博碩士論文 982203025 詳細資訊


姓名 柯明鑫(Ming-shin Ke)  查詢紙本館藏   畢業系所 化學學系
論文名稱 合成含氟苯并咪唑卡賓配位基的光敏染料運用於染料敏化太陽能電池
(Synthesis of a photosensitizer with a fluorine containing benzimidazole carbene ligand for dye sensitized solar cell application)
檔案 至系統瀏覽論文 (永不開放)
摘要(中) 本實驗室開發的N-Heterocyclic carbene-pyridine-based ruthenium染料結構,成功運用在染料敏化太陽能電池,在2010年發表在Angew. Chem. Int. Ed.,表現出高效率(η = 9.69%),超越過去公認所使用的N719染料(η = 8.98%)。
本論文則是以此結構為主體,合成出其含氟的多電子衍生物,預期其光電轉換效率有更進一步的突破。
摘要(英) The development of N-heterocyclic carbine-pyridine-based ruthenium dye structure in our laboratory, the successful use in dye-sensitized solar cells was published in Angew. Chem. Int. Ed.in 2010, showing high efficiency (η = 9.69%) beyond the recognized of N719 dye (η = 8.98%) in the past.
Therefore, the main structure in this thesis is synthesized for the fluorine-containing derivative, which will expect to be good in the efficient performance.
關鍵字(中) ★ 敏化染料太陽能電池 關鍵字(英) ★ dye-sensitized solar cells
論文目次 摘要......................................................i
Abstract.................................................ii
誌謝....................................................iii
目錄.....................................................iv
圖目錄....................................................v
表目錄...................................................vi
第一章 導論...............................................1
1-1  前言...............................................1
1-2  太陽能電池類型.....................................2
1-3  染料敏化太陽能電池.................................2
1-4  光電轉換原理介紹...................................3
1-5  有機染料...........................................5
1-6  其他金屬錯合物.....................................6
第二章 結果與討論.........................................7
2-1  含釕金屬結構染料...................................7
2-2  結構概念設計與動機.................................8
2-3  合成策略..........................................10
2-4  太陽能電池元件測試................................12
2-5  結論與未來展望....................................12
第三章 實驗部分..........................................13
3-1  實驗儀器..........................................13
3-2  實驗藥品..........................................13
3-3  實驗步驟..........................................15
參考文獻.................................................24
附圖.....................................................25
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[2] Vlachopoulos, N.; Liska, P.; Augustynski, J.; Grätzel, M., J. Am. Chem. Soc. 1988, 110, 1216.
[3] Mishra, A.; Fischer, M. K. R.; Bäuerle, P., Angew. Chem. Int. Ed. 2009, 48, 2474.
[4] Chia-Yuan Chen, Mingkui Wang, Jheng-Ying Li, Nuttapol Pootrakulchote, Leila Alibabaei, Cevey-ha Ngoc-le, Jean-David Decoppet Jia-Hung Tsai, Carole Grätzel, Chun-Guey Wu, * Shaik M. Zakeeruddin* and Michael Grätzel*, ACS Nano. 2009, 3, 3103-3109.
[5] Wei-Chun Chang, Huei-Siou Chen, Ting-Yu Li, Nai-Mu Hsu, Yogesh S. Tingare, Chung-Yen Li, Yi-Cheng Liu, Chaochin Su,* and Wen-Ren Li*, Angew. Chem. Int. Ed. 2010, 49, 8161 –8164
[6] Christian Burmester, Rüdiger Faust*, Synthesis 2008, 8, 1179–1181.
[7] T. Tu, W. Assenmacher, H. Peterlik, G. Schnakenburg, K. H. Doetz, Angew. Chem. Int. Ed. 2008, 47, 7127.
[8] L. Mercs, A. Neels, M. Albrecht, Dalton Trans. 2008, 5570.
[9] C.-Y. Chen, S.-J. Wu, C.-G. Wu, J.-G. Chen, K.-C. Ho, Angew. Chem. Int. Ed. 2006, 45, 5822.
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指導教授 李文仁(Wen-ren Li) 審核日期 2011-8-31

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