金屬粉末射出成型三維毛細吸附脫脂觀察與分析

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姓名

范智文(Zhi-Wen Fan) 查詢紙本館藏

畢業系所

機械工程學系

論文名稱

金屬粉末射出成型三維毛細吸附脫脂觀察與分析

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摘要(中)

在金屬粉末射出成形過程中，脫脂的步驟影響很大，主要原因是在於其過程極為耗時，和脫脂不當會導致成品易產生損壞。故為限制整個金屬射出成型產能的主要關鍵。
本研究以三維毛細吸附脫脂實驗為主使用金屬粉末而非鋼珠模擬以接近實際脫脂情形；做一吸附實驗，以空孔度、胚體厚度、脫脂溫度、不同吸附材粉末粒徑、不同胚體粉末粒徑為變因，探討這些變因對脫脂百分比的影響性，得到配合小胚體厚度和吸附材粉末粒徑要小，胚體粉末粒徑要大或是高胚體空孔度，以及適當的脫脂溫度可得到較快的脫脂百分比以及脫脂過程中無因次參數的變化加以分析，可知毛細力為主導吸附脫脂的主要力量，其次推導出一套符合本實驗中二維吸附部分的數值模擬，以探討理想的狀況下，胚體的脫脂百分比與脫脂時間之間的相互關係。兩者相互比對，可明白在脫脂過程中，理論模擬與實驗操作的差異性。

摘要(英)

Among the MIM processes, debinding is the most important and time-consuming step. Failing in this key process always leads to the overall failure of the MIM product. Therefore, it is the key point of the limiting the production rate of the MIM process.
To analyze the three dimension of wick debinding process, the influence of five different factors (porosity, compact height, debinding temperature, wick powder size, compact powder size) on the final debinding percentage is investigated. Results show that high porosity compact, small wick powder size, large compact powder size, and appropriate debinding temperature can increase the debinding percentage. By the dimensionless analysis of the parameters in debinding process, the capillary force is found to be the main driving force in the wick debinding. Furthermore, a mathematic of model is derived to simulate the idealized, two-dimensional debinding process, and the debinding percentage versus debinding time is calculated. The difference between simulation and experiment is compared and analyzed.

關鍵字(中)

★ 毛細力
★ 脫脂百分比
★ 空孔度
★ 毛細吸附脫脂
★ 金屬粉末射出成形

關鍵字(英)

★ metal powder injection molding
★ porosity
★ wick debinding
★ debinding percentage
★ capillary force

論文目次

中文摘要..................................................................................................Ⅰ
英文摘要..................................................................................................Ⅱ
目錄..........................................................................................................Ⅲ
表目錄.......................................................................................................V
圖目錄......................................................................................................VI
符號說明..................................................................................................Ⅸ
第一章序論............................................................................................1
1-1 起源...................................................................................1
1-2 MIM成形技術..................................................................2
1-2-1 MIM製造程序.....................................................2
1-2-2 MIM的優缺點.....................................................4
1-3 影響MIM成品的因子.....................................................5
1-3-1 粉末原料............................................................6
1-3-2 黏結劑.................................................................8
1-3-3 脫脂技術.............................................................9
1-4 MIM脫脂的分類............................................................10
1-5 文獻回顧.........................................................................13
1-6 研究方向.........................................................................20
第二章理論模式..................................................................................22
2-1 統御方程式.....................................................................22
2-2 空孔度.............................................................................23
2-3 滲透度.............................................................................24
2-4 毛係壓力.........................................................................25
2-5 飽和度.............................................................................26
2-6 無因次參數.....................................................................27
2-7 基本假設與數學模式.....................................................28
第三章實驗裝置與步驟......................................................................31
3-1 實驗設備.........................................................................31
3-2 實驗材料.........................................................................34
3-3 實驗方法.........................................................................35
3-3-1 胚體壓製...........................................................35
3-3-2 胚體脫脂...........................................................36
3-3-3 影像與數據擷取...............................................36
3-4 注意事項.........................................................................37
第四章結果與討論..............................................................................39
4-1 重力對毛細脫脂脂影響 .....................................................39
4-2 吸附材平均飽和度和其粒徑大小及胚體空孔度之
關係................................................................................40
4-3 空孔度對對毛細吸附脫脂的影響.................................41
4-4 胚體厚度對三維毛細吸附脫脂的影響.........................42
4-5 脫脂溫度和胚體粒徑對三維毛細吸附脫脂的影響….45
4-6 不同吸附材粒徑下的三維毛細吸附脫脂………...........46
4-7 無因次參數...................................................................47
第五章結論..........................................................................................49
參考文獻..................................................................................................52
表目錄
表 1-1 MIM與P/M特性比較............................................................56
表 3-1a 黏結劑和鐵粉性質表.............................................................57
表 3-1b 鋁粉性質表.............................................................................58
圖目錄
圖 1-1 MIM製造流程圖[2]...............................................................59
圖 1-2 MIM產品設計優勢[4]...........................................................60
圖 1-3 工業上脫脂技術的分野.........................................................61
圖 1-4 MIM熱脫脂示意圖[13]...........................................................62
圖 2-1 粉末在不同幾何配置下的堆疊狀態[25]..................................63
圖 2-2 毛細脫脂飽和度示意圖...........................................................64
圖 2-3 二維吸附胚體模型示意圖.......................................................65
圖 2-4 數值模擬胚體脫脂百分比與脫脂時間關係...........................66
圖 3-1 胚體壓製實驗裝置圖...............................................................67
圖 3-2 胚體脫脂模具圖.......................................................................68
圖 3-3a 實驗步驟流程圖-胚體壓製......................................................69
圖 3-3b 實驗步驟流程圖-胚體脫脂.....................................................70
圖 4-1 以全包覆吸附脫脂流動波前剖面圖.......................................71
圖 4-2 不同吸附材粒徑下的飽和度...................................................72
圖 4-3 二維毛細吸附時，不同胚體空孔度之脫脂百分比變化圖…73
圖 4-4 三維毛細吸附時，不同胚體空孔度之脫脂百分比變化圖…74
圖 4-5 在不同胚體厚度下，脫脂百分比之變化圖...........................75
圖 4-6 胚體厚度5mm其流動波前剖面圖.........................................76
圖 4-7 胚體厚度9mm其流動波前剖面圖.........................................77
圖 4-8 不同溫度下，脫脂百分比之變化圖........................................78
圖 4-9 脫脂時間為40分鐘時，溫度和脫脂百分比之變化圖..........79
圖 4-10 不同胚體粒徑下之脫脂百分比變化圖.................................80
圖 4-11 胚體粒徑15μm其流動波前剖面圖......................................81
圖 4-12(a) 不同吸附材粒徑下之脫脂百分比變化圖........................82
圖 4-12(b) 不同吸附材粒徑下之脫脂百分比變化圖........................83
圖 4-13 不同脫脂溫度下之無因次參數變化圖.................................84
圖 4-14 不同胚體厚度下之無因次參數變化圖.................................85

參考文獻

參考文獻
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指導教授

洪勵吾(Lih-Wu Hourng)

審核日期

2005-6-29

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