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姓名	辛昱諭(Yu-Yu Sin)  查詢紙本館藏	畢業系所	能源工程研究所
論文名稱	超高附著力之氟化石墨烯薄膜於固態磨潤之研究 (The study on the solid state lubrication of ultra-high adhesion fluorinated graphene film)
相關論文	★ 捲對捲乾轉印方法於製作高效能石墨烯透明導電膜之研究 ★ 利用氟素高分子摻雜於提升石墨烯導電膜的效能 與穩定性之研究 ★ 以石墨烯混成陶瓷粉末於製作高導熱及高電阻之聚亞醯胺薄膜的研究 ★ 以奈米銅催化輔助控制多孔石墨烯之孔隙結構及其於超級電容之研究 ★ 研究超潔淨石墨烯之場效電晶體 於提升基因感測器之效能 ★ 利用氟化自組裝膜輔助轉印石墨烯薄膜及其於場效電晶體特性之研究 ★ 多孔石墨烯邊界態之氮改質於超級電容的效能研究 ★ 石墨烯場效應電晶體應用於DNA生醫感測晶片之元件整合和效能評估的研究 ★ 添加氟化石墨烯於奈米高分子複合材料以增強防 腐性能 ★ 石墨烯功能性改質於鋰離子電池負極材料 之研究 ★ 紫外光輻照於輔助轉印高品質石墨烯之研究 ★ 氟化石墨烯複合結構於鋰離子電池的人工固態電解質界面膜之研究 ★ 真空壓印於二維材料轉印製程之研究 ★ 氟化石墨烯複合結構在鋰金屬電池中的雙功能陽極之機制探討 ★ 氟化石墨烯複合材料塗層於多功能披覆之研究 ★ 三維結構之微孔石墨烯於超級電容器之應用與研究
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摘要(中)	氟化石墨烯近年來憑藉其二維材料特有片層滑移系統及其更低之表面能(C-F鍵)，成為固態磨潤領域的高潛力材料。然而其在應用上仍有許多瓶頸急需要解決。傳統製程高毒性、汙染及氟化率不均問題使其目前仍難以達到工業上的均質及量產需求，此外這類二維材料在塗佈時的低附著性瓶頸更大幅限制了其實際應用。本研究將介紹一種以含氟高分子為前驅物之綠色製程於量產氟化石墨烯，相較於過去習用製程更為安全環保且產物更為均質穩定並符合量產製程所需。此外利用電泳沉積法製備具有高附著力和膜厚可控性之氟化石墨烯固態磨潤塗層，其厚度可簡單透過調整如施加電壓或是電泳時間控制於0.2至2.5 μm之間。研究發現透過電泳沉積法形成之新型態鍵結CF-Cu以及CF-Cu-FC鍵結可大幅提升氟化石墨烯與金屬底材之附著力，於刮痕測試中，其臨界荷重可達23.81 N遠大於一般刮塗之1.92 N。而在磨耗特性分析上，氟化石墨烯塗層可使銅基板之摩擦係數由0.77降低至0.26，且其壽命可達929 圈，並能有效降低磨耗率達35%。此外，此技術亦可延伸並應用於其他常見的工業金屬基板如鋁鎂合金以及碳鋼上，並發現其亦可分別降低磨耗率達50以及90%。本研究亦展示了此方法在時效性、熱穩定性以及複雜工件表面塗佈等方面之潛力。憑藉著符合工業需求之製程技術以及展現高抗磨耗之效能，本研究展示了新材料於固態磨潤的一種極具未來潛力的解決策略。
摘要(英)	With the unique interlayer sliding system and their extremely low surface free energy (C-F bonding), the fluorinated graphene (FG) became a potential 2D material in the research of solid lubricant. However, to become an industry product there are still some urgent issues that need to be solved. The toxic, high pollution chemicals and unstable fluorination degree of FG by the typical methods hinders their industry demand like the uniform mass production. In addition, the low adhesion issue in the 2D material coating seriously limited its practical applications. In this report, low pollution with high yield fabrication method of FG is introduced by using a high fluorine-based polymer as the precursor, which exhibited a higher safety and better product uniformity when compared to the traditional fluorinated method that enabled the request of mass production in industry application. In addition, by using the electrophoretic deposition method (EPD), an ultrahigh adhesion with a thickness controllable (0.2 to 2.5 μm) was achieved. With the formation of the unique CF-Cu and CF-Cu-FC bonding during the deposition process, the adhesion of FG film is highly improved, where the critical loading is up to 23.81 N which was much higher than FG coating prepared by print coating (1.92 N) in scratch testing. The as-prepared FG solid lubricant film on Cu substrate successfully decreases the coefficient of friction (CoF) from 0.77 to 0.26 with a long lifetime of up to 929 cycles and a decreasing wear rate by 35%. Also, the frequently used substrates such as aluminum-magnesium alloy and carbon steel were tested, where a decrease in wear rate by 50 and 90% were obtained, respectively. In this study, FG coating showed high stability while the EPD method exhibits the feasibility of deposition on complex surface substrates with high uniformity, which provides a new strategy to prepare a robust and high-performance solid lubricant film.
關鍵字(中)	★ 氟化石墨烯 ★ 電泳沉積法 ★ 強附著力二維材料薄膜 ★ 固態磨潤	關鍵字(英)	★ Fluorinated graphene ★ Electrophoretic deposition ★ Strong adhesion 2D material film ★ Solid state lubrication.
論文目次	摘要 I Abstract VI 誌謝 VII 總目錄 VIII 圖目錄 X 表目錄 XIV 第一章 緒論 1 1-1 前言 1 1-2 固態磨潤 2 第二章 研究背景與文獻回顧 4 2-1 石墨烯材料於磨潤應用之研究 4 2-2 氟化石墨烯於磨潤應用之研究 8 2-3 氟化石墨烯之製備方法 10 2-4 二維材料塗層低附著力問題 14 2-5 實驗動機 17 第三章 實驗方法與步驟 19 3-1 實驗方法 19 3-2 氟化石墨烯合成製備 20 3-3 氟化石墨烯特性分析 21 3-4 電泳氟化石墨烯固態磨潤薄膜 21 3-5 電泳氟化石墨烯塗層性質分析 22 3-6 磨潤特性分析 23 第四章 結果與討論 24 4-1 水熱法置備之氟化石墨烯性質分析 24 4-1-1 水熱製程中前驅物添加量對氟化石墨烯產物特性之影響 25 4-1-2 氟化石墨烯產物化學特性分析 27 4-1-3 氟化石墨烯產物片層結構特性分析 29 4-2 電泳氟化石墨烯塗層性質分析 31 4-2-1 電泳塗佈製程中電泳液中氟化石墨烯濃度對於沉積塗層品質之影響 31 4-2-2 電泳塗佈製程中電泳液分散劑對於沉積塗層品質之影響 32 4-2-3 電泳施加電壓以及沉積時間對於沉積塗層結構之影響 34 4-2-4 電泳沉積時間對於沉積塗層化學特性之影響 37 4-2-5 電泳沉積氟化石墨烯塗層之附著力分析 41 4-3 電泳氟化石墨烯塗層磨潤特性分析 50 4-3-1 氟化石墨烯固態磨潤塗層之摩擦係數分析 50 4-3-2 氟化石墨烯固態磨潤塗層之磨耗分析 54 4-4 電泳氟化石墨烯塗層於其他種類基板上之磨潤特性分析 56 4-4-1 氟化石墨烯固態磨潤塗層於鋁鎂合金上之磨潤特性分析 56 4-4-2 氟化石墨烯固態磨潤塗層於碳鋼上之磨潤特性分析 58 4-5 電泳氟化石墨烯固態磨潤塗層之穩定性評估 63 4-6 電泳氟化石墨烯固態磨潤塗層於複雜基板之塗佈 64 第五章 結論 65 第六章 未來工作 66 參考文獻 68
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指導教授	蘇清源(Ching-Yuan Su)	審核日期	2022-1-10
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