土壤對Triton 系列各EO鏈選擇性吸附之研究

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：8

、訪客IP：13.59.136.170

姓名

陳怡君(I-chun Chen ) 查詢紙本館藏

畢業系所

環境工程研究所

論文名稱

土壤對Triton 系列各EO鏈選擇性吸附之研究
(Selective sorption of some nonionic surfactant by soils)

相關論文

★ 工業廢水對灌溉水質影響之研究-以黃墘溪為例	★ 廢冷陰極管汞回收處理效率之研究
★ 室內懸浮微粒與生物氣膠之相關性探討-以某醫學中心為例	★ 化學機械研磨廢液對工業區污水處理效益與操作成本之影響
★ 網路數位電力監測系統於大學用電行為分析之研究	★ 光電業進行自願性碳標準(VCS)減量計畫可行性之研究
★ 污染農地整治後未能符合農用成因之探討	★ 桃園縣居家入侵紅火蟻防治方法探討
★ 印刷電路板產業濕式製程廢液回收鈀金屬可行性之研究	★ 不同表面特性黏土催化高分子凝聚劑與消毒劑(氯)反應之研究
★ 界面活性劑對土壤/水系統中有機污染物分佈行為之研究	★ 淨水程序中添加高分子凝聚劑對混凝與加氯處理效應之研究
★ 土壤無機相對揮發性有機污染物吸∕脫附行為之影響	★ 土壤有機質對土壤/水系統中低濃度非離子有機污染物吸附行為之研究
★ 不同表面特性黏土催化水中有機物之氯化反應研究	★ 分子間作用力影響土壤中非離子有機物傳輸行為之研究

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

[檢視]

[下載]

本電子論文使用權限為同意立即開放。
已達開放權限電子全文僅授權使用者為學術研究之目的，進行個人非營利性質之檢索、閱讀、列印。
請遵守中華民國著作權法之相關規定，切勿任意重製、散佈、改作、轉貼、播送，以免觸法。

摘要(中)

非離子界面活性劑具有高極性親水基（ethoxylated group）與低極性疏水基(alkylated group)的兩性結構，被土壤吸附後會改變土壤的吸附特性，進而影響土壤吸附有機污染物的分佈係數。本研究利用高效能液相層析質譜分析方法（LC/MS）來探討於不同平衡濃度下，土壤對非離子界面活性劑中各EO（ethoxylated group）鏈之選擇性吸附行為。
研究分別以三種不同性質的土壤(黏土、天然土壤與高有機質土)對含有不同EO鏈的非離子性界面活性劑(TX-100,TX-305,TX-405)分別進行吸附平衡實驗。對低極性的TX-100而言，吸附能力強的蒙特石呈現無選擇性的吸附結果；吸附能力較弱的高嶺土則容易吸附低EO鏈形成吸附性微胞。研究亦發現這兩種黏土對TX-305傾向於吸附高EO鏈的部份；TX-405則無選擇性吸附情形。天然土壤對Triton之吸附作用推測具有無機相吸附與有機質分佈兩種，其中紗帽山土對低極性TX-100的分佈作用較為明顯；而台中土則以大部分無機相吸附低EO鏈以形成吸附性微胞的方式與有機質分佈低EO鏈的作用為主，但這兩種天然土壤對高EO鏈的TX-305與TX-405吸附結果均比TX-100弱。含有高有機質土壤Ihss Florida Peat(I.F.P.)，其吸附低EO鏈的情形皆明顯大於高EO鏈，此結果係因為高有機質土IFP對低EO鏈有明顯的分佈作用。除了分佈作用外，IFP土壤中高極性的官能基對非離子界面活性劑中EO鏈組成具有氫鍵的作用，造成IFP對三種非離子界面活性劑的吸附量僅次於蒙特石。

摘要(英)

Triton X-100, Triton X-305 and Triton X-405 are mixtures of different ethoxylated group nonionic surfactant. When nonionic surfactant was sorbed onto soil surface, the sorption characteristics of soil and the partition coefficient of organic compounds can be profoundly changed.
In this study, we investigated selective sorption behavior of ethoxylated nonionic surfactant mixtures by various soils with High Performance Liquid Chromatography/ Mass Spectrometry technique. The sorption of TX-100 by Ca-Montmorillonite showed non-selective sorption behaviors. Among all surfactants tested, kaolin tended to sorption low EO groups for TX-100. On the other hand, clays preferred to adsorb higher EO groups for TX-305 and TX-405 . The result also indicated that low EO group surfactants are able to partition into the organic phase of Sao-Mao Hill soil and Tai-Chung soil. In addition to partition, we presumed that low EO nonionic surfactants formed admicelle on Tai-Chung soil surface. As a result, the absorption amount of surfactants on Tai-Chung soil was greater than that of Sao-Mao Hill soil. Since low EO group surfactants partitioning into the organic matter of Ihss Florida Peat (I.F.P.), the absorption capacity of TX-100 for I.F.P. was the greatest. A comparison of partitioning behavior, we also suggested that the hydrogen bond between the EO group of surfactants and function group of soil can enhance absorption capacity.

關鍵字(中)

★ 分佈作用
★ 環氧乙烷基
★ 選擇性吸附
★ 非離子界面活性劑
★ 高效率液相層析質譜儀

關鍵字(英)

★ High Performance Liquid Chromatography Mass Spectr
★ nonionic surfactant

論文目次

目錄
圖目錄
表目錄
第一章前言
1-1 研究緣起
1-2 研究目的與內容
第二章文獻回顧
2-1 土壤組成與基本性質
2-2-1土壤組成
2-2-2 土壤基本性質
2-2非離子性界面活性劑
2-2-1非離子性界面活性劑種類
2-2-2 界面活性劑之基本特性
2-2-3非離子型界面活性劑之分析方法
2-3土壤吸持界面活性劑作用
2-3-1土壤吸持作用
2-3-2有機相之分佈作用
2-4 非離子性界面活性劑於土壤/水系統吸持行為
2-4-1土壤吸附界面活性劑的模式
2-4-2土壤吸附非離子性界面活性劑之影響因子
2-4-3土壤吸附非離子性界面活性劑
2-5非離子型界面活性劑對有機物分佈與傳輸之影響
第三章實驗設備、材料、方法
3-1研究架構
3-2實驗設備
3-3實驗材料
3-3-1土樣
3-3-2非離子界面活性劑
3-3-3 移動相溶劑
3-4高效能液相層析/質譜分析非離子界面活性劑之方法
3-4-1系統平衡與調機.
3-4-2非離子型界面活性劑液相層析/質譜分析方法.
3-5非離子性界面活性劑於土壤/水系統之吸附實驗
第四章結果與討論
4-1 Triton 系列之液相層析/質譜定量方法建立
4-1-1 Triton 系列之特徵質譜圖
4-1-2 Triton系列質譜定量方法建立
4-1-3 檢量線建立
4-2 土壤對各EO鏈選擇性吸附之影響因子探討
4-2-1土壤性質對EO鏈分佈的影響
4-2-1-1蒙特石之吸附結果
4-2-1-2高嶺土之吸附結果
4-2-1-3紗帽山土之吸附結果
4-2-1-4台中土之吸附結果
4-2-1-5 IFP之吸附結果
4-2-2 界面活性劑平衡濃度對土壤吸附Triton系列之影響
4-2-2-1 Triton X-100的吸附情形
4-2-2-2 Triton X-305的吸附情形
4-2-2-3 Triton X-405的吸附情形
4-2-3 EO鏈長短對土壤吸附Triton系列之影響
第五章結論與建議
5-1 結論
5-2 建議
參考文獻

參考文獻

1.Adeel , Z., and Luthy, R. G., “Sorption and Transport Kinetics of a Nonionic Surfatant through an Aquifer Sediment”, Environ. Sci. Technol., 29, p.1032-1042(1995)
2.Anna , A., and Janusz, B. P., “Solid-Phase Microextration Coupled with High-Performance Liquid Chromatography for The Determination of Alkyphenol Ethoxylate Surfactanyts in Water ” Anal. Chem., 68, pp.1521-1529(1996)
3.Antonio D. C.,“Characterization of Surfactants and Their Biointermediates by Liquid Chromatography-Mass Spectrometry”, Journal of Chromatography A, 794, pp165-185(1998)
4.Brinck , J.; Bengt, J. and Fredrik T.,“Influence of Long-Chain Alcohols on the Adsorption of Nonionic Surfactants to Silica” Langmuir, 15, p.7719-7724(1999)
5.Brown, M. A., Liquid Chromatography/Mass Spectrometry- Applications in Agrcultural, Pharmaceutical, Environmental Chemistry, American Chemical Society, Washington, DC (1990)
6.Bruce , J. B.; Chen, Hua ;Wanjia Z. and John C. W., “Sorption of Nonionic Surfactants on Sediment Materials” Environ. Sci. Technol., 31, p.1735-1741 (1997)
7.Cano, M. L. and Philip, B. D., “Sorption of Two Model Alcohol Ethoxylate Surfactants to Sediment ” Chemosphere, 33, 6,PP.981-994(1996)
8.Chiou, C. T., “The Surface Area of Soil Organic Matter ” Environ. Sci. Technol., 24, p.1164-1166(1990)
9.Fytianos, K.; Pegiadou, S.; Raikos, N.; Eleftheriadis, I. and Tsoukali, H,“Determination of Nonionic Surfactants (polyethoxylated nonylphenols) by HPLC in Waste Water” Chemosphere , 35, 7, pp.1423-1429(1997)
10.Gu, T.; Zhu, B.-Y and Rupprecht, H., “Surfactant Adsorption and Surface Micellization ” Progress in Colloid and Polymer Science, 88 , p.74-85(1992)
11.Heinig, K., Vogt, C., Werner , G.,“Separation of Ionic and Neutral Surfactants by Capillary Electrophoresis and High-Performance Liquid Chromatography”, Journal of Chromatography A., 745, p. 281-292(1996)
12.Kamiusuki, T.; Takashi, M.; Nemoto, F.; Takeo; Konakahara, Y. T. “Separation and Characterization of Octylphenol Ethoxylate Surfactants Used by Reversed-Phase High-Performance Liquid Chromatography on Branched Fluorinated Silica Gel Column ”, Journal of Chromatography A., 852, p.475-485 (1999)
13.Kibbey, T.C.G., Hayes, K. F. “A Multicomponent Analysis of The Sorption of Polydisperse Ethoxylated Nonionic Surfactants to Aquifer Materials :Equilibrium Sorption Behavior” Environ. Sci. Technol., 31, p.1171-1777(1997)
14.Kibbey, T.C.G., Hayes, K.F. “A Predictive Numerical Thermodynamic Model of Mixed Nonionic Surfactant Sorption in Natural Systems (1.model formulation and sensitivity analysis)”Journal of Colloid and Interface Science, 197, p.198-209(1998)
15.Kibbey, T.C.G., Hayes, K. F. “A Predictive Numerical Thermodynamic Model of Mixed Nonionic Surfactant Sorption in Natural Systems (2.application to broadly distributed mixtures) ” Journal of Colloid and Interface Science, 197, p.210-220(1998)
16.Kibbey, T.C.G., Hayes, K. F. “Effect of Surfactant Concentration and Sorbent Properties on the Sorption and Transport of Ethoxylated Nonionic Surfactant Mixtures” Journal of Contaminant Hydrology , 41, p.1-22(2000)
17.Kibbey, T.C.G. ; Yavaraski, T. P.; Hayes,K.F.,“High-Performance Liquid Chromatographic Analysis of Polydisperse Ethoxylated Nonionic Surfactants in Aqueous Sample” Journal of Chromatography A. , 752 , P155-165 (1996)
18.Kiewiet, A.T.,and Vogt,P. D., “Chromatographic Tools for Analyzing and Tracking Non-ionic Surfactants in the Aquatic Environment (review) ”, 733, pp. 185-192(1996).
19.Liu , Z.; Edward, D. A. and Luthy, R. G. “ Sorption of Nonionic Surfactants onto Soil ” Water Res., 26, 10, PP.1337-1345 (1992)
20.Marcomini,A., and Pojana,G., “Surfactant Metabolites in Environmental Aqueous Samples: a Liquid Chromatographic Approach to The Routine Analysis of Alcohol Polyethoxylate Biointermediates” Water Analysis, M 35 (1998).
21.Marcomini, A.,and Zanette, M., “Chromatographic Determination of Non-ionic aliphatic Surfactants of the Alcohol Polyethoxylate Type in the Environment” Journal of Chromatography A, 733, pp. 193-126(1996).
22.Maruyama, K.; Yuan,M. and Otsuki A., “ Seasonal Changes in Ethylene Oxide Chain Length of Poly(oxyethylene) Alkylphenyl Ether Nonionic Surfactants in Three Main River in Tokyo ”,Environ. Sci. Technol., 34, p.343-348(2000)
23.Mira , P.,and Damia, B.,“Determination of Anionic and Nonionic Surfactants, Their Degradation Products, and Endocrine-Disrupting Compounds in Sewage Sludge by Liquid Chromatography/Mass Spectrometry”，Analytical Chemistry A (2000)
24.Montserrat, C.; Francesc,V. and Damia ,B.,“Sequential Solid Phase Extraction Protocol Followed by Liquid Chromatography Atomospheric Pressure Chemical Ionization-Mass Spectrometry for The Trace Determination of Nonionic Polyethoxylated Surfactants in Tannery Waste Waters ”, Waste Management, 19, pp101-110(1999)
25.Niessen; W. M. A. and Greef, J. V. D., Liquid Chromatography-Mass Spectrometry: Principles and Applications, Marcel Dekker, Inc., New York (1992).
26.Nissen; W. M. A. and Tinke A. P., “Liquid Chromatography-Mass Spectrometry-General Principles and Instrumentation (review)” Journal of Chromatography A., 703, pp.37-57(1995).
27.Nissen; W. M. A., “Advances in Instrumentation in Liquid Chromatography-Mass Spectrometry and Related Liquid- Introduction Techniques (review)” Journal of chromatography A., 794, pp.407-435 (1998).
28.P. L. F.;Charles, R. I. and Bruce, J. B., “ Analysis of Alkylphenol Ethoxylate Metabolites in The Aquatic Environment Using Liquid Chromatography-Electrospray Mass Spectrometry” Anal. Chem., 72 , pp.4322-4330(2000)
29.Plaza , M., and Pons, R.,“Study of Nonionic Surfactant Polarity By High-Performance Liquid Chromatography” Colloids and Surfaces A., 137, P 287-193 (1998)
30.Shang, D.Y ; Ikonomou, M.G., and Macdonald, R.W., “Quantitative Determination of Nonylphenol Polyethoxylate Surfactants in Marine Sediment Using Normal-Phase Liquid Chromatography- Electrospray Mass Spectrometry,” Journal of Chromatography A, 849, pp. 467-482 (1999).
31.Shen Y.-H.,“Sorption of Nonionic Surfactants to Soil: The Role of Soil Mineral Composition” Chemosphere , 41, p.711-716(2000)
32.Simon, D. S.; Malcolm, R. C.; Michael, C., and Alison E. A. “Determination of Surfactants in Surface Water by Solid-Phase Extraction, Liquid Chromatography and Liquid Chromatography Mass Spectrometry ”, Journal of Chromatography A, 733, pp207-216(1996)
33.W. W. J.; Gaobin , B.; Johnson W. P. and Stauffer T. B. “Sorption of Nonionic Surfactant Oligomers to Sediment and PCE DNAPL:Effect on PCE Distribution between Water and Sediment” , Environ. Sci. Technol., 34, p.672-679(2000)
34.Yuan, C., and Jafvert, C. T. “Sorption of Linear Alcohol Ethoxylate Surfactant Homologs to Soil” Journal of Contaminant Hydrology, 28, p.311-325(1997)
35.Zanette, M.; Antonio, M.; Marchiori, E., and Roberto, S.,“High Performance Liquid Chromatographic-Fluorescence Determination of Aliphatic Alcohol Polyethoxylates and Polyethylene glycols in Aqueous Sample”, Journal of Chromatography A., 756, p. 159-174 (1996)
36.王一雄，“土壤環境污染與農藥”，文海環境科學叢書，初版（1999）
37.李育輯，“土壤吸附非離子性界面活性劑對土壤/水系統中有機污染物分佈行為之影響” 中央大學環境工程研究所碩士論文，八十八年六月

38.洪崑煌，“土壤化學”，國立編譯館，初版（1996）
39.美商渥特斯儀器網站，http://www.waters.com (2000)
40.孫逸民、陳玉舜、趙明學、劉興鑑，儀器分析，全威圖書有限公司，臺北(1997)
41.液相層析串聯質譜儀於結構分析之應用，科儀新知，20（6），p81-87(88)
42.液相層析質譜術介面發展與應用，科儀新知，13（5），p38-52(81)
43.郭俊智，“界面活性劑於土壤/水系統中有機污染物分佈行為之影響” 中央大學環境工程研究所碩士論文，八十七年六月

44.陳百合，“不同土壤組成對界面活性劑吸附機制之研究”中央大學環境工程研究所碩士論文，八十六年六月

45.趙承琛，“界面科學基礎”，復文書局，十五版（1995）
46.質譜分析術專輯，國科會精儀中心，臺北。
47.質譜儀，科儀新知，19（2），p31-39(87)
48.閻誠麟，“不同類型界面活性劑對黏土礦物吸附非離子有機污染物之影響” 中央大學環境工程研究所碩士論文，八十六年六月

指導教授

李俊福(Jiunn-Fwu Lee)

審核日期

2001-7-13

推文