以現有規範初判粒料的鹼質與碳酸鹽反應活性之研究

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姓名

王巧吟(Chiao-Yin Wang) 查詢紙本館藏

畢業系所

土木工程學系

論文名稱

以現有規範初判粒料的鹼質與碳酸鹽反應活性之研究
(The study of scan for the aggregates if have ACR activity by going standard)

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摘要(中)

台灣擁有豐富的碳酸鹽類岩石，但台灣對鹼-碳酸鹽反應(ACR)的研究卻不多。本研究利用加拿大化學法(CSA A23.2-26A)普查可能具有ACR活性的粒料，規劃第二次取料的項目，再區分ASTM系統(ASTM C 586、ASTM C 1105、ASTM C 1293)、RILEM系統(RILEM TC 191-ARP-AAR-2、RILEM TC 191-ARP-AAR-5)、加拿大系統(CSA A23.2-26A、CSA A23.2-14A)、模擬中國蒸壓法進行粒料的ACR活性探討及在台灣地區的適用性分析，以微觀分析(SEM、XRD)輔助判別粒料活性，並以LiOH溶液區分粒料的AAR特性。結果顯示，具有ACR活性粒料共14種，其中二種同時具有ASR活性；ASTM及RILEM檢測粒料ACR活性系統均適合於台灣地區使用。綜合試驗結果，提出適用於台灣地區粒料ACR活性檢測的流程為，先以ASTM C 586或RILEM TC 191-ARP-AAR-5試驗法篩選粒料的ACR活性，判定為非活性粒料，可以直接用為混凝土用粒料，若判定具有ACR活性，在使用前應再經ASTM C 1105試驗作最終ACR活性判別，屬非活性方能使用。

摘要(英)

There are many carbonate rocks in Taiwan, but less study of alkali-carbonate reaction (ACR) in Taiwan. The research use the Canada chemical method (CSA A23.2-26A) to embryonic exploration the aggregates which may have alkali-carbonate reaction, and plan for second collect the aggregates. We proceed to treat ACR activity of the aggregates and analyze the applicability in Taiwan by the system of ASTM(ASTM C 586、ASTM C 1105、ASTM C 1293)、the system of RILEM(RILEM TC 191-ARP-AAR-2、RILEM TC 191-ARP-AAR-5)、the system of Canada(CSA A23.2-26A、CSA A23.2-14A)、the imitate autoclave method of China. Use micro-analyses(SEM、XRD)to assist identify activity of the aggregate, and use LiOH solution to discriminate AAR characteristic of the aggregate. The result of test show there are fourteen kinds of aggregates have ACR activity, and two kinds among fourteen kinds of aggregates which have ACR activity all have ASR activity. The system of ASTM and RILEM both adaptable to use to identify the aggregates which have ACR in Taiwan. Composite the result of test, and advance the procedure which adaptable to identify the aggregates which have ACR in Taiwan. First, using ASTM C 586 or RILEM TC 191-ARP-AAR-5 to scan for the aggregates if have ACR activity. If the aggregate is identified have no ACR activity, it can direct use in concrete. If the aggregate is identified have ACR activity, it need use ASTM C 1105 to finally identify if have ACR activity, and check it have no ACR activity before used.

關鍵字(中)

★ 白雲岩
★ 石灰岩
★ 砂漿棒
★ 角柱
★ 鹼-碳酸鹽反應

關鍵字(英)

★ dolomite
★ limestone
★ Alkali-carbonate reaction
★ concrete prism
★ mortar-bar

論文目次

摘要 1
目錄 3
表目錄 6
圖目錄 7
第一章研究動機內容及目的 1
1-1 研究動機 1
1-2 研究內容 2
1-3 研究目的 2
第二章文獻回顧 3
2-1 鹼質與粒料反應分類及反應機理 3
2-1-1 鹼-氧化矽反應 3
2-1-2 鹼-矽酸鹽反應(Alkali-Silicate Reaction) 4
2-1-3 鹼-碳酸鹽反應 5
2-2 區分鹼-碳酸鹽反應與鹼-氧化矽反應的方法 9
2-3 鹼-碳酸鹽反應預防方法 10
2-4 鹼-碳酸鹽反應問題的預防策略 10
2-5 鹼-碳酸鹽反應鑑定方法介紹 11
2-5-1 ASTM系統 11
2-5-2 RILEM系統 13
2-5-3 加拿大系統 15
2-5-4 其他試驗方法 17
第三章試驗規畫 25
3-1試驗計畫 25
3-1-1粒料採集 25
3-1-2 試驗方法與試驗流程 31
3-2 試驗材料 33
3-3 試驗器材 35
3-4 試驗步驟 36
3-4-1 粒料處理 36
3-4-2 ASTM系統 37
3-4-2 RILEM系統 40
3-4-3 加拿大系統 42
3-4-4 其他試驗法 44
第四章試驗結果分析與討論 48
4-1 初期試驗 48
4-2 後續單一試驗結果分析 49
4-2-1 XRD 49
4-2-2化學法(CSA A23.2-26A) 58
4-2-3 ASTM系統 60
4-2-4 RILEM系統 61
4-2-5 模擬中國蒸壓法 63
4-2-6 LiOH判別 63
4-2-7 SEM 64
4-3 後續實驗結果比較 73
4-3-1 ASTM C 1105與其他試驗比較 74
4-4 綜合討論 85
4-4-1 台灣東部地區石灰岩粒料ACR活性判斷 85
4-4-2 各試驗對台灣東部地區鹼-碳酸鹽反應活性粒料判斷的適用性 87
第五章結論與建議 89
5-1 結論 89
5-2建議 90
參考文獻 91

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指導教授

李釗(Chau Lee)

審核日期

2008-7-21

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