開發新穎的釕金屬錯合物敏化劑應用於染料敏化太陽能電池

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：18

、訪客IP：3.17.79.60

姓名

王俊棠(Jiun-Tang Wang) 查詢紙本館藏

畢業系所

化學學系

論文名稱

開發新穎的釕金屬錯合物敏化劑應用於染料敏化太陽能電池
(Synthesis of novel ruthenium sensitizers for dye-sensitized solar cells)

相關論文

★ 固相組合式合成Dioxopiperazine與Carbolinone衍生物	★ 一、開發組合式藥物合成所需具安全閥(Safety Catch)之鍵鏈劑二、開發新型紫外光吸收劑
★ 1. 固相組合式合成benzoimidazolone 衍生物 2. 研發新型有機盤狀液晶	★ 一、液相合成carbolinone衍生物二、有機雜環液晶之合成與探討
★ 1. 具安全閥(safety-catch)之新型鍵鏈劑應用於組合式化學之合成 2. 合成含羧酸基短鏈式之有機污染衍生物	★ 合成新穎非可逆擬胜肽小分子蛋白質酪胺酸磷酸酶 1B 抑制劑
★ 固相組合式合成Isoquinolinone及Carbolinone 衍生物	★ 利用固相合成方法開發新型紫外線吸收劑 (UV-absorbers)
★ 研發及製備銥(Ir)金屬環狀錯合物之新型Ligand	★ 合成銥金屬錯合物發光材料
★ 開發固相合成法製備銥(Ir)錯合物之發光體	★ 1.合成環境荷爾蒙烷基酚聚乙氧基酸衍生物 2.固相組合式合成蛋白質酪胺酸磷酸
★ 設計與合成銥金屬錯合物藍光材料	★ 開發可應用於組合式合成烯類化合物之新型具安全閥鍵鏈劑
★ 利用有機金屬組合式合成加速紅色磷光材料的篩選與開發	★ 固相組合式合成新穎蛋白質酪胺酸磷酸酶1B抑制劑

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

至系統瀏覽論文 ( 永不開放)

摘要(中)

開發新的替代能源為各國家努力投資的方向，其中直接使用太陽能來發電為目前最為可能的替代能源之一。染料敏化太陽能電池(DSSC)為太陽能電池中近幾年來被廣為研究探討的課題，原因在它的製備成本在所有太陽能電池為最低的。染料敏化太陽能電池(DSSC)的主要光電轉換核心為染料，其中目前使得光電轉換效率最好最穩定的染料為N3、N719及Black dye，其轉換效率約10%。
　　本篇論文為開發新穎的染料，我們設計的金屬錯合物中含有carbene與金屬的錯合，期望在此新型的有機金屬結構能有更好的光電轉換效率及穩定度。

摘要(英)

Increasing energy demands and concerns over global warming have led to a greater focus on renewable energy sources in recent years. The conversion of solar energy is likely to play a key role as one of the technologies in the generation of mass energy. However, the current high cost of solar panels made from traditional inorganic semiconductors imposes a restriction on their mass usage.
Alternative cheaper solar energy technologies are therefore under intensive study and in this context dye-sensitized solar cells have emerged as an important class of photovoltaic device to obtain robust, efficient and cheap devices that are suitable for practical use.
Dyes play an important role in dye-sensitized solar cells. N3, N719 and Black dyes are the best known stable dyes having more than 10 % power conversion efficiency.
The purpose of this project is to develop novel dye component for DSSC. N-heterocyclic carbene based ruthenium complex was designed in order to obtain high thermostability and high conversion efficiency than the known dyes.

關鍵字(中)

★ 釕金屬錯合物
★ 染料
★ 染料敏化太陽能電池

關鍵字(英)

★ dye
★ DSSC
★ Ruthenium complex

論文目次

目錄
謝誌………………………………………………………………………………Ⅰ
中文摘要…………………………………………………………………………Ⅱ
ABSTRACT…………………………………………………………………………Ⅲ
圖目錄……………………………………………………………………………Ⅴ
表目錄……………………………………………………………………………Ⅶ
附圖目錄…………………………………………………………………………Ⅷ
第一章序論………………………………………………………………………１
1-1前言…………………………………………………………………………１
1-2太陽能電池的發展及種類…………………………………………………２
1-3染料敏化太陽能電池(Dye-Sensitivity Solar Cell)…………………４
1-3-1染料敏化太陽能電池的工作原理………………………………………４
1-3-2太陽能電池電壓–電流輸出特性………………………………………７
1-3-3 染料敏化太陽能電池(DSSC)的組成……………………………………９
1-3-4近年來一些重要的染料介紹……………………………………………11
1-4什麼是N-heterocyclo carbene？…………………………………………17
第二章結果與討論…………………………………………………………………19
第三章實驗流程與光譜數據……………………………………………………36
3-1 實驗儀器……………………………………………………………………36
3-2 實驗藥品……………………………………………………………………37
3-3 各實驗步驟與光譜數據……………………………………………………38
參考文獻…………………………………………………………………………46
附圖………………………………………………………………………………50

參考文獻

1. Brian O’Regan; Michael Grätzel, Nature. 1991, 353, 737.
2. M. K. Nazeeruddin; A. Kay; I. Rodicio; R. Humphry-Baker; E. Mueller, P.
Liska; N.Vlachopoulos; and M. Graetzel, JACS. 1993, 115, 6382.
3. Md. K. Nazeeruddin; S. M. Zakeeruddin; R. Humphry-Baker; M. Jirousek; P.
Liska; N.Vlachopoulos; V. Shklover; Christian-H. Fischer; and M. Grätzel;
Inorganic Chemistry. 1999, 38, 6298.
4. Wang. Peng; Zakeeruddin; Shaik M; Moser; Jacques E; Nazeeruddin;
Mohammad K; Sekiguchi, Takashi; Graetzel, Michael; Nature Material.
2003, 2, 402.
5. Hirata, Narukuni; Lagref, Jean-Jacques; Palomares, Emilio J; Durrant,
James R.; Nazeeruddin, M. Khaja; Gratzel, Michael; Di Censo, Davide.
Chemistry--A European Journal. 2004, 10, 595
6. Wang, Peng; Zakeeruddin, Shaik M.; Moser, Jacques E.; Humphry-Ba
ker, Robin; Comte, Pascal; Aranyos, Viviane; Hagfeldt, Anders;
Nazeer- uddin, Mohammad K.; Graetzel, Michael. Advance Material,
2004, 16, 1806
7. Wang, Peng; Klein, Cedric; Humphry-Baker, Robin; Zakeeruddin, Shaik M.;
Graetzel, Michael. JACS, 2005, 127. 808
8. Nazeeruddin, Mohammad K.; Wang, Qing; Cevey, Le; Aranyos, Viviane;
Liska, Paul; Figgemeier, Egbert; Klein, Cedric; Hirata, Narukuni; Koops,
Sara; Haque, Saif A.; Durrant, James R.; Hagfeldt, Anders; Lever, A. B. P.;
Graetzel, Michael. Inorg. Chem. 2006, 45, 787
9. Kuang, Daibin; Klein, Cedric; Ito, Seigo; Moser, Jacques-E.; Humphry-
Baker, Robin; Zakeeruddin, Shaik. M.; Gratzel, Michael. Adv. Funct. Mater.
2007, 17, 154
10.Kuang, Daibin; Klein, Cedric; Ito, Seigo; Moser, Jacques-E.;
Humphry-Baker, Robin; Evans, Nick; Duriaux, Francine; Gratzel, Carole;
Zakeeruddin, Shaik M.; Gratzel, Michael. Adv. Mater. 2007,19, 1133
11.Jiang, Ke-Jian; Masaki, Naruhiko; Xia, Jiang-bin; Noda, Shuji; Yanagida,
Shozo. Chem. Commun. 2006, 2460.
12.Chen, Chia-Yuan; Wu, Shi-Jhang; Wu, Chun-Guey; Chen, Jian-Ging; Ho,
Kuo-Chuan. Angew. Chem. Inter. Ed. 2006, 45, 5822
13.Chen, Chia-Yuan; Wu, Shi-Jhang; Li, Jheng-Ying; Wu, Chun-Guey; Chen,
Jian-Ging; Ho, Kuo-Chuan. Adv. Mater. 2007, 19, 388
14.Nazeeruddin, Mohammad K.; Pechy, Peter; Renouard, Thierry; Zakeeruddin,
Shaik M.; Humphry-Baker, Robin; Comte, Pascal; Liska, Paul; Cevey, Le;
Costa, Emiliana; Shklover, Valery; Spiccia, Leone; Deacon, Glen B.;
Bignozzi, Carlo A.; Graetzel, Michael. JACS, 2001, 123, 1613
15.Chemical Communication, 1995, 65
16.Wang, Peng; Klein, Cedric; Moser, Jacques-E.; Humphry-Baker, Robin;
Cevey-Ha, Ngoc-Le; Charvet, Raphael; Comte, Pascal; Zakeeruddin, Shaik
M.; Graetzel, Michael. J. Phys. Chem. B. 2004, 108, 17553.
17.Horiuchi, Tamotsu; Miura, Hidetoshi; Sumioka, Kouichi; Uchida, Satoshi.
JACS, 2004, 126, 12218
18.Wang, Zhong-Sheng; Cui, Yan; Hara, Kohjiro; Dan-oh, Yasufumi; Kasada,
Chiaki; Shinpo, Akira. Adv. Mater. 2007, 19, 1138
19.Garrison, Jered C.; Youngs, Wiley J. Chem. Rev. 2005, 105, 3978.
20.Anthony J. Arduengo, Richard L. Harlow, and Michael Kline. JACS, 1991,
113, 361
21.Scholl, Matthias; Ding, Sheng; Lee, Choon Woo; Grubbs, Robert H. Org.
Lett. 1999, 1, 953
22.Meier, Peter; Legraverant, Stephanie; Mueller, Sascha; Schaub, Josette.
Synthesis, 2003, 4, 551
23.Hoertz, Paul G.; Staniszewski, Aaron; Marton, Andras; Higgins, Gerard T.;
Incarvito, Christopher D.; Rheingold, Arnold L.; Meyer, Gerald J. JACS,
2006, 128, 8234
24.Li, Xianghong; Chen, Zhao; Zhao, Qiang; Shen, Li; Li, Fuyou; Yi, Tao;
Cao, Yong; Huang, Chunhui. Inorg. Chem. 2007, 46, 5518
25.Zhou, Hai-Bin; Liu, Guan-Sai; Yao, Zhu-Jun. Org. Lett. 2007, 9, 2003.
26.Wagaw, Seble; Buchwald, Stephen L. J. Org. Chem. 1996, 61, 7240
27.Wolfe, John P.; Buchwald, Stephen L. Tetra. Lett. 1997, 38, 6359.
28.Khramov, Dimitri M.; Boydston, Andrew J.; Bielawski, Christopher W. Org.
Lett. 2006, 8, 1831
29.Saravanakumar, Shanmuganathan; Oprea, Anca I.; Kindermann, Markus K.;
Jones, Peter G.; Heinicke, Joachim. Chemistry--A European Journal. 2006,
12, 3143
30.Page, Philip C. Bulman; Buckley, Benjamin R.; Christie, Steven D. R.;
Edgar, Mark; Poulton, Andrew M.; Elsegood, Mark R. J.; McKee, Vickie.
Jounal of Organometallic Chemistry. 2005, 690, 6210
31.Frank, Birgit; Beckert, Rainer; Rau, Sven; Goerls, Helmar. Zeitschrift fuer
Naturforschung, B: Chemical Sciences, 2005, 60, 771
32.Son, Seung Uk; Park, Kang Hyun; Lee, Young-Shin; Kim, Bo Yun; Choi,
Cheol Ho; Lah, Myoung Soo; Jang, Yun Hee; Jang, Du-Jeon; Chung, Young
Keun. Inorg. Chem. 2004, 43, 6896
33.Danopoulos, Andreas A.; Winston, Scott; Motherwell, William B. Chem.
Commun. 2002, 1376
34.Fuerstner, Alois; Krause, Helga; Ackermann, Lutz; Lehmann, Christian W.
Chem. Commun. 2001, 2240
35.Arduengo, Anthony J., III; Krafczyk, Roland; Schmutzler, Reinhard; Craig,
Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus.
Tetrahedron. 1999, 55, 14523
36.Saravanakumar, Shanmuganathan; Kindermann, Markus K.; Heinicke,
Joachim; Koeckerling, Martin. Chem. Commun. 2006, 640

指導教授

李文仁(Wen-Ren Li)

審核日期

2008-7-17

推文