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姓名 孫立中(Li-Chung Sun)  查詢紙本館藏   畢業系所 地球物理研究所
論文名稱 抑制鏡煤素反射率之量測成因-以分離台灣裕峰煤為例
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摘要(中) 在ZnCl2分離液對煤樣的熱裂分析的影響上,樣品分成原始樣、浸泡ZnCl2分離液及洗除ZnCl2分離液後之樣品。結果顯示:ZnCl2分離液對Tmax(熱解烴峰值溫度)、S1(游離烴)、S2(熱解烴)、TOC(總有機碳)及HI(氫指數)等之測定均有明顯下降的影響,但對IP(產率指數)並沒有產生影響。洗除ZnCl2分離液後,除IP有明顯下降外,其它熱裂參數幾乎可恢復如原始樣的情況。
在鏡煤素反射率受抑制的機制上,一種可能的原因是來自於量測的機率與垂直方向的透光問題;即在膜煤素高含量的情況下,拋光後所出現的鏡煤素薄層,當其達到透光的程度時,可以造成垂直方向的疊加透光效應,使得低值反射率被量測到的次數頻率增加,而平均反射率則向低值偏移。
摘要(英) Exinite-riched macerals were separated from coal samples by using density centrifugation of ZnCl2 solution. The frequency distributions of vitrinite reflectance were compared among original coal sample, washed coal sample and the separated exinite-riched sample, the probable reason for suppression of vitrinite reflectance can then be discussed. The suppression of vitrinite reflectance may be resulted from exinite underneath the measuring surface of thin-layered vitrinite.
關鍵字(中) ★ 鏡煤素反射率
★ 抑制
★ 分離
關鍵字(英) ★ vitrinite reflectance
★ supprission
論文目次 封面
論文提要
誌謝
目錄
圖目
表目
符號說明
第一章 緒言
1.1 研究動機與目的
1.2 內文簡介
第二章 文獻回顧與基本原理
2.1 煤岩學與有機成熟度
2.2 鏡煤素反射率之應用與仰制
2.3 熱裂分析
2.4 煤素質卅油母質的分離
2.5 結語
第三章 實驗方法
3.1 樣品的選取
3.2 煤樣製作與拋光
3.3 煤素質群的分析方法
3.4 鏡煤素反射率之測量
3.5 熱裂分析方法
3.6 煤素質的分離
3.7 結語
第四章 氯化鋅分離液之實驗結果與討論
4.1 熱裂分析之系統比較
4.2 熱裂分析之再現性
4.3 氯化鋅( ZnCl?)分離液對熱裂分析的影響
4.4 結語
第五章 鏡煤素反射率實驗結果與討論
5.1 前言
5.2 實驗方法
5.3 結果分析
5.4 討論
5.5 綜合討論
第六章 結論
參考文獻
附錄
圖版說明
英文摘要
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指導教授 蔡龍珆(Louis L. Tsai) 審核日期 2000-7-19
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