博碩士論文 108384601 詳細資訊




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姓名 蓓達(Belda Amelia Junisu)  查詢紙本館藏   畢業系所 化學工程與材料工程學系
論文名稱 聚(4-乙烯基吡啶)和聚(2-乙烯基吡啶)薄膜的表面不穩定性
(Surface Instability in Poly(4-Vinyl Pyridine) and Poly(2-Vinyl Pyridine) Films)
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摘要(中) 此篇高分子薄膜研究,其源於對液體於自由表面濕潤現象以及介面作用力的興趣。此外,對於高分子薄膜表面不穩定性的理解在技術應用的廣泛領域中不斷取得進展。對於特定的應用來說,表面不穩定是一件須要避免的事情,因此,薄膜穩定性是非常重要的。然而,能夠檢測和調控薄膜表面的不穩定性也可以在光電子學、生物科技、奈米微影製程和新型感測器和驅動器等應用中帶來優勢。許多研究專注於高分子薄膜受外力所誘發表面不穩定性之複雜性。在此篇研究中,我們利用聚(4-乙烯基吡啶)(P4VP)以及聚(2-乙烯基吡啶)(P2VP)來研究薄膜的不穩定性。我們利用含浸法來測試聚(4-乙烯基吡啶) (P4VP)和聚(2-乙烯基吡啶) (P4VP)的表面不穩定性,利用旋轉塗佈法將薄膜固定於基材上,然後浸入包含四氯金酸(HAuCl4)及碳酸鉀(K2CO3)混合物的種子溶液中。聚合物與溶劑之間作用力以及界面力所導致的協同效應使得聚(4-乙烯基吡啶)P4VP和聚(2-乙烯基吡啶)P2VP薄膜表面分別形成皺紋和坑洞。表面皺紋和坑洞的多寡受到多種因素的強烈影響,包括薄膜厚度、四氯金酸(HAuCl4)的量以及金離子的類型。除此之外,我們還對旋轉塗佈過程中聚(4-乙烯基吡啶)P4VP薄膜表面不穩定性進行了研究。觀察到在巨觀尺度、微觀尺度和介觀尺度上的多層級結構。這些結果為了解聚(4-乙烯基吡啶)P4VP和聚(2-乙烯基吡啶)P2VP薄膜表面不穩定性的動態提供了寶貴的見解。
摘要(英) The study of thin polymer films is driven by a fundamental interest in wetting phenomena and interfacial interactions of liquids at free surfaces. Furthermore, the vast field of technological applications sparks continuous advancements in the understanding of surface instability in polymer thin films. Surface instability might be undesirable for some applications where the stability of thin films is important. However, the ability to detect and manipulate surface instabilities in thin films can also be advantageous for applications such as optoelectronics, biotechnology, nanolithography, and novel sensors and actuators. Numerous studies have focused on the complexity of surface instability in polymer thin films induced by external forces. In this study, we investigate the specific case of thin film instability in poly(4-vinyl pyridine) (P4VP) and poly(2-vinyl pyridine) (P2VP) thin films. The surface instability in P4VP and P2VP is based on the immersion approach in which the films are spin-coated onto a solid substrate and subsequently immersed in a seed solution containing HAuCl4 and its mixtures with K2CO3. The synergistic effect between polymer-solvent interactions and interfacial forces leads to the formation of wrinkles and craters on the surface of P4VP and P2VP thin films, respectively. The degree of surface wrinkling and cratering is strongly governed by various factors such as film thickness, amount of HAuCl4, and type of gold ions. Furthermore, the surface instability on the as-spun P4VP films during spin-coating is also investigated. Hierarchical patterns at macro-scale, micro-scale, and mesoscale are observed. The results provide valuable insights into the dynamics of surface instability in P4VP and P2VP thin films.
關鍵字(中) ★ 高分子
★ 表面不穩定
★ 聚(4-乙烯基吡啶)
★ 聚(2-乙烯基吡啶)
★ 四氯金酸
★ 介面作用力
關鍵字(英) ★ Polymer
★ Surface Instability
★ P4VP
★ P2VP
★ HAuCl4
★ Interfacial
論文目次 文摘要 i
ENGLISH ABSTRACT ii
TABLE OF CONTENTS iii
LIST OF FIGURES vi
LIST OF TABLES ix
CHAPTER I: INTRODUCTION 1
1.1 Stability of Thin Films 1
1.2 Introduction to Surface Instabilities 4
1.3 Surface Instabilities in Polymer Films and Application of Patterned Surfaces 8
1.3.1 Surface patterning driven by surface/interfacial energy 9
1.3.2 Surface patterning induced by the addition of external stimulus 11
1.3.3 Surface patterning due to the alteration of polymeric material in response to a changing in the ambient condition 12
1.4 Organization of this dissertation 14
References 16

CHAPTER II: MATERIALS AND INSTRUMENTATION 30
2.1 Materials 30
2.2 Instrumentation 31
2.3 Sample Preparation 32
2.4 Instrumental Analysis 36
References 46

CHAPTER III: SURFACE WRINKLING ON POLYMER FILMS 47
3.1 Introduction 47
3.2 Background 50
3.2.1 Fabrication of wrinkled polymer surfaces 50
3.2.2 Controlling the wrinkle parameters 56
3.2.3 Applications of wrinkled interfaces 57
3.3 Sample Preparation and Characterization 59
3.4 Results and Discussion 62
3.4.1 Characteristics of Gold Seed Solutions 62
3.4.2 Wrinkles formation controlled by various parameters 64
3.4.3 Mechanism of surface wrinkling for P4VP thin films 72
3.5 Summary 78
References 79

CHAPTER IV: BLISTERING AND CRATERING ON POLYMER FILMS 88
4.1 Introduction 88
4.2 Background 91
4.2.1 P2VP-based film instability 91
4.2.2 Particle-surface interaction in the polymer-substrate interface 93
4.2.3 Fluidic motion during evaporation of drying droplets 96
4.3 Sample Preparation and Characterization 99
4.4 Results and Discussion 102
4.4.1 The formation of craters from P2VP films by controlling various parameters 102
4.4.2 Mechanism of blistering and cratering for P2VP thin films 107
4.5 Summary 120
References 121

CHAPTER V: SURFACE INSTABILITY ON AS-SPUN P4VP FILMS 128
5.1 Introduction 128
5.2 Background 131
5.2.1 Parameters that control thin film deposition 131
5.2.2 Film instability induced by Bénard-Marangoni convection 134
5.3 Sample Preparation and Characterization 137
5.4 Results and Discussion 138
5.4.1 Macro-scale instability 138
5.4.2 Micro-scale instability 145
5.4.2 Meso-scale instability 151
5.5 Summary 157
5.6 References 158

APPENDIX 164
參考文獻 REFERENCES (1)

1. Qi, Y.; Nguyen, H.; Lim, K. S. E.; Wang, W.; Chen, W. Adsorptive Spin Coating to Study Thin-Film Stability in Both Wetting and Nonwetting Regimes. Langmuir 2019, 35 (21), 6922-6928.
2. Liu, Q.; Yan, Y.; Meng, L.; Zhang, Z.; Zhou, P. Influence of Airflow Disturbance on the Uniformity of Spin Coating Film Thickness on Large Area Rectangular Substrates. Coatings 2022, 12 (9), 1253.
3. Baeg, K. J.; Khim, D.; Kim, D. Y.; Jung, S. W.; Koo, J. B.; You, I. K.; Yan, H.; Facchetti, A.; Noh, Y. Y. High Speeds Complementary Integrated Circuits Fabricated with All‐Printed Polymeric Semiconductors. J. Polym Sci B Polym Phys. 2011, 49 (1), 62-67.
4. Khim, D.; Han, H.; Baeg, K. J.; Kim, J.; Kwak, S. W.; Kim, D. Y.; Noh, Y. Y. Simple Bar‐Coating Process for Large‐Area, High‐Performance Organic Field‐Effect Transistors and Ambipolar Complementary Integrated Circuits. Adv. Mater. 2013, 25 (31), 4302-4308.
5. Abdelsamie, M.; Zhao, K.; Niazi, M. R.; Chou, K. W.; Amassian, A. In-situ UV-Visible Absorption during Spin-Coating of Organic Semiconductors: A New Probe for Organic Electronics and Photovoltaics. J. Mater. Chem. C 2014, 2 (17), 3373-3381.
6. Liu, C.; Li, Y.; Lee, M. V.; Kumatani, A.; Tsukagoshi, K., Self-Assembly of Semiconductor/Insulator Interfaces in One-Step Spin-Coating: A Versatile Approach for Organic Field-Effect Transistors. Phys. Chem. Chem. Phys. 2013, 15 (21), 7917-7933.
7. Pichumani, M.; Bagheri, P.; Poduska, K. M.; González-Viñas, W.; Yethiraj, A. Dynamics, Crystallization and Structures in Colloid Spin Coating. Soft Matter 2013, 9 (12), 3220-3229.
8. Zhou, Z.; Mao, H.; Wang, X.; Sun, T.; Chang, Q.; Chen, Y.; Xiu, F.; Liu, Z.; Liu, J.; Huang, W. Transient and Flexible Polymer Memristors Utilizing Full-Solution Processed Polymer Nanocomposites. Nanoscale 2018, 10 (31), 14824-14829.
9. Wang, H.; Zhang, W.; Xu, C.; Bi, X.; Chen, B.; Yang, S. Efficiency Enhancement of Polymer Solar Cells by Applying Poly (Vinylpyrrolidone) as A Cathode Buffer Layer via Spin Coating or Self-Assembly. ACS Appl. Mater. & Interfaces 2013, 5 (1), 26-34.
10. Zhao, K.; Hu, H.; Spada, E.; Jagadamma, L. K.; Yan, B.; Abdelsamie, M.; Yang, Y.; Yu, L.; Munir, R.; Li, R. Highly Efficient Polymer Solar Cells with Printed Photoactive Layer: Rational Process Transfer from Spin-Coating. J. Mater. Chem. A 2016, 4 (41), 16036-16046.
11. Toolan, D. T.; Howse, J. R. Development of In Situ Studies of Spin Coated Polymer Films. J. Mater. Chem. C 2013, 1 (4), 603-616.
12. Meyerhofer, D. Characteristics of Resist Films Produced by Spinning. J. Appl. Phys. 1978, 49 (7), 3993-3997.
13. Emslie, A. G.; Bonner, F. T.; Peck, L. G. Flow of A Viscous Liquid on A Rotating Disk. J. Appl. Phys. 1958, 29 (5), 858-862.
14. Birnie III, D. P., Combined Flow and Evaporation during Spin Coating of Complex Solutions. J. Non-Cryst. Solids 1997, 218, 174-178.
15. Birnie III, D. P.; Manley, M. Combined flow and evaporation of fluid on a spinning disk. Physics of Fluids 1997, 9 (4), 870-875.
16. Mouhamad, Y.; Mokarian-Tabari, P.; Clarke, N.; Jones, R.; Geoghegan, M. Dynamics of Polymer Film Formation during Spin Coating. J. Appl. Phys. 2014, 116 (12), 123513.
17. Birnie, D. P. Rational Solvent Selection Strategies to Combat Striation Formation during Spin Coating of Thin Films. J. Mater Res. 2001, 16, 1145-1154.
18. Haas, D. E.; Quijada, J. N.; Picone, S. J.; Birnie III, D. P. In Effect of Solvent Evaporation Rate on Skin Formation during Spin Coating of Complex Solution. Sol-Gel Optics V 2000, 280-284.
19. Li, E. Q.; Vakarelski, I. U.; Chan, D. Y.; Thoroddsen, S. T. Stabilization of Thin Liquid Films by Repulsive Van Der Waals Force. Langmuir 2014, 30 (18), 5162-5169.
20. Hauxwell, F.; Ottewill, R., A Study of The Surface of Water by Hydrocarbon Adsorption. J. Colloid Interface Sci. 1970, 34 (4), 473-479.
21. Sabisky, E.; Anderson, C. Verification of The Lifshitz Theory of The Van Der Waals Potential using Liquid-Helium Films. Phys, Rev. A 1973, 7 (2), 790.
22. Pérez, E.; Schäffer, E.; Steiner, U. Spreading Dynamics of Polydimethylsiloxane Drops: Crossover from Laplace to Van Der Waals Spreading. J. Colloid Interface Sci. 2001, 234 (1), 178-193.
23. Li, B.; Zhao, H.-P.; Feng, X.-Q. Spontaneous Instability of Soft Thin Films on Curved Substrates due To Van Der Waals Interaction. J. Mech. Phys. Solids 2011, 59 (3), 610-624.
24. Zhang, W. W.; Lister, J. R. Similarity Solutions for Van Der Waals Rupture of A Thin Film on A Solid Substrate. Phys. Fluids 1999, 11 (9), 2454-2462.
25. Lin, Z.; Kerle, T.; Baker, S. M.; Hoagland, D. A.; Schäffer, E.; Steiner, U.; Russell, T. P. Electric Field Induced Instabilities at Liquid/Liquid Interfaces. J. Chem. Phys. 2001, 114 (5), 2377-2381.
26. Schaeffer, E.; Thurn-Albrecht, T.; Russell, T. P.; Steiner, U. Electrically Induced Structure Formation and Pattern Transfer. Nature 2000, 403 (6772), 874-877.
27. Reiter, G.; Sharma, A.; Casoli, A.; David, M.-O.; Khanna, R.; Auroy, P. Thin Film Instability Induced by Long-Range Forces. Langmuir 1999, 15 (7), 2551-2558.
28. Rickayzen, G.; Richmond, P. Thin Liquid Films: Fundamentals and Applications. Marcel Dekker New York: 1988, New York.
29. Derjaguin, B. V.; Churaev, N. V.; Muller, V. M.; Kisin, V. Surface forces. Springer: 1987.
30. Vrij, A.; Overbeek, J. T. G. Rupture of Thin Liquid Films due to Spontaneous Fluctuations in Thickness. J. Am. Chem. Soc. 1968, 90 (12), 3074-3078.
31. Sarma, R.; Mondal, P. K. Marangoni Instability in A Thin Film Heated from Below: Effect of Nonmonotonic Dependence of Surface Tension on Temperature. Phys. Rev. E 2018, 97 (4), 043105.
32. Yun, H. S.; Kim, D. H.; Kwon, H. G.; Choi, H. K. Centrifugal Force-Induced Alignment in the Self-Assembly of Block Copolymers. Macromolecules 2022, 55 (11), 4305-4312.
33. Ma, C.; Hu, S.; Dong, G.; Li, B. Fingering Instability of a Gravity-Driven Thin Film Flowing Down a Vertical Tube with Wall Slippage. Appl. Sci. 2019, 10 (1), 76.
34. Ledesma-Aguilar, R.; Hernández-Machado, A.; Pagonabarraga, I. Dynamics of Gravity Driven Three-Dimensional Thin Films on Hydrophilic− Hydrophobic Patterned Substrates. Langmuir 2010, 26 (5), 3292-3301.
35. Schäffer, E.; Thurn-Albrecht, T.; Russell, T. P.; Steiner, U. Electrohydrodynamic Instabilities in Polymer Films. Europhys. Lett. 2001, 53 (4), 518.
36. Yang, Q.; Liu, Y.; Jia, X.; Zhang, T.; Song, F. Numerical Study of The Thermocapillary Instability in A Thin Liquid–Air Film. Phys. Fluids 2022, 34 (9), 092117.
37. Schäffer, E.; Harkema, S.; Blossey, R.; Steiner, U. Temperature-Gradient–Induced Instability in Polymer Films. Europhys. Lett. 2002, 60 (2), 255.
38. Sharma, A. Equilibrium and Dynamics of Evaporating or Condensing Thin Fluid Domains: Thin Film Stability and Heterogeneous Nucleation. Langmuir 1998, 14 (17), 4915-4928.
39. Gjennestad, M. A.; Wilhelmsen, Ø. Thermodynamic Stability of Volatile Droplets and Thin Films Governed by Disjoining Pressure in Open and Closed Containers. Langmuir 2020, 36 (27), 7879-7893.
40. Brenner, H. Interfacial transport processes and rheology. Elsevier: 2013.
41. Grigor’ev, A.; Koromyslov, V.; Shiryaeva, S. Effect of Disjoining Pressure on The Instability of A Charged Thin Liquid Film on A Spherical Rigid Core. Fluid Dyn. 1999, 34, 87-90.
42. Dai, B.; Leal, L. G.; Redondo, A. Disjoining Pressure for Nonuniform Thin Films. Phys. Rev. E 2008, 78 (6), 061602.
43. Mendez, A. R.; Bogy, D. B. Lubricant Dewetting on The Slider’s Air-Bearing Surface in Hard Disk Drives. Tribology Lett. 2016, 61, 1-11.
44. Overbee, J.; Verwey, E. Theory of the Stability of Lyophobic Colloids: The Interaction of Sol Particles Having an Electric Double Layer. Elsevier, New York: 1948.
45. Nejati, I.; Dietzel, M.; Hardt, S. Conjugated Liquid Layers Driven by The Short-Wavelength Bénard–Marangoni Instability: Experiment and Numerical Simulation. J. Fluid Mech. 2015, 783, 46-71.
46. Bestehorn, M.; Pototsky, A.; Thiele, U. 3D Large Scale Marangoni Convection in Liquid Films. Eur. Phys. J. B. 2003, 33, 457-467.
47. Chapman, N.; Chapman, M.; Euler, W. B. Evolution of Surface Morphology of Spin-Coated Poly (Methyl Methacrylate) Thin Films. Polymers 2021, 13 (13), 2184.
48. Bassou, N.; Rharbi, Y. Role of Benard− Marangoni Instabilities During Solvent Evaporation in Polymer Surface Corrugations. Langmuir 2009, 25 (1), 624-632.
49. Chiang, K.-T. Effect of A Non-Uniform Basic Temperature Gradient on The Onset of Bénard-Marangoni Convection: Stationary and Oscillatory Analyses. Int. Commun. Heat Mass Transf. 2005, 32 (1-2), 192-203.
50. Paronyan, T. M.; Pigos, E. M.; Chen, G.; Harutyunyan, A. R. Formation of Ripples in Graphene as A Result of Interfacial Instabilities. ACS Nano 2011, 5 (12), 9619-9627.
51. Zhu, J.-L.; Shi, W.-Y.; Feng, L. Bénard-Marangoni Instability in Sessile Droplet Evaporating at Constant Contact Angle Mode on Heated Substrate. Int. J. Heat Mass Transf. 2019, 134, 784-795.
52. Wang, T.-S.; Shi, W.-Y. Influence of Substrate Temperature on Marangoni Convection Instabilities in A Sessile Droplet Evaporating at Constant Contact Line Mode. Int. J. Heat Mass Transf. 2019, 131, 1270-1278.
53. Wang, H.; Wang, Z.; Huang, L.; Mitra, A.; Yan, Y. Surface Patterned Porous Films by Convection-Assisted Dynamic Self-Assembly of Zeolite Nanoparticles. Langmuir 2001, 17 (9), 2572-2574.
54. Uchiyama, H.; Matsui, T.; Kozuka, H. Spontaneous Pattern Formation Induced by Bénard–Marangoni Convection for Sol–Gel-Derived Titania Dip-Coating Films: Effect of Co-Solvents with A High Surface Tension and Low Volatility. Langmuir 2015, 31 (45), 12497-12504.
55. Sobac, B.; Colinet, P.; Pauchard, L. Influence of Bénard–Marangoni Instability on The Morphology of Drying Colloidal Films. Soft Matter 2019, 15 (11), 2381-2390.
56. Efstratiou, M.; Christy, J. R.; Bonn, D.; Sefiane, K. Transition from Dendritic to Cell-like Crystalline Structures in Drying Droplets of Fetal Bovine Serum under the Influence of Temperature. Langmuir 2022, 38 (14), 4321-4331.
57. Prashanth, K.; Eckert, J. Formation of Metastable Cellular Microstructures in Selective Laser Melted Alloys. J. Alloys Compd. 2017, 707, 27-34.
58. Fan, Y.; Fang, J.; Chang, X.; Tang, M.-C.; Barrit, D.; Xu, Z.; Jiang, Z.; Wen, J.; Zhao, H.; Niu, T. Scalable Ambient Fabrication of High-Performance CsPbI2Br Solar Cells. Joule 2019, 3 (10), 2485-2502.
59. Zhang, Z.; Wen, L.; Jiang, L. Bioinspired Smart Asymmetric Nanochannel Membranes. Chem. Soc. Rev. 2018, 47 (2), 322-356.
60. Amar, M. B.; Ciarletta, P. Swelling Instability of Surface-Attached Gels as A Model of Soft Tissue Growth Under Geometric Constraints. J. Mech. Phys. Solids 2010, 58 (7), 935-954.
61. Dunstan, J.; Lee, K. J.; Hwang, Y.; Park, S. F.; Goldstein, R. E. Evaporation-Driven Convective Flows in Suspensions of Nonmotile Bacteria. Phys. Rev. Fluids 2018, 3 (12), 123102.
62. Lu, Y.; Fan, D.; Wang, Y.; Xu, H.; Lu, C.; Yang, X. Surface Patterning of Two-Dimensional Nanostructure-Embedded Photothermal Hydrogels for High-Yield Solar Steam Generation. ACS Nano 2021, 15 (6), 10366-10376.
63. Gonuguntla, M.; Sharma, A. Polymer Patterns in Evaporating Droplets on Dissolving Substrates. Langmuir 2004, 20 (8), 3456-3463.
64. Giorgiutti-Dauphiné, F.; Pauchard, L. Drying Drops: Drying Drops Containing Solutes: from Hydrodynamical to Mechanical Instabilities. Eur. Phy.s J. E 2018, 41, 1-15.
65. Xue, L.; Zhang, J.; Han, Y. Phase Separation Induced Ordered Patterns in Thin Polymer Blend Films. Prog. Polym. Sci. 2012, 37 (4), 564-594.
66. Li, Y.; Diddens, C.; Lv, P.; Wijshoff, H.; Versluis, M.; Lohse, D. Gravitational Effect in Evaporating Binary Microdroplets. Phys. Rev. Lett. 2019, 122 (11), 114501.
67. Uchiyama, H.; Mantani, Y.; Kozuka, H. Spontaneous Formation of Linearly Arranged Microcraters on Sol–Gel-Derived Silica–Poly (Vinylpyrrolidone) Hybrid Films Induced by Bénard–Marangoni Convection. Langmuir 2012, 28 (27), 10177-10182.
68. Daubersies, L.; Salmon, J.-B. Evaporation of Solutions and Colloidal Dispersions in Confined Droplets. Phys. Rev. E 2011, 84 (3), 031406.
69. Carrithers, A. D.; Brown, M. J.; Rashed, M. Z.; Islam, S.; Velev, O. D.; Williams, S. J. Multiscale Self-Assembly of Distinctive Weblike Structures from Evaporated Drops of Dilute American Whiskeys. ACS Nano 2020, 14 (5), 5417-5425.
70. Thokchom, A. K.; Swaminathan, R.; Singh, A. Fluid Flow and Particle Dynamics Inside An Evaporating Droplet Containing Live Bacteria Displaying Chemotaxis. Langmuir 2014, 30 (41), 12144-12153.
71. Joseph, A.; Mathew, S. Ferrofluids: Synthetic Strategies, Stabilization, Physicochemical Features, Characterization, and Applications. Chem. Plus. Chem 2014, 79 (10), 1382-1420.
72. Fedorets, A. A.; Shcherbakov, D. V.; Dombrovsky, L. A.; Bormashenko, E.; Nosonovsky, M. Impact of Surfactants on The Formation and Properties of Droplet Clusters. Langmuir 2020, 36 (37), 11154-11160.
73. Jiang, X.; Deng, Z.; Wu, S.; Liu, X. Studying on The Marangoni Effect in Double Emulsions with A Hybrid Multi-Relaxation Time Lattice Boltzmann Method-Finite Difference Method. Phys.Fluids 2023.
74. Kabova, Y.; Kuznetsov, V.; Kabov, O.; Gambaryan-Roisman, T.; Stephan, P. Evaporation f A Thin Viscous Liquid Film Sheared by Gas in A Microchannel. Int. J. Heat Mass Transf. 2014, 68, 527-541.
75. Mejia, L.; Zhu, P.; Hyman, J. D.; Mohanty, K. K.; Balhoff, M. T. Coreflood on A Chip: Core-Scale Micromodels for Subsurface Applications. Fuel 2020, 281, 118716.
76. Butzhammer, L.; Köhler, W. Thermocapillary and Thermosolutal Marangoni Convection of Ethanol and Ethanol–Water Mixtures i A Microfluidic Device. Microfluid. Nanofluidics 2017, 21, 1-10.
77. Abolhosseini, P.; Khosravi, M.; Rostami, B.; Masoudi, M. Experimental and Analytical Investigation on Effects of Different Mechanisms on Recovery of Bypassed Oil During Immiscible Methane Injection. Saint Petersburg 2018, (1), 1-5.
78. Rodríguez-Hernández, J. Wrinkled Interfaces: Taking Advantage of Surface Instabilities to Pattern Polymer Surfaces. Prog. Polym. Sci. 2015, 42, 1-41.
79. Chung, J. Y.; Nolte, A. J.; Stafford, C. M. Surface Wrinkling: A Versatile Platform for Measuring Thin‐Film Properties. Adv. Mater. 2011, 23 (3), 349-368.
80. Yang, S.; Khare, K.; Lin, P. C. Harnessing Surface Wrinkle Patterns in Soft Matter. Adv. Funct. Mater. 2010, 20 (16), 2550-2564.
81. Reiter, G.; Hamieh, M.; Damman, P.; Sclavons, S.; Gabriele, S.; Vilmin, T.; Raphaël, E. Residual Stresses in Thin Polymer Films Cause Rupture and Dominate Early Stages of Dewetting. Nature Mater. 2005, 4 (10), 754-758.
82. Chung, J. Y.; Chastek, T. Q.; Fasolka, M. J.; Ro, H. W.; Stafford, C. M. Quantifying Residual Stress in Nanoscale Thin Polymer Films via Surface Wrinkling. ACS Nano 2009, 3 (4), 844-852.
83. Zhao, X.; Wang, J.; Huang, J.; Li, L.; Liu, E.; Zhao, J.; Li, Q.; Zhang, X.; Lu, C. Path-Guided Hierarchical Surface Relief Gratings on Azo-Films Induced by Polarized Light Illumination through Surface-Wrinkling Phase Mask. Langmuir 2020, 36 (11), 2837-2846.
84. Izawa, H. Preparation of Biobased Wrinkled Surfaces via Lignification-Mimetic Reactions And Drying: A New Approach for Developing Surface Wrinkling. Polym. J. 2017, 49 (11), 759-765.
85. Fang, Q.; Ye, F.; Yang, X. Hierarchical Morphology of Polymer Blend Films Induced by Convection-Driven Solvent Evaporation. Langmuir 2018, 34 (19), 5551-5557.
86. Li, Y.; Salvator, V.; Wijshoff, H.; Versluis, M.; Lohse, D. Evaporation-Induced Crystallization of Surfactants in Sessile Multicomponent Droplets. Langmuir 2020, 36 (26), 7545-7552.
87. Reiter, G. Unstable Thin Polymer Films: Rupture and Dewetting Processes. Langmuir 1993, 9 (5), 1344-1351.
88. Xie, R.; Karim, A.; Douglas, J. F.; Han, C. C.; Weiss, R. A. Spinodal Dewetting of Thin Polymer Films. Phys. Rev. Lett. 1998, 81 (6), 1251.
89. Sharma, A.; Reiter, G., Instability of thin polymer films on coated substrates: rupture, dewetting, and drop formation. J. Colloid Interface Sci. 1996, 178 (2), 383-399.
90. Müller-Buschbaum, P.; Bauer, E.; Wunnicke, O.; Stamm, M., The control of thin film morphology by the interplay of dewetting, phase separation and microphase separation. J. Phys. Condens. Matter. 2005, 17 (9), S363.
91. González-Henríquez, C.; Rodríguez-Hernández, J. Wrinkled Polymer Surfaces: Strategies, Methods and Applications. Springer: 2019.
92. Vital, A.; Vayer, M.; Tillocher, T.; Dussart, R.; Boufnichel, M.; Sinturel, C. Morphology Control in Thin Films of PS: PLA Homopolymer Blends by Dip-Coating Deposition. Appl. Surf. Sci. 2017, 393, 127-133.
93. Krausch, G. Surface Induced Self Assembly in Thin Polymer Films. Mater. Sci. Eng.: R: Rep.1995, 14 (1-2), v-94.
94. Mrđenović, D. a.; Abbott, D.; Mougel, V.; Su, W.; Kumar, N.; Zenobi, R. Visualizing Surface Phase Separation in PS-PMMA Polymer Blends at the Nanoscale. ACS Appl. Mater. Interfaces 2022, 14 (21), 24938-24945.
95. Cai, Y.; Newby, B.-m. Z. Dewetting of Polystyrene Thin Films on Poly (Ethylene Glycol)-Modified Surfaces as A Simple Approach for Patterning Proteins. Langmuir 2008, 24 (10), 5202-5208.
96. Gentili, D.; Foschi, G.; Valle, F.; Cavallini, M.; Biscarini, F. Applications of Dewetting In Micro and Nanotechnology. Chem. Soc. Rev. 2012, 41 (12), 4430-4443.
97. Yin, J.; Lu, C. Hierarchical Surface Wrinkles Directed by Wrinkled Templates. Soft Matter 2012, 8 (24), 6528-6534.
98. Wang, D.; Liu, H.; Liu, F.; Ma, G.; Yang, J.; Gu, X.; Zhou, M.; Chen, Z. Phase-Separation-Induced Porous Lithiophilic Polymer Coating for High-Efficiency Lithium Metal Batteries. Nano Lett. 2021, 21 (11), 4757-4764.
99. Zoumpouli, G. A.; Yiantsios, S. G. Hydrodynamic Effects on Phase Separation Morphologies in Evaporating Thin Films of Polymer Solutions.Phys. Fluids 2016, 28 (8), 082108.
100. Sinturel, C.; Vayer, M.; Morris, M.; Hillmyer, M. A. Solvent Vapor Annealing of Block Polymer Thin Films. Macromolecules 2013, 46 (14), 5399-5415.
101. Huang, C.; Zhu, Y.; Man, X. Block Copolymer Thin Films. Phys. Rep. 2021, 932, 1-36.
102. Matsunaga, K.; Kukai, W.; Ishizaki, M.; Kurihara, M.; Yamamoto, S.; Mitsuishi, M.; Yabu, H.; Nagano, S.; Matsui, J. Formation of Perpendicularly Aligned Sub-10 nm Nanocylinders in Poly (N-dodecylacrylamide-b-ethylene glycol) Block Copolymer Films by Hierarchical Phase Separation. Macromolecules 2020, 53 (21), 9601-9610.
103. Mei, S.; Wang, L.; Feng, X.; Jin, Z. Swelling of Block Copolymer Nanoparticles: A Process Combining Deformation and Phase Separation. Langmuir 2013, 29 (14), 4640-4646.
104. Zhang, J.; Yu, X.; Yang, P.; Peng, J.; Luo, C.; Huang, W.; Han, Y. Microphase Separation of Block Copolymer Thin Films. Macromol. Rapid Commun. 2010, 31 (7), 591-608.
105. Prabhu, V. M. Interfacial Tension in Polyelectrolyte Systems Exhibiting Associative Liquid–Liquid Phase Separation. Curr. Opin. Colloid Interface Sci. 2021, 53, 101422.
106. Liu, C.; Lafdi, K. Self-Assembly and Surface Tension Induced Fractal Conductive Network in Ternary Polymer System. ACS Appl. Polym. Mater. 2019, 1 (3), 493-499.
107. Bartelt, J. A.; Douglas, J. D.; Mateker, W. R.; Labban, A. E.; Tassone, C. J.; Toney, M. F.; Fréchet, J. M.; Beaujuge, P. M.; McGehee, M. D. Controlling Solution‐Phase Polymer Aggregation with Molecular Weight and Solvent Additives to Optimize Polymer‐Fullerene Bulk Heterojunction Solar Cells. Adv. Energy Mater. 2014, 4 (9), 1301733.
108. Zhou, N.; Dudnik, A. S.; Li, T. I.; Manley, E. F.; Aldrich, T. J.; Guo, P.; Liao, H.-C.; Chen, Z.; Chen, L. X.; Chang, R. P. All-Polymer Solar Cell Performance Optimized via Systematic Molecular Weight Tuning of Both Donor and Acceptor Polymers. J. Am. Chem. Soc. 2016, 138 (4), 1240-1251.
109. Ferrell, W. H.; Kushner, D. I.; Hickner, M. A. Investigation of Polymer–Solvent Interactions in Poly (Styrene Sulfonate) Thin Films. J. Polym. Sci. B: Polym. Phys.2017, 55 (18), 1365-1372.
110. Huraux, K.; Narita, T.; Frétigny, C.; Lequeux, F. Solution Drying and Phase Separation Morphology of Polyacrylamide/Poly (Ethylene Glycol)/Water System. Macromolecules 2007, 40 (23), 8336-8341.
111. Kim, J. F.; Kim, J. H.; Lee, Y. M.; Drioli, E. Thermally Induced Phase Separation and Electrospinning Methods for Emerging Membrane Applications: A Review. AIChE J. 2016, 62 (2), 461-490.
112. Garbern, J. C.; Hoffman, A. S.; Stayton, P. S. Injectable Ph-and Temperature-Responsive Poly (N-Isopropylacrylamide-Co-Propylacrylic Acid) Copolymers for Delivery Of Angiogenic Growth Factors. Biomacromolecules 2010, 11 (7), 1833-1839.
113. He, Z.; Zhang, Z.; Bi, S. Polyacrylate Polymer Assisted Crystallization: Improved Charge Transport And Performance Consistency For Solution-Processable Small-Molecule Semiconductor Based Organic Thin Film Transistors. J. Sci.: Adv. Mater. Devices. 2019, 4 (3), 467-472.
114. Xu, J.; Wang, S.; Wang, G.-J. N.; Zhu, C.; Luo, S.; Jin, L.; Gu, X.; Chen, S.; Feig, V. R.; To, J. W. Highly Stretchable Polymer Semiconductor Films Through the Nanoconfinement Effect. Science 2017, 355 (6320), 59-64.
115. Duan, S.; Gao, X.; Wang, Y.; Yang, F.; Chen, M.; Zhang, X.; Ren, X.; Hu, W. Scalable Fabrication of Highly Crystalline Organic Semiconductor Thin Film by Channel‐Restricted Screen Printing toward The Low‐Cost Fabrication of High‐Performance Transistor Arrays. Adv. Mater. 2019, 31 (16), 1807975.
116. Cho, S. Y.; Ko, J. M.; Jung, J.-Y.; Lee, J. Y.; Choi, D. H.; Lee, C. High-Performance Organic Thin Film Transistors Based on Inkjet-Printed Polymer/TIPS Pentacene Blends. Org. Electron. 2012, 13 (8), 1329-1339.
117. Treat, N. D.; Chabinyc, M. L. Phase Separation in Bulk Heterojunctions of Semiconducting Polymers and Fullerenes for Photovoltaics. Annu. Rev. Phys. Chem. 2014, 65, 59-81.
118. Kim, M.; Lee, J.; Jo, S. B.; Sin, D. H.; Ko, H.; Lee, H.; Lee, S. G.; Cho, K. Critical Factors Governing Vertical Phase Separation in Polymer–PCBM Blend Films for Organic Solar Cells. J. Mater. Chem. A 2016, 4 (40), 15522-15535.
119. Kang, H.; Uddin, M. A.; Lee, C.; Kim, K.-H.; Nguyen, T. L.; Lee, W.; Li, Y.; Wang, C.; Woo, H. Y.; Kim, B. J. Determining The Role of Polymer Molecular Weight for High-Performance All-Polymer Solar Cells: Its Effect on Polymer Aggregation and Phase Separation. J. Am. Chem. Soc. 2015, 137 (6), 2359-2365.
120. Reiter, G. Dewetting of Thin Polymer Films. Phys. Rev. Lett. 1992, 68 (1), 75.
121. Sehgal, A.; Bandyopadhyay, D.; Kargupta, K.; Sharma, A.; Karim, A. From Finite-Amplitude Equilibrium Structures to Dewetting in Thin Polymer Films on Chemically Patterned Substrates. Soft Matter 2012, 8 (40), 10394-10402.
122. Verma, A.; Sharma, A. Self-Organized Nano-Lens Arrays by Intensified Dewetting of Electron Beam Modified Polymer Thin-Films. Soft Matter 2011, 7 (23), 11119-11124.
123. Xue, L.; Han, Y. Pattern Formation by Dewetting of Polymer Thin Film. Prog. Polym. Sci.2011, 36 (2), 269-293.
124. Roy, S.; Bandyopadhyay, D.; Karim, A.; Mukherjee, R. Interplay of Substrate Surface Energy and Nanoparticle Concentration in Suppressing Polymer Thin Film Dewetting. Macromolecules 2015, 48 (2), 373-382.
125. Rahman, M. U.; Xi, Y.; Li, H.; Chen, F.; Liu, D.; Wei, J. Dynamics and Structure Formation of Confined Polymer Thin Films Supported on Solid Substrates. Polymers 2021, 13 (10), 1621.
126. Mukherjee, R.; Sharma, A. Instability, Self-Organization and Pattern Formation in Thin Soft Films. Soft Matter 2015, 11 (45), 8717-8740.
127. Sachan, P.; Kulkarni, M.; Sharma, A. Hierarchical Micro/Nano Structures by Combined Self-Organized Dewetting and Photopatterning of Photoresist Thin Films. Langmuir 2015, 31 (45), 12505-12511.
128. Golany, Z.; Weisbord, I.; Abo-Jabal, M.; Manor, O.; Segal-Peretz, T. Polymer Dewetting in Solvent-Non-Solvent Environment-New Insights on Dynamics and Lithography-Free Patterning. J. Colloid Interface Sci. 2021, 596, 267-277.
129. Ghezzi, M.; Thickett, S. C.; Neto, C. Early And Intermediate Stages of Guided Dewetting in Polystyrene Thin Films. Langmuir 2012, 28 (27), 10147-10151.
130. Verma, R.; Sharma, A. Defect Sensitivity in Instability and Dewetting of Thin Liquid Films: Two Regimes of Spinodal Dewetting. Ind. Eng. Chem. Res. 2007, 46 (10), 3108-3118.
131. Luan, S.; Cheng, Z.; Xing, R.; Wang, Z.; Yu, X.; Han, Y. Patterning Organic Luminescent Materials by Solvent-Assisted Dewetting and Polymer-Bonding Lithography. American Institute of Physics: 2005.
132. Lenz, P.; Lipowsky, R. Morphological Transitions of Wetting Layers on Structured Surfaces. Phys. Rev. Lett. 1998, 80 (9), 1920.
133. Gau, H.; Herminghaus, S.; Lenz, P.; Lipowsky, R. Liquid Morphologies on Structured Surfaces: From Microchannels to Microchips. Science 1999, 283 (5398), 46-49.
134. Kumar, A.; Whitesides, G. M. Patterned Condensation Figures as Optical Diffraction Gratings. Science 1994, 263 (5143), 60-62.
135. Kargupta, K.; Sharma, A. Mesopatterning of Thin Liquid Films by Templating on Chemically Patterned Complex Substrates. Langmuir 2003, 19 (12), 5153-5163.
136. Kargupta, K.; Sharma, A. Templating of Thin Films Induced by Dewetting on Patterned Surfaces. Phys. Rev. Lett. 2001, 86 (20), 4536.
137. Xing, R.; Luo, C.; Wang, Z.; Han, Y. Dewetting of Polymethyl Methacrylate on The Patterned Elastomer Substrate by Solvent Vapor Treatment. Polymer 2007, 48 (12), 3574-3583.
138. Kargupta, K.; Sharma, A. Dewetting of Thin Films on Periodic Physically and Chemically Patterned Surfaces. Langmuir 2002, 18 (5), 1893-1903.
139. McNeill, C. R.; Watts, B.; Thomsen, L.; Belcher, W. J.; Greenham, N. C.; Dastoor, P. C. Nanoscale Quantitative Chemical Mapping of Conjugated Polymer Blends. Nano Lett. 2006, 6 (6), 1202-1206.
140. Wei, J. H.; Coffey, D. C.; Ginger, D. S. Nucleating Pattern Formation in Spin-Coated Polymer Blend Films with Nanoscale Surface Templates. J. Phys. Chem. B.2006, 110 (48), 24324-24330.
141. Park, L. Y.; Munro, A. M.; Ginger, D. S. Controlling Film Morphology in Conjugated Polymer: Fullerene Blends with Surface Patterning. J. Am. Chem. Soc. 2008, 130 (47), 15916-15926.
142. Fang, L.; Wei, M.; Shang, Y.; Kazmer, D.; Barry, C.; Mead, J. Precise Pattern Replication of Polymer Blends into Nonuniform Geometries via Reducing Interfacial Tension Between Two Polymers. Langmuir 2012, 28 (27), 10238-10245.
143. Wei, M.; Fang, L.; Lee, J.; Somu, S.; Xiong, X.; Barry, C.; Busnaina, A.; Mead, J. Directed Assembly of Polymer Blends using Nanopatterned Templates. Adv. Mater. 2009, 21 (7), 794-798.
144. Goldberg‐Oppenheimer, P.; Mahajan, S.; Steiner, U. Hierarchical Electrohydrodynamic Structures for Surface‐Enhanced Raman Scattering. Adv. Mater. 2012, 24 (23), OP175-OP180.
145. Goldberg-Oppenheimer, P.; Kabra, D.; Vignolini, S.; Hüttner, S.; Sommer, M.; Neumann, K.; Thelakkat, M.; Steiner, U. Hierarchical Orientation of Crystallinity By Block-Copolymer Patterning and Alignment in An Electric Field. Chem. Mater. 2013, 25 (7), 1063-1070.
146. Goldberg‐Oppenheimer, P.; Steiner, U. Rapid Electrohydrodynamic Lithography Using Low‐Viscosity Polymers. Small 2010, 6 (11), 1248-1254.
147. Wu, N.; Russel, W. B. Micro-And Nano-Patterns Created via Electrohydrodynamic Instabilities. Nano Today 2009, 4 (2), 180-192.
148. Mahajan, S.; Hutter, T.; Steiner, U.; Goldberg Oppenheimer, P. Tunable Microstructured Surface-Enhanced Raman Scattering Substrates via Electrohydrodynamic Lithography. J. Phys. Chem. Lett. 2013, 4 (23), 4153-4159.
149. Wu, S.-K.; Mo, T.-S.; Lin, J.-D.; Huang, S.-Y.; Huang, C.-Y.; Yeh, H.-C.; Chen, L.-J.; Lee, C.-R. Electrohydrodynamics-Induced Abnormal Electro-Optic Characteristics in a Polymer-Dispersed Liquid Crystal Film. Crystals 2017, 7 (7), 227.
150. Luo, M.; Epps III, T. H. Directed Block Copolymer Thin Film Self-Assembly: Emerging Trends in Nanopattern Fabrication. Macromolecules 2013, 46 (19), 7567-7579.
151. Chen, C. M.; Yang, S. Wrinkling Instabilities in Polymer Films and Their Applications. Polym. Int. 2012, 61 (7), 1041-1047.
152. Stuart, M. A. C.; Huck, W. T.; Genzer, J.; Müller, M.; Ober, C.; Stamm, M.; Sukhorukov, G. B.; Szleifer, I.; Tsukruk, V. V.; Urban, M. Emerging Applications of Stimuli-Responsive Polymer Materials. Nat. Mater 2010, 9 (2), 101-113.
153. Vasilev, K. Nanoengineered Plasma Polymer Films for Biomaterial Applications. Plasma Chem. Plasma Process 2014, 34, 545-558.
154. Schäffer, E.; Harkema, S.; Roerdink, M.; Blossey, R.; Steiner, U. Thermomechanical Lithography: Pattern Replication using A Temperature Gradient Driven Instability. Adv. Mater. 2003, 15 (6), 514-517.
155. Douaud, A.; Messaddeq, S. H.; Messaddeq, Y. Microstructure Formation in Chalcogenide Thin Films Assisted by Thermal Dewetting. J. Mater. Sci.: Mater. Electron. 2017, 28, 6989-6999.
156. Vohra, V.; Yunus, S.; Attout, A.; Giovanella, U.; Scavia, G.; Tubino, R.; Botta, C.; Bolognesi, A. Bifunctional Microstructured Films and Surfaces Obtained by Soft Lithography from Breath Figure Arrays. Soft Matter 2009, 5 (8), 1656-1661.
157. Muñoz-Bonilla, A.; Fernández-García, M.; Rodríguez-Hernández, J. Towards Hierarchically Ordered Functional Porous Polymeric Surfaces Prepared by The Breath Figures Approach. Prog. Polym. Sci.2014, 39 (3), 510-554.
158. Cong, H.; Wang, J.; Yu, B.; Tang, J. Preparation of A Highly Permeable Ordered Porous Microfiltration Membrane of Brominated Poly (Phenylene Oxide) on An Ice Substrate by The Breath Figure Method. Soft Matter 2012, 8 (34), 8835-8839.
159. Nishikawa, T.; Nishida, J.; Ookura, R.; Nishimura, S.-I.; Wada, S.; Karino, T.; Shimomura, M. Honeycomb-Patterned Thin Films of Amphiphilic Polymers as Cell Culture Substrates. Mater. Sci. Eng. C 1999, 8, 495-500.
160. Calejo, M. T.; Ilmarinen, T.; Skottman, H.; Kellomäki, M. Breath Figures in Tissue Engineering and Drug Delivery: State-Of-The-Art and Future Perspectives. Acta Biomater. 2018, 66, 44-66.
161. Madej, W.; Budkowski, A.; Raczkowska, J.; Rysz, J. Breath Figures in Polymer and Polymer Blend Films Spin-Coated in Dry and Humid Ambience. Langmuir 2008, 24 (7), 3517-3524.
162. Liu, H.; Pang, B.; Zhang, K. Breath Figure Templated Self-Assembly of Surface-Acylated Cellulose Nanowhiskers Confined as Honeycomb Films. Cellulose 2021, 28, 10939-10951.
163. Escalé, P.; Rubatat, L.; Billon, L.; Save, M. Recent Advances in Honeycomb-Structured Porous Polymer Films Prepared via Breath Figures. Eur. Polym. J. 2012, 48 (6), 1001-1025.
164. Wu, B.; Zhang, W.; Gao, N.; Zhou, M.; Liang, Y.; Wang, Y.; Li, F.; Li, G. Poly (Ionic Liquid)-Based Breath Figure Films: A New Kind of Honeycomb Porous Films with Great Extendable Capability. Sci. Rep. 2017, 7 (1), 13973.
165. Siretanu, I.; Chapel, J. P.; Drummond, C. Water−Ions Induced Nanostructuration of Hydrophobic Polymer Surfaces. ACS Nano 2011, 5 (4), 2939-2947.
166. Barad, H.-N.; Kwon, H.; Alarcón-Correa, M.; Fischer, P. Large Area Patterning of Nanoparticles and Nanostructures: Current Status and Future Prospects. ACS Nano 2021, 15 (4), 5861-5875.
167. Tanaka, K.-i. Surface Nano-Structuring by Adsorption and Chemical Reactions. Materials 2010, 3 (9), 4518-4549.
168. Tarábková, H.; Janda, P. Nanobubble Assisted Nanopatterning Utilized for Ex Situ Identification of Surface Nanobubbles. J. Phys. Condens. Matter 2013, 25 (18), 184001.
169. Darwich, S.; Mougin, K.; Vidal, L.; Gnecco, E.; Haidara, H. Nanobubble and Nanodroplet Template Growth of Particle Nanorings Versus Nanoholes in Drying Nanofluids and Polymer Films. Nanoscale 2011, 3 (3), 1211-1217.
170. Wang, Y.; Bhushan, B.; Zhao, X. Nanoindents Produced by Nanobubbles on Ultrathin Polystyrene Films in Water. Nanotechnology 2008, 20 (4), 045301.
171. Duan, L.; Yang, L.; Jin, J.; Yang, F.; Liu, D.; Hu, K.; Wang, Q.; Yue, Y.; Gu, N. Micro/Nano-Bubble-Assisted Ultrasound to Enhance The EPR Effect and Potential Theranostic Applications. Theranostics 2020, 10 (2), 462.


REFERENCES (2)

1. Sanders, W. C. Atomic Force Microscopy: Fundamental Concepts and Laboratory Investigations. CRC Press: 2019.
2. Alunda, B. O.; Lee, Y. J. Cantilever-Based Sensors for High Speed Atomic Force Microscopy. Sensors 2020, 20 (17), 4784.
3. Bowen, W. R.; Doneva, T. A. Artefacts in AFM Studies of Membranes: Correcting Pore Images using Fast Fourier Transform Filtering. J. Membr. Sci 2000, 171 (1), 141-147.
4. Sharma, S. K.; Verma, D. S.; Khan, L. U.; Kumar, S.; Khan, S. B. Handbook of Materials Characterization. Springer: 2018.
5. Egerton, R. F. Physical Principles of Electron Microscopy. Springer: 2005; Vol. 56.
6. Ul-Hamid, A. A Beginners′ Guide to Scanning Electron Microscopy. Springer: 2018; Vol. 1.
7. Murphy, D. B.; Davidson, M. W. Fundamentals of Light Microscopy and Electronic Imaging. John Wiley & Sons: 2012.
8. Toledo, M. UV/VIS Spectrophotometry: Fundamentals and Applications. IOP Conf. Ser.: Mater. Sci. Eng. 2019, 515, 012077.
9. Akash, M. S. H.; Rehman, K. Essentials Of Pharmaceutical Analysis. Springer: 2020.
10. Picollo, M.; Aceto, M.; Vitorino, T. UV-Vis Spectroscopy. Phys. Sci. Rev. 2018, 4 (4), 20180008.
11. Perkampus, H.-H. UV-VIS Spectroscopy and its Applications. Springer Science & Business Media: 2013.


REFERENCES (3)

1. Yang, S.; Khare, K.; Lin, P. C. Harnessing Surface Wrinkle Patterns in Soft Matter. Adv. Funct. Mater. 2010, 20 (16), 2550-2564.
2. Chung, J. Y.; Nolte, A. J.; Stafford, C. M. Surface Wrinkling: A Versatile Platform for Measuring Thin‐Film Properties. Adv. Mater. 2011, 23 (3), 349-368.
3. Jung, W.-B.; Cho, K. M.; Lee, W.-K.; Odom, T. W.; Jung, H.-T. Universal Method for Creating Hierarchical Wrinkles on Thin-Film Surfaces. ACS Appl. Mater. Interfaces 2018, 10 (1), 1347-1355.
4. Yu, X.; Wang, Y.; Li, L.; Li, H.; Shang, Y. Soft and Wrinkled Carbon Membranes Derived from Petals for Flexible Supercapacitors. Sci. Rep. 2017, 7 (1), 1-8.
5. Cantarella, G.; Vogt, C.; Hopf, R.; Münzenrieder, N.; Andrianakis, P.; Petti, L.; Daus, A.; Knobelspies, S.; Büthe, L.; Tröster, G. Buckled Thin-Film Transistors and Circuits on Soft Elastomers for Stretchable Electronics. ACS Appl. Mater. Interfaces 2017, 9 (34), 28750-28757.
6. Chen, C.; Airoldi, C. A.; Lugo, C. A.; Bay, R. K.; Glover, B. J.; Crosby, A. J. Flower Inspiration: Broad‐Angle Structural Color Through Tunable Hierarchical Wrinkles in Thin Film Multilayers. Adv. Funct. Mater. 2021, 31 (5), 2006256.
7. González-Henríquez, C.; Rodríguez-Hernández, J. Wrinkled Polymer Surfaces: Strategies, Methods and Applications. Springer: 2019.
8. Rodríguez-Hernández, J. Wrinkled Interfaces: Taking Advantage of Surface Instabilities to Pattern Polymer Surfaces. Prog. Polym. Sci.2015, 42, 1-41.
9. Li, Y. Reversible Wrinkles of Monolayer Graphene on A Polymer Substrate: Toward Stretchable and Flexible Electronics. Soft Matter 2016, 12 (13), 3202-3213.
10. Yan, Z.; Wang, B.; Wang, K. Stretchability and Compressibility of A Novel Layout Design for Flexible Electronics Based on Bended Wrinkle Geometries. Compos. B. Eng. 2019, 166, 65-73.
11. Hou, H.; Yin, J.; Jiang, X. Smart Patterned Surface with Dynamic Wrinkles. Acc. Chem. Res. 2019, 52 (4), 1025-1035.
12. Wu, K.; Sun, Y.; Yuan, H.; Zhang, J.; Liu, G.; Sun, J. Harnessing Dynamic Wrinkling Surfaces for Smart Displays. Nano Lett. 2020, 20 (6), 4129-4135.
13. Li, Y.; John, J.; Kolewe, K. W.; Schiffman, J. D.; Carter, K. R. Scaling Up Nature: Large Area Flexible Biomimetic Surfaces. ACS Appl. Mater. Interfaces 2015, 7 (42), 23439-23444.
14. Xie, M.; Xu, F.; Zhang, L.; Yin, J.; Jiang, X. Reversible Surface Dual-Pattern with Simultaneously Dynamic Wrinkled Topography and Fluorescence. ACS Macro Lett. 2018, 7 (5), 540-545.
15. Yang, Y.; Han, X.; Ding, W.; Jiang, S.; Cao, Y.; Lu, C. Controlled Free Edge Effects in Surface Wrinkling via Combination of External Straining and Selective O2 Plasma Exposure. Langmuir 2013, 29 (23), 7170-7177.
16. Gao, N.; Zhang, X.; Liao, S.; Jia, H.; Wang, Y. Polymer Swelling Induced Conductive Wrinkles for An Ultrasensitive Pressure Sensor. ACS Macro Lett. 2016, 5 (7), 823-827.
17. Ferretti, G. L.; Nania, M.; Matar, O. K.; Cabral, J. T. Wrinkling Measurement of The Mechanical Properties of Drying Salt Thin Films. Langmuir 2016, 32 (9), 2199-2207.
18. Zhao, X.; Wang, J.; Huang, J.; Li, L.; Liu, E.; Zhao, J.; Li, Q.; Zhang, X.; Lu, C. Path-Guided Hierarchical Surface Relief Gratings on Azo-Films Induced by Polarized Light Illumination through Surface-Wrinkling Phase Mask. Langmuir 2020, 36 (11), 2837-2846.
19. Palacios-Cuesta, M.; Liras, M.; del Campo, A.; García, O.; Rodríguez-Hernández, J. Versatile Approach for The Fabrication of Functional Wrinkled Polymer Surfaces. Langmuir 2014, 30 (44), 13244-13254.
20. González-Henríquez, C. M.; Sagredo-Oyarce, D. H.; Sarabia-Vallejos, M. A.; Rodríguez-Hernández, J. Fabrication of Micro and Sub-Micrometer Wrinkled Hydrogel Surfaces Through Thermal and Photocrosslinking Processes. Polymer 2016, 101, 24-33.
21. Chan, E. P.; Kundu, S.; Lin, Q.; Stafford, C. M. Quantifying the Stress Relaxation Modulus of Polymer Thin Films via Thermal Wrinkling. ACS Appl. Mater. Interfaces 2011, 3 (2), 331-338.
22. Izawa, H. Preparation of Biobased Wrinkled Surfaces via Lignification-Mimetic Reactions and Drying: A New Approach for Developing Surface Wrinkling. Polym. J. 2017, 49 (11), 759-765.
23. Guvendiren, M.; Burdick, J. A.; Yang, S. Kinetic Study of Swelling-Induced Surface Pattern Formation and Ordering in Hydrogel Films with Depth-Wise Crosslinking Gradient. Soft Matter 2010, 6 (9), 2044-2049.
24. Hou, J.; Li, Q.; Han, X.; Lu, C. Swelling/Deswelling-Induced Reversible Surface Wrinkling on Layer-By-Layer Multilayers. J. Phys. Chem. B.2014, 118 (49), 14502-14509.
25. Xuan, Y.; Guo, X.; Cui, Y.; Yuan, C.; Ge, H.; Cui, B.; Chen, Y. Crack-Free Controlled Wrinkling of A Bilayer Film with A Gradient Interface. Soft Matter 2012, 8 (37), 9603-9609.
26. Juřík, P.; Slepička, P.; Nagyová, M.; Švorčík, V. Wrinkle Pattern on PLLA Induced by Stress of Polymer-Metal Bilayer. Surf. Coat. Technol. 2017, 311, 344-350.
27. Ebata, Y.; Croll, A. B.; Crosby, A. J. Wrinkling and Strain Localizations in Polymer Thin Films. Soft Matter 2012, 8 (35), 9086-9091.
28. Li, J.; An, Y.; Huang, R.; Jiang, H.; Xie, T. Unique Aspects of A Shape Memory Polymer as The Substrate for Surface Wrinkling. ACS Appl. Mater. Interfaces 2012, 4 (2), 598-603.
29. Schedl, A. E.; Neuber, C.; Fery, A.; Schmidt, H.-W. Controlled Wrinkling of Gradient Metal Films. Langmuir 2018, 34 (47), 14249-14253.
30. Li, F.; Hou, H.; Yin, J.;Jiang, X. Multi-Responsive Wrinkling Patterns by The Photoswitchable Supramolecular Network. ACS Macro Lett.2017, 6 (8), 848-853.
31. Tanaka, T.; Sun, S.-T.; Hirokawa, Y.; Katayama, S.; Kucera, J.; Hirose, Y.; Amiya, T. Mechanical Instability of Gels at The Phase Transition. Nature 1987, 325 (6107), 796-798.
32. Guvendiren, M.; Yang, S.; Burdick, J. A. Swelling‐Induced Surface Patterns in Hydrogels with Gradient Crosslinking Density. Adv. Funct. Mater. 2009, 19 (19), 3038-3045.
33. Zhang, L.; Lang, X.; Hirata, A.; Chen, M. Wrinkled Nanoporous Gold Films with Ultrahigh Surface-Enhanced Raman Scattering Enhancement. ACS Nano 2011, 5 (6), 4407-4413.
34. Pazos-Pérez, N.; Ni, W.; Schweikart, A.; Alvarez-Puebla, R. A.; Fery, A.; Liz-Marzán, L. M. Highly Uniform SERS Substrates Formed by Wrinkle-Confined Drying of Gold Colloids. Chem. Sci. 2010, 1 (2), 174-178.
35. Koya, A. N.; Zhu, X.; Ohannesian, N.; Yanik, A. A.; Alabastri, A.; Proietti Zaccaria, R.; Krahne, R.; Shih, W.-C.; Garoli, D. Nanoporous Metals: From Plasmonic Properties to Applications in Enhanced Spectroscopy and Photocatalysis. ACS Nano 2021, 15 (4), 6038-6060.
36. Ron, R.; Haleva, E.; Salomon, A. Nanoporous Metallic Networks: Fabrication, Optical Properties, and Applications. Adv. Mater. 2018, 30 (41), 1706755.
37. Hayward, R. C.; Chmelka, B. F.;Kramer, E. J. Template Cross-Linking Effects on Morphologies of Swellable Block Copolymer and Mesostructured Silica Thin Films. Macromolecules 2005, 38 (18), 7768-7783.
38. Lee, J. H.; Jeong, H.-C.; Won, J.; Kim, D. H.;Lee, D. W.; Song, I. H.; Oh, J. Y.; Kim, D.-H.; Liu, Y.; Seo, D.-S. Formation of The Wrinkle Structure on A Styrene–Butadiene–Styrene Block Copolymer Surface by Surface Chemical Reformation via Ion-Beam Irradiation. J. Phys. Chem. C 2020, 124 (15), 8378-8385.
39. Li, X.; Han, Y. Tunable Wavelength Antireflective Film by Non-Solvent-Induced Phase Separation of Amphiphilic Block Copolymer Micelle Solution. J. Mater. Chem. 2011, 21 (44), 18024-18033.
40. Schauer, S.; Worgull, M.;Hölscher, H. Bio-Inspired Hierarchical Micro- and Nano-Wrinkles Obtained via Mechanically Directed Self-Assembly on Shape-Memory Polymers. Soft Matter 2017, 13 (24), 4328-4334.
41. Lao, Z.; Pan, D.; Yuan, H.; Ni, J.; Ji, S.; Zhu, W.; Hu, Y.; Li, J.; Wu, D.; Chu, J. Mechanical-Tunable Capillary-Force-Driven Self-Assembled Hierarchical Structures on Soft Substrate. ACS Nano 2018, 12 (10), 10142-10150.
42. Rizzieri, R.; Mahadevan, L.; Vaziri, A.; Donald, A. Superficial Wrinkles in Stretched, Drying Gelatin Films. Langmuir 2006, 22 (8), 3622-3626.
43. Gallardo, A.; Lujan, N.; Reinecke, H.; García, C.; Campo, A. d.; Rodríguez-Hernández, J. Chemical and Topographical Modification of Polycarbonate Surfaces Through Diffusion/Photocuring Processes of Hydrogel Precursors Based on Vinylpyrrolidone. Langmuir 2017, 33 (7), 1614-1622.
44. Owais, A.; Smith-Palmer, T.; Gentle, A.; Neto, C. Influence of Long-Range Forces and Capillarity on The Function of Underwater Superoleophobic Wrinkled Surfaces. Soft Matter 2018, 14 (32), 6627-6634.
45. Vapaavuori, J.; Stimpson, T. C.; Moran-Mirabal, J. M. Dynamically Evolving Surface Patterns through Light-Triggered Wrinkling Erasure. Langmuir 2018, 35 (4), 875-881.
46. Hu, X.;Lyon, L. A. Thin Films Constructed by Centrifugal Deposition of Highly Deformable, Charged Microgels. ACS Macro Lett. 2015, 4 (3), 302-307.
47. Junisu, B. A.; Sun, Y.-S., Three-Dimensional Interconnected Network of Gold Nanostructures for Molecular Sensing via Surface-Enhanced Raman Scattering Spectroscopy. ACS Appl. Nano Mater. 2020, 3 (8), 7950-7962.
48. Huntington, M. D.; Engel, C. J.; Hryn, A. J.; Odom, T. W. Polymer Nanowrinkles with Continuously Tunable Wavelengths. ACS Appl. Mater. Interfaces 2013, 5 (13), 6438-6442.
49. Kim, P.; Abkarian, M.; Stone, H. A. Hierarchical Folding of Elastic Membranes Under Biaxial Compressive Stress. Nat. Mater. 2011, 10 (12), 952-957.
50. Holmes, D. P.; Crosby, A. J. Draping Films: A Wrinkle to Fold Transition. Phys. Rev. Lett. 2010, 105 (3), 038303.
51. Pocivavsek, L.; Dellsy, R.; Kern, A.; Johnson, S.; Lin, B.; Lee, K. Y. C.; Cerda, E. Stress and Fold Localization in Thin Elastic Membranes. Science 2008, 320 (5878), 912-916.
52. Chatterjee, S.; McDonald, C.; Niu, J.; Velankar, S. S.; Wang, P.; Huang, R. Wrinkling and Folding of Thin Films by Viscous Stress. Soft Matter 2015, 11 (9), 1814-1827.
53. El Haitami, A.; Bretagnol, F. d. r.; Assuid, P.; Petitet, G.; Cantournet, S.; Corté, L. Erasable and Reversible Wrinkling of Halogenated Rubber Surfaces. Langmuir 2013, 29 (50), 15664-15672.
54. Okayasu, T.; Zhang, H. L.; Bucknall, D. G.; Briggs, G. A. D. Spontaneous Formation of Ordered Lateral Patterns in Polymer Thin‐Film Structures. Adv. Funct. Mater. 2004, 14 (11), 1081-1088.
55. Lu, C.; Yu, S.; Li, H.; Zhou, H.; Jiao, Z.; Li, L. Harnessing Heterogeneous Wrinkles in Metal/Polydimethylsiloxane Film System by Combination of Mechanical Loading and Heat Treatment. Adv. Mater. Interfaces 2020, 7 (9), 1902188.
56. Kim, H. S.; Crosby, A. J. Solvent‐Responsive Surface via Wrinkling Instability. Adv. Mater. 2011, 23 (36), 4188-4192.
57. Vandeparre, H.; Gabriele, S.; Brau, F.; Gay, C.; Parker, K. K.; Damman, P. Hierarchical Wrinkling Patterns. Soft Matter 2010, 6 (22), 5751-5756.
58. Chen, C. M.; Yang, S. Wrinkling Instabilities in Polymer Films and Their Applications. Polym. Int. 2012, 61 (7), 1041-1047.
59. Huang, Z.; Hong, W.; Suo, Z. Nonlinear Analyses of Wrinkles in A Film Bonded to A Compliant Substrate. J. Mech. Phys. Solids 2005, 53 (9), 2101-2118.
60. Chung, J. Y.; Nolte, A. J.; Stafford, C. M. Diffusion‐Controlled, Self‐Organized Growth of Symmetric Wrinkling Patterns. Adv. Mater. 2009, 21 (13), 1358-1362.
61. Oscurato, S. L.; Formisano, F.; de Lisio, C.; d′Ischia, M.; Gesuele, F.; Maddalena, P.; Manini, P.; Migliaccio, L.; Pezzella, A. Spontaneous Wrinkle Emergence in Nascent Eumelanin Thin Films. Soft Matter 2019, 15 (45), 9261-9270.
62. Basu, S. K.; McCormick, A. V.; Scriven, L. Stress Generation by Solvent Absorption and Wrinkling of A Cross-Linked Coating Atop A Viscous or Elastic Base. Langmuir 2006, 22 (13), 5916-5924.
63. Li, Y.; Peterson, J. J.; Jhaveri, S. B.; Carter, K. R. Patterned Polymer Films via Reactive Silane Infusion-Induced Wrinkling. Langmuir 2013, 29 (14), 4632-4639.
64. Kim, Y. H.; Lee, Y. M.; Lee, J. Y.; Ko, M. J.; Yoo, P. J. Hierarchical Nanoflake Surface Driven by Spontaneous Wrinkling of Polyelectrolyte/Metal Complexed Films. ACS Nano 2012, 6 (2), 1082-1093.
65. Gao, F.; Guo, W.; Chen, P.; Cai, C.; Peng, G. Numerical Analysis on The Wrinkling Instability of A Stiff Film Adhering to An Elastic Substrate with A Graded Coating. Intl. J. Appl. Mech. 2019, 11 (02), 1950015.
66. Sjölander, J.; Hallander, P.; Åkermo, M. Forming Induced Wrinkling 0f Composite Laminates: A Numerical Study 0n Wrinkling Mechanisms. Composites Part A: Appl. Sci. Manuf. 2016, 81, 41-51.
67. Huang, R.; Suo, Z. Wrinkling of A Compressed Elastic Film on A Viscous Layer. J. Appl. Phys. 2002, 91 (3), 1135-1142.
68. Nikravesh, S.; Ryu, D.; Shen, Y.-L. Instabilities of Thin Films on A Compliant Substrate: Direct Numerical Simulations from Surface Wrinkling to Global Buckling. Sci. Rep. 2020, 10 (1), 5728.
69. Matsuo, E. S.; Tanaka, T. Patterns in Shrinking Gels. Nature 1992, 358 (6386), 482-485.
70. Huraux, K.; Narita, T.; Bresson, B.; Frétigny, C.; Lequeux, F. Wrinkling of A Nanometric Glassy Skin/Crust Induced bBy Drying in Poly (Vinyl Alcohol) Gels. Soft Matter 2012, 8 (31), 8075-8081.
71. Ramanathan, M.; Lokitz, B. S.; Messman, J. M.; Stafford, C. M.; Kilbey II, S. M. Spontaneous Wrinkling in Azlactone-Based Functional Polymer Thin Films in 2D and 3D Geometries for Guided Nanopatterning. J. Mater. Chem. C 2013, 1 (11), 2097-2101.
72. Katzenstein, J. M.; Janes, D. W.; Cushen, J. D.; Hira, N. B.; McGuffin, D. L.; Prisco, N. A.; Ellison, C. J. Patterning by Photochemically Directing the Marangoni Effect. ACS Macro Lett. 2012, 1 (10), 1150-1154.
73. Bin Kim, C.; Janes, D. W.; McGuffin, D. L.; Ellison, C. J. Surface Energy Gradient Driven Convection for Generating Nanoscale and Microscale Patterned Polymer Films using Photosensitizers. J. Polym. Sci. B: Polym. Phys. 2014, 52 (18), 1195-1202.
74. Jones, A. R.; Kim, C. B.; Zhou, S. X.; Ha, H.; Katsumata, R.; Blachut, G.; Bonnecaze, R. T.; Ellison, C. J. Generating Large Thermally Stable Marangoni-Driven Topography in Polymer Films by Stabilizing the Surface Energy Gradient. Macromolecules 2017, 50 (11), 4588-4596.
75. Chiche, A.; Stafford, C. M.; Cabral, J. T. Complex Micropatterning of Periodic Structures on Elastomeric Surfaces. Soft Matter 2008, 4 (12), 2360-2364.
76. Stafford, C. M.; Vogt, B. D.; Harrison, C.; Julthongpiput, D.; Huang, R. Elastic Moduli of Ultrathin Amorphous Polymer Films. Macromolecules 2006, 39 (15), 5095-5099.
77. Lu, C.; Dönch, I.; Nolte, M.; Fery, A. Au Nanoparticle-Based Multilayer Ultrathin Films with Covalently Linked Nanostructures: Spraying Layer-By-Layer Assembly and Mechanical Property Characterization. Chem. Mater. 2006, 18 (26), 6204-6210.
78. Bassou, N.; Rharbi, Y. Role of Benard−Marangoni Instabilities during Solvent Evaporation in Polymer Surface Corrugations. Langmuir 2009, 25 (1), 624-632.
79. Yin, J.; Lu, C. Hierarchical Surface Wrinkles Directed by Wrinkled Templates. Soft Matter 2012, 8 (24), 6528-6534.
80. Torres, J. M.; Stafford, C. M.; Vogt, B. D. Photoinitator Surface Segregation Induced Instabilities from Polymerization of A Liquid Coating on A Rigid Substrate. Soft Matter 2012, 8 (19), 5225-5232.
81. Kang, M. K.; Huang, R. Effect of Surface Tension on Swell-Induced Surface Instability of Substrate-Confined Hydrogel Layers. Soft Matter 2010, 6 (22), 5736-5742.
82. Thami, T.; Ramonda, M.; Ferez, L.; Flaud, V.; Petit, E.; Cot, D.; Rebière, B.; Ameduri, B. Growth-Induced Wrinkles and Dotlike Patterns of a Swollen Fluoroalkylated Thin Film by the Reaction of Surface-Attached Polymethylhydrosiloxane. Langmuir 2022, 38 (46), 14140-14152.
83. Gan, Y.; Jiang, X.; Yin, J. Self-Wrinkling Patterned Surface of Photocuring Coating Induced by the Fluorinated POSS Containing Thiol Groups (F-POSS-SH) as The Reactive Nanoadditive. Macromolecules 2012, 45 (18), 7520-7526.
84. Zu, M.; Li, Q.; Wang, G.; Byun, J. H.; Chou, T. W. Carbon Nanotube Fiber based Stretchable Conductor. Adv. Funct. Mater. 2013, 23 (7), 789-793.
85. Wu, H.; Kustra, S.; Gates, E. M.; Bettinger, C. J. Topographic Substrates as Strain Relief Features in Stretchable Organic Thin Film Transistors. Org. Electron. 2013, 14 (6), 1636-1642.
86. Kim, J. B.; Kim, P.; Pégard, N. C.; Oh, S. J.; Kagan, C. R.; Fleischer, J. W.; Stone, H. A.; Loo, Y.-L. Wrinkles and Deep Folds as Photonic Structures in Photovoltaics. Nat. Photonics 2012, 6 (5), 327-332.
87. Bahners, T.; Prager, L.; Kriehn, S.; Gutmann, J. S. Super-Hydrophilic Surfaces by Photo-Induced Micro-Folding. Appl. Surf. Sci. 2012, 259, 847-852.
88. Lee, S. G.; Lee, D. Y.; Lim, H. S.; Lee, D. H.; Lee, S.; Cho, K. Switchable Transparency and Wetting of Elastomeric Smart Windows. Adv. Mater. 2010, 22 (44), 5013-5017.
89. Stenberg, H.; Matikainen, A.; Daniel, S.; Nuutinen, T.; Stenberg, P.; Honkanen, S.; Pakkanen, T.; Vahimaa, P.; Suvanto, M. Self‐organized Polymer Wrinkles: A Lithography‐free Pathway for Surface‐enhanced Raman Scattering (SERS) Substrates. Macromol. Mater. Eng. 2015, 300 (4), 386-390.
90. Schweikart, A.; Pazos-Pérez, N.; Alvarez-Puebla, R. A.; Fery, A. Controlling Inter-Nanoparticle Coupling by Wrinkle-Assisted Assembly. Soft Matter 2011, 7 (9), 4093-4100.
91. Goia, D.; Matijević, E. Tailoring te Particle Size of Monodispersed Colloidal Gold. Colloids Surf. A Physicochem. Eng. Asp. 1999, 146 (1-3), 139-152.
92. Park, H.-G.; Jeong, H.-C.; Jung, Y. H.; Seo, D.-S. Control of The Wrinkle Structure on Surface-Reformed Poly (Dimethylsiloxane) via Ion-Beam Bombardment. Sci. Rep. 2015, 5 (1), 1-8.
93. Peng, S.; Li, W.; Zhang, J. Diffraction-Pattern Based on Spontaneous Wrinkled Thin Films. Mater. Trans. 2017, 58 (1), 1-5.
94. Reignier, J.; Sarbu, A.; Barraud, V. Spontaneous Formation of Two-Dimensional Wrinkles in Poly (Urethane-Isocyanurate) Rigid Foam Boards. J. Cell. Plast. 2020, 56 (3), 297-315.
95. Kennemur, J. G. Poly (Vinylpyridine) Segments in Block Copolymers: Synthesis, Self-Assembly, and Versatility. Macromolecules 2019, 52 (4), 1354-1370.
96. Malpani, D.; Majumder, A.; Samanta, P.; Srivastava, R. K.; Nandan, B. Supramolecular Route for Enhancing Polymer Electrospinnability. ACS omega 2018, 3 (11), 15666-15678.
97. Evans, C. M.; Narayanan, S.; Jiang, Z.; Torkelson, J. M. Modulus, Confinement, and Temperature Effects on Surface Capillary Wave Dynamics in Bilayer Polymer Films Near the Glass Transition. Phys. Rev. Lett. 2012, 109 (3), 038302.
98. Reiter, G.; Hamieh, M.; Damman, P.; Sclavons, S.; Gabriele, S.; Vilmin, T.; Raphaël, E. Residual Stresses in Thin Polymer Films Cause Rupture and Dominate Early Stages of Dewetting. Nat. Mater 2005, 4 (10), 754-758.
99. Damman, P.; Gabriele, S.; Coppée, S.; Desprez, S.; Villers, D.; Vilmin, T.; Raphaël, E.; Hamieh, M.; Al Akhrass, S.; Reiter, G. Relaxation of Residual Stress and Reentanglement of Polymers in Spin-Coated Films. Phys. Rev. Lett. 2007, 99 (3), 036101.
100. Lin, C.-C.; Yang, F.; Lee, S. Surface Wrinkling of an Elastic Film: Effect of Residual Surface Stress. Langmuir 2008, 24 (23), 13627-13631.
101. Muñoz-Bonilla, A.; Fernández-García, M.; Rodríguez-Hernández, J. Towards Hierarchically Ordered Functional Porous Polymeric Surfaces Prepared by the Breath Figures Approach. Prog. Polym. Sci. 2014, 39 (3), 510-554.
102. Reese, C. M.; Guo, W.; Thompson, B. J.; Logan, P. K.; Stafford, C. M.; Patton, D. L. Quantifying Strain via Buckling Instabilities in Surface-Modified Polymer Brushes. Macromolecules 2020, 53 (11), 4552-4559.
103. Gao, H.; Zhang, Y.; Wu, Q.; Song, J. An Analytical Model For Predicting The Machining Deformation of A Plate Blank Considers Biaxial Initial Residual Stresses. Int. J. Adv. Manuf. Technol. 2017, 93, 1473-1486.
104. Tolpigo, V.; Clarke, D. Wrinkling Of α-Alumina Films Grown by Thermal Oxidation-I. Quantitative Studies on Single Crystals of Fe-Cr-Al Alloy. Acta Mater 1998, 46, 5151.
105. Muñoz-Bonilla, A.; Fernández-García, M.; Rodríguez-Hernández, J. Towards Hierarchically Ordered Functional Porous Polymeric Surfaces Prepared by The Breath Figures Approach. Prog. Pol. Sci. 2014, 39 (3), 510-554.
106. Cong, H.; Wang, J.; Yu, B.; Tang, J. Preparation of A Highly Permeable Ordered Porous Microfiltration Membrane of Brominated Poly (Phenylene Oxide) on An Ice Substrate by the Breath Figure Method. Soft Matter 2012, 8 (34), 8835-8839.
107. Wu, B.; Zhang, W.; Gao, N.; Zhou, M.; Liang, Y.; Wang, Y.; Li, F.; Li, G. Poly (Ionic Liquid)-Based Breath Figure Films: A New Kind of Honeycomb Porous Films with Great Extendable Capability. Sci. Rep. 2017, 7 (1), 13973.


REFERENCES (4)

1. Harnish, B.; Robinson, J. T.; Pei, Z.; Ramström, O.; Yan, M. UV-Cross-Linked Poly (Vinylpyridine) Thin Films as Reversibly Responsive Surfaces. Chem. Mater. 2005, 17 (16), 4092-4096.
2. Arizaga, A.; Ibarz, G.; Piñol, R. Stimuli-Responsive Poly (4-Vinyl Pyridine) Hydrogel Nanoparticles: Synthesis by Nanoprecipitation and Swelling Behavior. J. Colloid Interface Sci. 2010, 348 (2), 668-672.
3. Orlov, M.; Tokarev, I.; Scholl, A.; Doran, A.; Minko, S. pH-responsive Thin Film Membranes from Poly (2-Vinylpyridine): Water Vapor-Induced Formation of A Microporous Structure. Macromolecules 2007, 40 (6), 2086-2091.
4. Armes, S.; Aldissi, M. Preparation and Characterization of Colloidal Dispersions of Polypyrrole Using Poly (2-Vinyl Pyridine)-Based Steric Stabilizers. Polymer 1990, 31 (3), 569-574.
5. Drechsler, A.; Synytska, A.; Uhlmann, P.; Stamm, M.; Kremer, F. Tuning the Adhesion of Silica Microparticles to A Poly (2-Vinyl Pyridine) Brush: An AFM Force Measurement Study. Langmuir 2012, 28 (44), 15555-15565.
6. Fujii, S.; Kameyama, S.; Armes, S. P.; Dupin, D.; Suzaki, M.; Nakamura, Y. pH-Responsive Liquid Marbles Stabilized with Poly (2-Vinylpyridine) Particles. Soft Matter 2010, 6 (3), 635-640.
7. Kennemur, J. G. Poly (Vinylpyridine) Segments in Block Copolymers: Synthesis, Self-Assembly, and Versatility. Macromolecules 2019, 52 (4), 1354-1370.
8. Kocak, G.; Tuncer, C.; Bütün, V. pH-Responsive Polymers. Polym. Chem. 2017, 8 (1), 144-176.
9. Zha, W.; Han, C. D.; Lee, D. H.; Han, S. H.; Kim, J. K.; Kang, J. H.; Park, C. Origin of the Difference in Order− Disorder Transition Temperature between Polystyrene-block-poly (2-vinylpyridine) and Polystyrene-block-poly (4-vinylpyridine) Copolymers. Macromolecules 2007, 40 (6), 2109-2119.
10. Li, F.; Yao, X.; Wang, Z.; Xing, W.; Jin, W.; Huang, J.;Wang, Y. Highly Porous Metal Oxide Networks of Interconnected Nanotubes by Atomic Layer Deposition. Nano Lett. 2012, 12 (9), 5033-5038.
11. Wang, Y.; He, C.; Xing, W.; Li, F.; Tong, L.; Chen, Z.; Liao, X.; Steinhart, M. Nanoporous Metal Membranes with Bicontinuous Morphology from Recyclable Block‐Copolymer Templates. Adv. Mater. 2010, 22 (18), 2068-2072.
12. Sun, Y.-S.; Lin, C.-F.; Luo, S.-T.;Su, C.-Y. Block-Copolymer-Templated Hierarchical Porous Carbon Nanostructures with Nitrogen-Rich Functional Groups for Molecular Sensing. ACS Appl. Mater. Interfaces 2017, 9 (37), 31235-31244.
13. Yin, J.; Yao, X.; Liou, J.-Y.; Sun, W.; Sun, Y.-S.; Wang, Y. Membranes with Highly Ordered Straight Nanopores by Selective Swelling of Fast Perpendicularly Aligned Block Copolymers. ACS Nano 2013, 7 (11), 9961-9974.
14. Topham, P. D.; Howse, J. R.; Fernyhough, C. M.; Ryan, A. J. The Performance of Poly (Styrene)-Block-Poly (2-Vinyl Pyridine)-Block-Poly (Styrene) Triblock Copolymers as Ph-Driven Actuators. Soft Matter 2007, 3 (12), 1506-1512.
15. Junisu, B. A.; Sun, Y.-S. Three-Dimensional Interconnected Network of Gold Nanostructures for Molecular Sensing via Surface-Enhanced Raman Scattering Spectroscopy. ACS Appl. Nano Mater. 2020, 3 (8), 7950-7962.
16. Mistark, P. A.; Park, S.; Yalcin, S. E.; Lee, D. H.; Yavuzcetin, O.; Tuominen, M. T.; Russell, T. P.; Achermann, M. Block-Copolymer-Based Plasmonic Nanostructures. ACS Nano 2009, 3 (12), 3987-3992.
17. Xie, M.; Xu, F.; Zhang, L.; Yin, J.; Jiang, X. Reversible Surface Dual-Pattern with Simultaneously Dynamic Wrinkled Topography and Fluorescence. ACS Macro Lett.2018, 7 (5), 540-545.
18. Gao, N.; Zhang, X.; Liao, S.; Jia, H.; Wang, Y. Polymer Swelling Induced Conductive Wrinkles for An Ultrasensitive Pressure Sensor. ACS Macro Lett.2016, 5 (7), 823-827.
19. Ferretti, G. L.; Nania, M.; Matar, O. K.; Cabral, J. T. Wrinkling Measurement of The Mechanical Properties of Drying Salt Thin Films. Langmuir 2016, 32 (9), 2199-2207.
20. Lu, C.; Yu, S.; Li, H.; Zhou, H.; Jiao, Z.; Li, L. Harnessing Heterogeneous Wrinkles in Metal/Polydimethylsiloxane Film System by Combination of Mechanical Loading and Heat Treatment. Adv. Mater. Interfaces 2020, 7 (9), 1902188.
21. Guvendiren, M.; Yang, S.; Burdick, J. A. Swelling‐Induced Surface Patterns in Hydrogels with Gradient Crosslinking Density. Adv. Funct. Mater. 2009, 19 (19), 3038-3045.
22. Baik, S.; Kim, D. W.; Park, Y.; Lee, T.-J.; Ho Bhang, S.; Pang, C. A Wet-Tolerant Adhesive Patch Inspired by Protuberances in Suction Cups of Octopi. Nature 2017, 546 (7658), 396-400.
23. Choi, M. K.; Park, O. K.; Choi, C.; Qiao, S.; Ghaffari, R.; Kim, J.; Lee, D. J.; Kim, M.; Hyun, W.; Kim, S. J. Cephalopod‐Inspired Miniaturized Suction Cups for Smart Medical Skin. Adv. Healthc. Mater. 2016, 5 (1), 80-87.
24. Chang, W.-Y.; Wu, Y.; Chung, Y.-C. Facile Fabrication of Ordered Nanostructures from Protruding Nanoballs to Recessional Nanosuckers via Solvent Treatment on Covered Nanosphere Assembled Monolayers. Nano Lett. 2014, 14 (3), 1546-1550.
25. Lee, H.; Um, D. S.; Lee, Y.; Lim, S.; Kim, H. j.; Ko, H. Octopus‐Inspired Smart Adhesive Pads for Transfer Printing of Semiconducting Nanomembranes. Adv. Mater. 2016, 28 (34), 7457-7465.
26. Dannenberg, H. Measurement of Adhesion by A Blister Method. J. Appl. Polym. Sci. 1961, 5 (14), 125-134.
27. Fedorov, A.; Van Veen, A.; van Tijum, R.; De Hosson, J. T. M. Adhesion Strength of Polymer Coatings studied by Laser Induced Delamination. MRS Online Proceedings Library 2003, 795, 517-522.
28. Burtovyy, R.; Luzinov, I. Reversibility of pH-Induced Dewetting of Poly (Vinyl Pyridine) Thin Films on Silicon Oxide Substrate. Langmuir 2008, 24 (11), 5903-5910.
29. Torun, N.; Torun, I.; Sakir, M.; Kalay, M.; Onses, M. S. Physically Unclonable Surfaces via Dewetting of Polymer Thin Films. ACS Appl. Mater. Interfaces 2021, 13 (9), 11247-11259.
30. Lu, S.-Y.; Chen, H.-L.; Wu, K.-H.; Chen, Y.-Y. Formation of Nanowire Striations Driven by Marangoni Instability in Spin-Cast Polymer Thin Films. Langmuir 2007, 23 (20), 10069-10073.
31. Ul Haq, A.; Carotenuto, F.; De Matteis, F.; Prosposito, P.; Francini, R.; Teodori, L.; Pasquo, A.; Di Nardo, P. Intrinsically Conductive Polymers For Striated Cardiac Muscle Repair. Int. J. Mol. Sci. 2021, 22 (16), 8550.
32. Hangarter, C. M.; Myung, N. V. Magnetic Alignment of Nanowires. Chem. Mater. 2005, 17 (6), 1320-1324.
33. Arbatan, T.; Li, L.; Tian, J.; Shen, W. Liquid Marbles as Micro‐Bioreactorsvfor Rapid Blood Typing. Adv. Healthc. Mater. 2012, 1 (1), 80-83.
34. Oliveira, N. M.; Reis, R. L.; Mano, J. F. The Potential of Liquid Marbles for Biomedical Applications: A Critical Review. Adv. Healthc. Mater. 2017, 6 (19), 1700192.
35. Fujii, S. Liquid Marble as an Amphibious Carrier for the Controlled Delivery and Release of Substances. Langmuir 2022, 38 (42), 12757-12763.
36. Dampeirou, C. Hydrophobic Silica-Based Water Powder. WO Patent 2005034917A2 2005.
37. Lahanas, K.; Vrabie, N.; Santos, E.; Miklean, S. US Pat., 6290941, Color Access. Inc: 2001.
38. Stamm, M. Polymer Surfaces and Interfaces. Characterization, Modification and Applications; Springer, Berlin, Germany: 2008.
39. Wang, Z.; Orejon, D.; Takata, Y.; Sefiane, K. Wetting and Evaporation of Multicomponent Droplets. Phys. Rep. 2022, 960, 1-37.
40. Kaplan, W. D.; Chatain, D.; Wynblatt, P.; Carter, W. C. A Review of Wetting Versus Adsorption, Complexions, and Related Phenomena: The Rosetta Stone of Wetting. J. Mater. Sci. 2013, 48, 5681-5717.
41. Israelachvili, J. N. Intermolecular and Surface Forces. Academic press: 2011.
42. Gentili, D.; Foschi, G.; Valle, F.; Cavallini, M.; Biscarini, F. Applications of Dewetting in Micro and Nanotechnology. Chem. Soc. Rev. 2012, 41 (12), 4430-4443.
43. Jing, B.; Zhao, J.; Wang, Y.; Yi, X.; Duan, H. Water-Swelling-Induced Morphological Instability of A Supported Polymethyl Methacrylate Thin Film. Langmuir 2010, 26 (11), 7651-7655.
44. Bangera, A. E.; Appaiah, K. Tunable Wettability and Prediction of Total Surface Energy for Nanocoatings: An Empirical Model. Surf. Coat. Technol. 2020, 383, 125277.
45. Tadmor, R.; Pepper, K. G. Interfacial Tension and Spreading Coefficient for Thin Films. Langmuir 2008, 24 (7), 3185-3190.
46. Zenkin, S.; Belosludtsev, A.; Kos, Š.; Čerstvý, R.; Haviar, S.; Netrvalová, M. Thickness Dependent Wetting Properties and Surface Free Energy of HfO2 Thin Films. Appl. Phys. Lett. 2016, 108 (23), 231602.
47. Zhong, X.; Duan, F. Flow Regime and Deposition Pattern of Evaporating Binary Mixture Droplet Suspended with Particles. Eur. Phys. J. E - Soft Matter 2016, 39 (2).
48. Zhou, P.; Yu, H.; Zou, W.; Wang, Z.; Liu, L. High‐Resolution and Controllable Nanodeposition Pattern of Ag Nanoparticles by Electrohydrodynamic Jet Printing Combined with Coffee Ring Effect. Adv. Mater. Interfaces 2019, 6 (20), 1900912.
49. Birnie, D. P. Rational Solvent Selection Strategies to Combat Striation Formation during Spin Coating of Thin Films. J. Mater. Res. 2001, 16, 1145-1154.
50. Birnie, D. P. Surface Skin Development and Rupture during Sol-Gel Spin-Coating. J. Sol-Gel Sci. Technol. 2004, 31, 225-228.
51. Uno, K.; Hayashi, K.; Hayashi, T.; Ito, K.; Kitano, H. Particle Adsorption In Evaporating Droplets Of Polymer Latex Dispersions On Hydrophilic And Hydrophobic Surfaces. Colloid Polym. Sci. 1998, 276, 810-815.
52. Deegan, R. D.; Bakajin, O.; Dupont, T. F.; Huber, G.; Nagel, S. R.; Witten, T. A. Capillary Flow as the Cause of Ring Stains from Dried Liquid Drops. Nature 1997, 389 (6653), 827-829.
53. Weon, B. M.; Je, J. H. Fingering Inside the Coffee Ring. Phys. Rev. E2013, 87 (1), 013003.
54. Anyfantakis, M.; Geng, Z.; Morel, M.; Rudiuk, S.; Baigl, D. Modulation of the Coffee-Ring Effect in Particle/Surfactant Mixtures: The Importance of Particle–Interface Interactions. Langmuir 2015, 31 (14), 4113-4120.
55. Ren, J.; Crivoi, A.; Duan, F. Disk-Ring Deposition in Drying A Sessile Nanofluid Droplet with Enhanced Marangoni Effect and Particle Surface Adsorption. Langmuir 2020, 36 (49), 15064-15074.
56. Shmuylovich, L.; Shen, A. Q.; Stone, H. A. Surface Morphology of Drying Latex Films: Multiple Ring Formation. Langmuir 2002, 18 (9), 3441-3445.
57. Hu, H.; Larson, R. G. Marangoni Effect Reverses Coffee-Ring Depositions. J. Phys. Chem. B. 2006, 110 (14), 7090-7094.
58. Kajiya, T.; Kobayashi, W.; Okuzono, T.; Doi, M. Controlling the Drying and Film Formation Processes of Polymer Solution Droplets with Addition of Small Amount of Surfactants. J. Phys. Chem. B. 2009, 113 (47), 15460-15466.
59. Kim, H.; Stone, H. A. Direct Measurement of Selective Evaporation of Binary Mixture Droplets by Dissolving Materials. J. Fluid Mech. 2018, 850, 769-783.
60. Li, Y.; Salvator, V.; Wijshoff, H.; Versluis, M.; Lohse, D. Evaporation-Induced Crystallization of Surfactants in Sessile Multicomponent Droplets. Langmuir 2020, 36 (26), 7545-7552.
61. Lohse, D.; Zhang, X. Physicochemical Hydrodynamics of Droplets Out of Equilibrium. Nat. Rev. Phys. 2020, 2 (8), 426-443.
62. Muñoz-Bonilla, A.; Fernández-García, M.; Rodríguez-Hernández, J. Towards Hierarchically Ordered Functional Porous Polymeric Surfaces Prepared by the Breath Figures Approach. Prog. Polym. Sci.2014, 39 (3), 510-554.
63. Tanaka, T.; Sun, S.-T.; Hirokawa, Y.; Katayama, S.; Kucera, J.; Hirose, Y.; Amiya, T. Mechanical Instability of Gels At the Phase Transition. Nature 1987, 325 (6107), 796-798.
64. Rodríguez-Hernández, J. Wrinkled Interfaces: Taking Advantage of Surface Instabilities to Pattern Polymer Surfaces. Prog. Polym. Sci.2015, 42, 1-41.
65. Yang, S.; Khare, K.; Lin, P. C. Harnessing Surface Wrinkle Patterns in Soft Matter. Adv. Funct. Mater. 2010, 20 (16), 2550-2564.
66. Chung, J. Y.; Chastek, T. Q.; Fasolka, M. J.; Ro, H. W.; Stafford, C. M. Quantifying Residual Stress in Nanoscale Thin Polymer Films via Surface Wrinkling. ACS Nano 2009, 3 (4), 844-852.
67. Reiter, G. Unstable Thin Polymer Films: Rupture snd Dewetting Processes. Langmuir 1993, 9 (5), 1344-1351.
68. Xie, R.; Karim, A.; Douglas, J. F.; Han, C. C.; Weiss, R. A. Spinodal Dewetting of Thin Polymer Films. Phys. Rev. Lett. 1998, 81 (6), 1251.
69. Sharma, A.; Reiter, G. Instability of Thin Polymer Films on Coated Substrates: Rupture, Dewetting, and Drop Formation. J. Colloid Interface Sci. 1996, 178 (2), 383-399.
70. Sharp, J.; Jones, R. Swelling-Induced Morphology in Ultrathin Supported Films of Poly (D, L− Lactide). Phys. Rev. E 2002, 66 (1), 011801.
71. Giguère, A.; Beerens, J.; Terreault, B. Creating Nanostructures on Silicon Using Ion Blistering and Electron Beam Lithography. Nanotechnology 2006, 17 (2), 600.
72. Brioude, M. M.; Laborie, M. P.; Airoudj, A.; Haidara, H.;Roucoules, V. Stability of Maleic Anhydride Plasma Polymer Film to Water Drop Evaporation. Plasma Process. Polym. 2017, 14 (8), 1600195.
73. Fares, H. M.; Wang, Q.; Yang, M.; Schlenoff, J. B. Swelling and Inflation in Polyelectrolyte Complexes. Macromolecules 2018, 52 (2), 610-619.
74. Zhao, S. Osmotic Pressure Versus Swelling Pressure: Comment on “Bifunctional Polymer Hydrogel Layers as Forward Osmosis Draw Agents for Continuous Production of Fresh Water using Solar Energy”. Environ. Sci. Technol. 2014, 48 (7), 4212-4213.
75. Flory, P. J.; Rehner Jr, J. Statistical Mechanics of Cross‐Linked Polymer Networks I. Rubberlike Elasticity. J. Chem. Phys. 1943, 11 (11), 512-520.
76. Toomey, R.; Freidank, D.; Rühe, J. Swelling Behavior of Thin, Surface-Attached Polymer Networks. Macromolecules 2004, 37 (3), 882-887.
77. Brau, F.; Thouvenel-Romans, S.; Steinbock, O.; Cardoso, S. S.; Cartwright, J. H. Filiform Corrosion as A Pressure-Driven Delamination Process. Soft Matter 2019, 15 (4), 803-812.
78. Effendy, S.; Zhou, T.; Eichman, H.; Petr, M.; Bazant, M. Z. Blistering Failure of Elastic Coatings With Applications to Corrosion Resistance. Soft Matter 2021, 17 (41), 9480-9498.
79. Des Cloizeaux, J.; Noda, I. Osmotic Pressure of Long Polymers in Good Solvents at Moderate Concentrations: A Comparison Between Experiments and Theory. Macromolecules 1982, 15 (6), 1505-1507.
80. Noda, I.; Kato, N.; Kitano, T.; Nagasawa, M. Thermodynamic Properties of Moderately Concentrated Solutions of Linear Polymers. Macromolecules 1981, 14 (3), 668-676.
81. Noda, I.; Higo, Y.; Ueno, N.; Fujimoto, T. Semidilute Region for Linear Polymers in Good Solvents. Macromolecules 1984, 17 (5), 1055-1059.
82. Takahashi, Y.; Noda, I.; Nagasawa, M. Steady-State Compliance of Linear Polymer Solutions over A Wide Range of Concentration. Macromolecules 1985, 18 (11), 2220-2225.
83. Matsushita, Y.; Shimizu, K.; Nakao, Y.; Choshi, H.; Noda, I.; Nagasawa, M. Preparation and Characterization of Poly (2-Vinylpyridine) with Narrow Molecular Weight Distributions. Polym. J. 1986, 18 (4), 361-366.
84. Matsushita, Y.; Nakao, Y.; Shimizu, K.; Noda, I.; Nagasawa, M. Conformations of Diblock Copolymers in Dilute Solutions. Macromolecules 1988, 21 (9), 2790-2793.
85. Jensen, H. M. The Blister Test for Interface Toughness Measurement. Eng. Fract. Mech. 1991, 40 (3), 475-486.
86. Berkelaar, R. P.; Bampoulis, P.; Dietrich, E.; Jansen, H. P.; Zhang, X.; Kooij, E. S.; Lohse, D.; Zandvliet, H. J. Water-Induced Blister Formation in A Thin Film Polymer. Langmuir 2015, 31 (3), 1017-1025.
87. Nadermann, N.; Hui, C.-Y.; Jagota, A. Solid Surface Tension Measured by A Liquid Drop under A Solid Film. Proc. Natl. Acad. Sci. 2013, 110 (26), 10541-10545.
88. Wang, Y.; Bhushan, B.; Zhao, X. Nanoindents Produced by Nanobubbles on Ultrathin Polystyrene Films in Water. Nanotechnology 2008, 20 (4), 045301.
89. Li, D.; Jing, D.; Pan, Y.; Wang, W.; Zhao, X. Coalescence and Stability Analysis of Surface Nanobubbles on The Polystyrene/Water Interface. Langmuir 2014, 30 (21), 6079-6088.
90. Siretanu, I.; Chapel, J. P.; Drummond, C. Water−Ions Induced Nanostructuration Of Hydrophobic Polymer Surfaces. ACS Nano 2011, 5 (4), 2939-2947.


REFERENCES (5)

1. Baeg, K. J.; Khim, D.; Kim, D. Y.; Jung, S. W.; Koo, J. B.; You, I. K.; Yan, H.; Facchetti, A.; Noh, Y. Y. High Speeds Complementary Integrated Circuits Fabricated with All‐Printed Polymeric Semiconductors. J. Polym. Sci. B 2011, 49 (1), 62-67.
2. Khim, D.; Han, H.; Baeg, K. J.; Kim, J.; Kwak, S. W.; Kim, D. Y.; Noh, Y. Y. Simple Bar‐Coating Process for Large‐Area, High‐Performance Organic Field‐Effect Transistors and Ambipolar Complementary Integrated Circuits. Adv. Mater 2013, 25 (31), 4302-4308.
3. Abdelsamie, M.; Zhao, K.; Niazi, M. R.; Chou, K. W.; Amassian, A. In Situ UV-Visible Absorption during Spin-Coating of Organic Semiconductors: A New Probe for Organic Electronics and Photovoltaics. J. Mater. Chem. C. 2014, 2 (17), 3373-3381.
4. Liu, C.; Li, Y.; Lee, M. V.; Kumatani, A.; Tsukagoshi, K. Self-Assembly of Semiconductor/Insulator Interfaces in One-Step Spin-Coating: A Versatile Approach for Organic Field-Effect Transistors. Phys. Chem. Chem. Phys 2013, 15 (21), 7917-7933.
5. Pichumani, M.; Bagheri, P.; Poduska, K. M.; González-Viñas, W.; Yethiraj, A. Dynamics, crystallization And Structures In Colloid Spin Coating. Soft Matter 2013, 9 (12), 3220-3229.
6. Zhou, Z.; Mao, H.; Wang, X.; Sun, T.; Chang, Q.; Chen, Y.; Xiu, F.; Liu, Z.; Liu, J.; Huang, W. Transient and Flexible Polymer Memristors Utilizing Full-Solution Processed Polymer Nanocomposites. Nanoscale 2018, 10 (31), 14824-14829.
7. Zhao, K.; Hu, H.; Spada, E.; Jagadamma, L. K.; Yan, B.; Abdelsamie, M.; Yang, Y.; Yu, L.; Munir, R.; Li, R. Highly Efficient Polymer Solar Cells with Printed Photoactive Layer: Rational Process Transfer from Spin-Coating. J. Mater. Chem. A 2016, 4 (41), 16036-16046.
8. Birnie, D. P. Rational Solvent Selection Strategies to Combat Striation Formation during Spin Coating of Thin Films. J. Mater. Res. 2001, 16, 1145-1154.
9. Birnie, D. P. Surface Skin Development and Rupture during Sol-Gel Spin-Coating. J. Solgel Sci. Technol. 2004, 31, 225-228.
10. Uchiyama, H.; Matsui, T.; Kozuka, H. Spontaneous Pattern Formation Induced by Bénard–Marangoni Convection for Sol–Gel-Derived Titania Dip-Coating Films: Effect of Co-Solvents With a High Surface Tension and Low Volatility. Langmuir 2015, 31 (45), 12497-12504.
11. Sobac, B.; Colinet, P.; Pauchard, L. Influence Of Bénard–Marangoni Instability on The Morphology of Drying Colloidal Films. Soft Matter 2019, 15 (11), 2381-2390.
12. Chapman, N.; Chapman, M.; Euler, W. B. Evolution of Surface Morphology of Spin-Coated Poly (Methyl Methacrylate) Thin Films. Polymers 2021, 13 (13), 2184.
13. Kozuka, H. Radiative Striations in Spin-Coating Films. In Handbook of Sol-Gel Science and Technology: Processing, Characterization and Applications, Klein, L.; Aparicio, M.; Jitianu, A. Eds. Springer International Publishing: Cham, 2018; pp 313-331.
14. Haas, D. E.; Quijada, J. N.; Picone, S. J.; Birnie III, D. P. In Effect of Solvent Evaporation Rate on Skin Formation during Spin Coating of Complex Solutions. Sol-Gel Optics V, SPIE: 2000; pp 280-284.
15. Fan, X.; Wang, C.; Fei, L.; Zhou, Q.; Xue, Z.; Ma, J.; Ma, Y. Nascent Holes on Spin-Coated Polymer Nanofilms: Effect of Processing and Solvents. ACS Appl. Polym. Mater. 2022, 4 (4), 2767-2782.
16. De Gennes, P. G. Instabilities during The Evaporation of A Film: Non-Glassy Polymer+ Volatile Solvent. Eur. Phys. J. E 2001, 6, 421-424.
17. Chapman, N.; Chapman, M.; Euler, W. B. Modeling of Poly (Methylmethacrylate) Viscous Thin Films by Spin-Coating. Coatings 2021, 11 (2), 198.
18. Uchiyama, H.; Namba, W.; Kozuka, H. Spontaneous Formation of Linear Striations and Cell-Like Patterns on Dip-Coating Titania Films Prepared from Alkoxide Solutions. Langmuir 2010, 26 (13), 11479-11484.
19. Tyona, M. A Theoritical Study on Spin Coating Technique. Adv. Mater. Res. 2013, 2 (4), 195.
20. Mouhamad, Y.; Mokarian-Tabari, P.; Clarke, N.; Jones, R.; Geoghegan, M. Dynamics of Polymer Film Formation during Spin Coating. J. Appl. Phys. 2014, 116 (12), 123513.
21. Sahu, N.; Parija, B.; Panigrahi, S. Fundamental Understanding and Modeling of Spin Coating Process: A Review. Indian J. Phys. 2009, 83 (4), 493-502.
22. Schubert, D. W.; Dunkel, T. Spin Coating from A Molecular Point of View: Its Concentration Regimes, Influence of Molar Mass and Distribution. Mater. Res. Innov. 2003, 7 (5), 314-321.
23. Cochran, W. In The flow due to a rotating disc, Mathematical proceedings of the Cambridge philosophical society, Cambridge University Press: 1934; pp 365-375.
24. Rehg, T. J.; Higgins, G. Spin Coating of Colloidal Suspensions. AIChE journal 1992, 38 (4), 489-501.
25. Emslie, A. G.; Bonner, F. T.; Peck, L. G. Flow of A Viscous Liquid on A Rotating Disk. J. Appl. Phys. 1958, 29 (5), 858-862.
26. Shereda, L. T.; Larson, R. G.; Solomon, M. J. Local Stress Control of Spatiotemporal Ordering of Colloidal Crystals in Complex Flows. Phys. Rev. Lett. 2008, 101 (3), 038301.
27. Meyerhofer, D., Characteristics of resist films produced by spinning. J. Appl. Phys. 1978, 49 (7), 3993-3997.
28. Bornside, D.; Macosko, C.; Scriven, L. Spin Coating: One‐Dimensional Model. J. Appl. Phys. 1989, 66 (11), 5185-5193.
29. Flack, W. W.; Soong, D. S.; Bell, A. T.; Hess, D. W. A Mathematical Model for Spin Coating of Polymer Resists. J. Appl. Phys. 1984, 56 (4), 1199-1206.
30. Lawrence, C. The Mechanics of Spin Coating Of Polymer Films. Phys. Fluids 1988, 31 (10), 2786-2795.
31. Strawhecker, K. E.; Kumar, S. K.; Douglas, J. F.; Karim, A. The Critical Role of Solvent Evaporation on The Roughness of Spin-Cast Polymer Films. Macromolecules 2001, 34 (14), 4669-4672.
32. Gonuguntla, M.; Sharma, A. Polymer Patterns in Evaporating Droplets on Dissolving Substrates. Langmuir 2004, 20 (8), 3456-3463.
33. Mokarian-Tabari, P.; Geoghegan, M.; Howse, J.; Heriot, S.; Thompson, R.; Jones, R. Quantitative Evaluation of Evaporation Rate during Spin-Coating of Polymer Blend Films: Control of Film Structure Through Defined-Atmosphere Solvent-Casting. Eur. Phys. J. E 2010, 33, 283-289.
34. Wolf, C.; Gambaryan-Roisman, T. Wetting and Evaporation of Solvents on Thin Soluble Substrates. Colloids and Interfaces 2020, 4 (4), 48.
35. Müller-Buschbaum, P.; Gutmann, J. S.; Wolkenhauer, M.; Kraus, J.; Stamm, M.; Smilgies, D.; Petry, W. Solvent-Induced Surface Morphology of Thin Polymer Films. Macromolecules 2001, 34 (5), 1369-1375.
36. Bunz, U. H. F. Breath Figures as A Dynamic Templating Method for Polymers and Nanomaterials. Adv. Mater 2006, 18 (8), 973-989.
37. Park, M. S.; Joo, W.; Kim, J. K. Porous Structures of Polymer Films Prepared by Spin Coating with Mixed Solvents under Humid Condition. Langmuir 2006, 22 (10), 4594-4598.
38. Zhang, A.; Bai, H.; Li, L. Breath Figure: A Nature-Inspired Preparation Method for Ordered Porous Films. Chem. Rev. 2015, 115 (18), 9801-9868.
39. Park, M. S.; Kim, J. K. Breath Figure Patterns Prepared by Spin Coating in A Dry Environment. Langmuir 2004, 20 (13), 5347-5352.
40. Bang, J.; Kim, B. J.; Stein, G. E.; Russell, T. P.; Li, X.; Wang, J.; Kramer, E. J.; Hawker, C. J. Effect Of Humidity on The Ordering of PEO-Based Copolymer Thin Films. Macromolecules 2007, 40 (19), 7019-7025.
41. Benard, H. Experimental Studies on The Movement of Liquids Propagated by Heat by Means of Convection. Permanent System: Cellular Turbulence. Comptes Rendus Hebdomadaires Des Seances De L Academie Des Sciences 1900, 130, 1004-1007.
42. Rayleigh, L., LIX. On Convection Currents in A Horizontal Layer of Fluid, when The Higher Temperature is on The under Side. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 1916, 32 (192), 529-546.
43. Block, M. J. Surface Tension as The Cause of Bénard Cells and Surface Deformation in A Liquid Film. Nature 1956, 178, 650-651.
44. Pearson, J. On Convection Cells Induced by Surface Tension. J. Fluid Mech. 1958, 4 (5), 489-500.
45. Fowler, P. D.; Ruscher, C.; McGraw, J. D.; Forrest, J. A.; Dalnoki-Veress, K. Controlling Marangoni-Induced Instabilities in Spin-Cast Polymer Films: How to Prepare Uniform Films. Eur. Phys. J. E2016, 39, 1-8.
46. Bassou, N.; Rharbi, Y. Role of Benard− Marangoni Instabilities during Solvent Evaporation in Polymer Surface Corrugations. Langmuir 2009, 25 (1), 624-632.
47. Wang, T.-S.; Shi, W.-Y. Influence of Substrate Temperature on Marangoni Convection Instabilities in A Sessile Droplet Evaporating at Constant Contact Line Mode. Int. J. Heat Mass Transf. 2019, 131, 1270-1278.
48. Stowell, C.; Korgel, B. A. Self-Assembled Honeycomb Networks of Gold Nanocrystals. Nano Lett. 2001, 1 (11), 595-600.
49. Kang, E.-S.; Takahashi, M.; Tokuda, Y.; Yoko, T. Template-Free Magnesium Oxide Hollow Sphere Inclusion in Organic− Inorganic Hybrid Films via Sol− Gel Reaction. Langmuir 2006, 22 (12), 5220-5223.
50. Kabova, Y.; Kuznetsov, V.; Kabov, O.; Gambaryan-Roisman, T.; Stephan, P. Evaporation of A Thin Viscous Liquid Film Sheared By Gas in A Microchannel. Int. J. Heat Mass Transf. 2014, 68, 527-541.
51. Daubersies, L.; Salmon, J.-B. Evaporation of Solutions and Colloidal Dispersions in Confined Droplets. Phys. Rev. E 2011, 84 (3), 031406.
52. Nečas, D.; Klapetek, P. Gwyddion: An Open-Source Software for SPM Data Analysis. Open Phys. 2012, 10 (1), 181-188.
53. Wang, J.-F.; Li, C.-X.; Wang, Z.-H.; Li, Z.-J.; Jiang, Y.-B. Vapor Pressure Measurement for Water, Methanol, Ethanol, and Their Binary Mixtures in The Presence of An Ionic Liquid 1-Ethyl-3-Methylimidazolium Dimethylphosphate. Fluid Ph. Equilibria 2007, 255 (2), 186-192.
54. Ouaar, F.; Mokbel, I.; Negadi, A.; Aguilar, F.; Montero, E. A.; Jose, J.; Bahadur, I.; Negadi, L. Vapor–Liquid Equilibria, Density, Sound Velocity, and Refractive Index for Binary Mixtures Containing 2-(2-Ethoxyethoxy) Ethanol and 1-Propanol or 2-Propanol or 1-Butanol or 2-Butanol at Different Temperatures. J. Chem. Eng. Data 2020, 65 (5), 2351-2372.
55. Hansen, C. M. Hansen solubility parameters: a user′s handbook. CRC press: 2007.
56. Shiratori, S.; Kubokawa, T. Double-Peaked Edge-Bead in Drying Film of Solvent-Resin Mixtures. Phys. Fluids 2015, 27 (10), 102105.
57. Yun, J.-W.; Ullah, F.; Jang, S.-J.; Kim, D. H.; Nguyen, T. K.; Ryu, K. Y.; Cho, S.; Jang, J. I.; Lee, D.; Park, S. Ultrasonic-Assisted Spin-Coating: Improved Junction by Enhanced Permeation of a Coating Material within Nanostructures. ACS Appl. Mat. Inter. 2018, 10 (23), 20025-20031.
58. Muñoz-Bonilla, A.; Fernández-García, M.; Rodríguez-Hernández, J. Towards hierarchically Ordered Functional Porous Polymeric Surfaces Prepared by The Breath Figures Approach. Prog. Polym. Sci. 2014, 39 (3), 510-554.
59. Bormashenko, E. Breath-Figure Self-Assembly, A Versatile Method of Manufacturing Membranes and Porous Structures: Physical, Chemical and Technological Aspects. Membranes 2017, 7 (3), 45.
60. Munir, B.; Xu, Y. Effects of Gravity and Surface Tension on Steady Microbubble Propagation in Asymmetric Bifurcating Airways. Phys. Fluids 2020, 32 (7), 072105.
61. Malashenko, A.; Tsuda, A.; Haber, S. Propagation and Breakup of Liquid Menisci and Aerosol Generation in Small Airways. J. Aerosol Med. Pulm. 2009, 22 (4), 341-353.
62. Yang, Y.; Chen, X.; Huang, Y. Spreading Dynamics of Droplet Impact on A Wedge-Patterned Biphilic Surface. Appl. Sci. 2019, 9 (11), 2214.
63. Mamba, S. S.; Magniez, J.; Zoueshtiagh, F.; Baudoin, M. Dynamics of A Liquid Plug on A Capillary Tube under Cyclic Forcing: Memory Effects And Airway Reopening. J. Fluid Mech.2018, 838, 165-191.
64. Yabu, H. Fabrication of Honeycomb Films by The Breath Figure Technique and Their Applications. Sci. Technol. Adv. Mater. 2018, 19 (1), 802-822.
65. Escalé, P.; Rubatat, L.; Billon, L.; Save, M. Recent Advances in Honeycomb-Structured Porous Polymer Films Prepared via Breath Figures. Eur. Polym. J. 2012, 48 (6), 1001-1025.
66. Wu, S.-K.; Mo, T.-S.; Lin, J.-D.; Huang, S.-Y.; Huang, C.-Y.; Yeh, H.-C.; Chen, L.-J.; Lee, C.-R. Electrohydrodynamics-Induced Abnormal Electro-Optic Characteristics in a Polymer-Dispersed Liquid Crystal Film. Crystals 2017, 7 (7), 227.
67. Vohra, V.; Yunus, S.; Attout, A.; Giovanella, U.; Scavia, G.; Tubino, R.; Botta, C.; Bolognesi, A. Bifunctional Microstructured Films and Surfaces Obtained by Soft Lithography from Breath Figure Arrays. Soft Matter 2009, 5 (8), 1656-1661.
68. Cong, H.; Wang, J.; Yu, B.; Tang, J. Preparation of A Highly Permeable Ordered Porous Microfiltration Membrane of Brominated Poly (Phenylene Oxide) on An Ice Substrate by The Breath Figure Method. Soft Matter 2012, 8 (34), 8835-8839.
69. Liu, H.; Pang, B.; Zhang, K. Breath Figure Templated Self-Assembly of Surface-Acylated Cellulose Nanowhiskers Confined as Honeycomb Films. Cellulose 2021, 28, 10939-10951.
70. Hecht, U.; Schilz, C.; Stratmann, M. Influence of Relative Humidity during Film Formation Processes on The Structure of Ultrathin Polymeric Films. Langmuir 1998, 14 (23), 6743-6748.
71. Magnus, G. Versuche über die Spannkräfte des Wasserdampfs. Annalen der Physik 1844, 137 (2), 225-247.
72. Perović, B.; Klimenta, D.; Jevtić, M.;Milovanović, M. The Effect of Different Sky Temperature Models on the Accuracy in the Estimation of the Performance of a Photovoltaic Module. Journal of the Technical University of Gabrovo 2019, 59, 78-82.
73. Kita, Y.; Okauchi, Y.; Fukatani, Y.; Orejon, D.; Kohno, M.; Takata, Y.; Sefiane, K. Quantifying Vapor Transfer Into Evaporating Ethanol Drops in A Humid Atmosphere. Phys. Chem. Chem. Phys 2018, 20 (29), 19430-19440.
74. Li, M.; Lohse, D.; Huisman, S. G. High Humidity Enhances the Evaporation of Non-Aqueous Volatile Sprays. J. Fluid Mech. 2023, 956, A19.
指導教授 黃俊仁 孫亞賢(Huang Jun Ren Sun Ya-Sen) 審核日期 2023-7-25
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