiFSI/FT 13，但在高速充放電及graphite負極中表現較好。

摘要(英)

In the first part of the study, we first compared the ionic liquid 0.8 m LiFSI/PMP-FSI with the traditional carbonate electrolyte 1 M LiPF6/EC-DEC in a high voltage LiNi0.5Mn1.5O4/Li half-cell. 0.8 m LiFSI/PMP-FSI electrolytes can achieve better performance than 1 M LiPF6/EC-DEC in thermal stability and immersion experiments; however, aluminum corrosion occurs at 0.8 m LiFSI/PMP-FSI in high voltage environments. The problem is that it cannot be applied to LiNi0.5Mn1.5O4.
Continuing the results of the first part, the second part was modified for 0.8 m LiFSI/PMP-FSI. First, increase the lithium salt concentration to try to suppress the aluminum corrosion reaction. It is found that the higher the lithium salt concentration, the more the aluminum corrosion reaction can be inhibited, but the 3.2 m LiFSI/PMP-FSI is the maximum dissolved concentration and can not completely inhibit the aluminum corrosion. Therefore, it is necessary to find other methods to solve the aluminum corrosion problem.
In the second part, it was found that increasing the lithium salt concentration did improve the aluminum corrosion problem, but it could not be completely suppressed. Therefore, the addition of TFSI anion in the third part is expected to give better results. Compared with the pure FSI-based ionic liquid, the aluminum corrosion reaction after adding the TFSI anion is significantly reduced, and the aluminum corrosion can be solved under the condition of 0.8 m LiFSI/FT 13. However, it was found that its electrical performance in high-speed charge and discharge and graphite anodes is worse than that of pure FSI-based ionic liquids. Therefore, this study is expected to obtain the best electrical performance in improving the formulation.
In the fourth part, combined with the second and third parts of the study, while increasing the concentration of Li and TFSI, it was found that the aluminum corrosion problem can be suppressed under the formulation with a lower TFSI ratio, of which 2.4 m LiTFSI/PMP-FSI is inhibiting aluminum. Corrosion is slightly inferior to 0.8 m LiFSI/FT 13, but it performs better in high-speed charge and discharge and graphite anode.

關鍵字(中)

★ 高電壓
★ 離子液體

關鍵字(英)

論文目次

摘要 I
ABSTRACT III
誌謝 V
總目錄 VI
表目錄 X
圖目錄 XV
一、前言 1
二、研究背景與文獻回顧 3
2-1 高電壓鋰離子電池正極 3
2-1-1 高電壓正極材料簡介 3
2-1-2 LiNi0.5Mn1.5O4正極材料 5
2-2 有機電解質應用於高電壓鋰離子電池 7
2-2-1 電解質溶劑分解 7
2-2-2 鋰鹽分解 13
2-2-3 全電池問題 14
2-2-4 安全性 17
2-3 離子液體電解質 19
2-3-1 離子液體於高電壓下研究現況 19
2-3-2 FSI-系列離子液體於負極下研究現況 22
2-3-3 FSI-系列離子液體在正極下的應用 26
2-4 FSI-based離子液體在高電壓下的問題 28
2-4-1 鋁基材腐蝕 28
2-4-2 鋁基材腐蝕解決方法 33
三、實驗方法與步驟 39
3-1 實驗藥品與器材 39
3-1-1 實驗藥品 39
3-1-2 實驗器材 40
3-2 離子液體製備 41
3-2-1 不同LiFSI濃度離子液體 41
3-2-2 不同陰離子比例離子液體 41
3-2-3 不同LiTFSI濃度離子液體 42
3-3 電池製備 43
3-3-1 極片製作 43
3-3-2 鈕扣型電池封裝 43
3-4 基礎性質分析 44
3-4-1 Raman 44
3-4-2 黏度計 44
3-4-3 燃燒測試 44
3-4-4 TGA 45
3-4-5 浸泡實驗 45
3-4-6 XRF 45
3-4-7 SEM 45
3-5 電化學性質測試 46
3-5-1 線性掃描伏安法與定電壓測試(Linear scan voltammetry) 46
3-5-2 計時電位法(Chronopotentimetry) 46
四、結果與討論 47
4-1 不同電解質應用於LNMO正極 47
4-1-1 電解質之黏度 47
4-1-2 TGA熱穩定分析 48
4-1-3 燃燒測試 49
4-1-4 浸泡實驗 51
4-1-5 電解質電位窗量測 53
4-1-6 室溫下的石墨負極定電流充放電 54
4-1-7 電解質之鋁腐蝕探討 59
4-1-8 室溫下的LNMO正極定電流充放電 63
4-2 不同LiFSI濃度離子液體電解質應用於LNMO正極 66
4-2-1 電解質之黏度 66
4-2-2 電解質之結構鑑定 67
4-2-3 TGA熱穩定分析 71
4-2-4 燃燒測試 72
4-2-5 電解質之鋁腐蝕探討 74
4-2-6 室溫下的LNMO正極定電流充放電 78
4-3 FSI-及TFSI-混和型離子液體電解質 84
4-3-1 電解質之黏度 84
4-3-2 電解質之結構鑑定 85
4-3-3 TGA之熱穩定分析 87
4-3-4 燃燒測試 88
4-3-5 電解質之鋁腐蝕探討 90
4-3-6 室溫下的LNMO正極定電流充放電 94
4-3-7 室溫下的石墨負極定電流充放電 101
4-4 不同LiTFSI濃度離子液體電解質應用於LNMO正極 107
4-4-1 電解質之黏度 107
4-4-2 電解質之結構鑑定 108
4-4-3 TGA之熱穩定分析 110
4-4-4 電解質之鋁腐蝕探討 111
4-4-5 室溫下的LNMO正極定電流充放電 116
4-4-6 室溫下的石墨負極定電流充放電 122
五、結論 128
六、參考文獻 129

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指導教授

張仍奎李勝偉

審核日期

2018-10-18

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