變溫吸附程序分離煙道氣中二氧化碳之連續性探討與實驗設計分析

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姓名

何宇軒(Yu-Xuan He) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

變溫吸附程序分離煙道氣中二氧化碳之連續性探討與實驗設計分析

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摘要(中)

近年由於溫室氣體引起的環境問題日益受到重視，溫室氣體減量計畫變得勢不容緩。而溫室氣體中的二氧化碳排放最主要來自於工業上化石燃料的燃燒，因此如何純化及回收煙道氣中的二氧化碳便顯得相當重要。
本研究以發電後所產生之煙道氣作為變溫吸附分離程序實驗的對象(15.03% CO2和84.97% N2)，所使用的吸附劑為依台電綜合研究所配方製備的聚苯胺固態CO2吸附劑，目的為藉微量天平實驗、貫流曲線實驗和變溫吸附實驗數據，分析連續操作所造成的暫時性或永久性特性變化，並利用實驗設計分析方法探討各操作變因（進料壓力、吸附溫度、脫附溫度、沖洗壓力等）對製程的影響，期望對未來建立量產製程與系統環境操作提供參考。

摘要(英)

Due to the environmental problems cased by greenhouse gases in recent years, the projects of reducing the emission of greenhouse gases become urgent. CO2 released into the atmosphere are mainly attributed to fossil fuel combustion, so the purification and recovery of CO2 from flue gas is the first important step in solving CO2 problem.
In this study, temperature swing adsorption process is utilized to separate CO2 and N2 from the power plant flue gas(15.03% CO2和84.97% N2) with solid polyaniline sorbent. By using Micro-Balance Thermo D-200, breakthrough curve experiment and temperature swing adsorption experiment, the property change of adsorbent cased by continuous operation can be analyzed. Also,using the method of experimental design analysis to investigate the change of CO2 concentration and recovery by varying the operating conditions(feed gas pressure, adsorption temperature, desorption temperature,purge pressure, etc), can provide references to the establishment of the mass production process and system operation in the future.

關鍵字(中)

★ 突破曲線
★ 實驗設計
★ 變溫吸附
★ 連續性操作

關鍵字(英)

★ temperature swing adsorption process
★ breakthrough curve
★ continuous operation
★ experimental design analysis

論文目次

第一章、緒論 - 1 -
第二章、簡介及文獻回顧 - 4 -
2-1 吸附現象簡介 - 4 -
2-1-1 變溫吸附法的基本原理 - 5 -
2-1-2 吸附劑及其選擇性 - 6 -
2-1-3 再生方法 - 7 -
2-1-4 等溫平衡吸附曲線 - 8 -
2-1-5貫流曲線 - 12 -
2-2聚苯胺固態二氧化碳吸附劑 - 13 -
2-2-1 胺基化處理 - 14 -
2-2-2 苯胺聚合物反應 - 19 -
2-3 變溫吸附程序（TSA）相關文獻 - 22 -
第三章、實驗 - 23 -
3-1聚苯胺固態CO2吸附劑之製備 - 23 -
3-1-1 實驗藥品 - 23 -
3-1-2 矽膠固著苯胺聚合物吸附劑製備流程 - 23 -
3-2等溫吸附平衡曲線實驗 - 26 -
3-2-1實驗裝置 - 26 -
3-2-2實驗步驟 - 31 -
3-2-3天平校正 - 32 -
3-2-4空白實驗 - 32 -
3-2-5連續變溫吸脫附實驗 - 33 -
3-3貫流曲線實驗 - 34 -
3-3-1 實驗裝置、各部規格及特性 - 34 -
3-3-2實驗系統參數與操作條件 - 38 -
3-3-3實驗步驟 - 39 -
3-4變溫吸附實驗 - 40 -
3-4-1實驗裝置、各部規格及特性 - 42 -
3-4-2實驗步驟 - 46 -
第四章、實驗結果與討論 - 49 -
4-1等溫吸附平衡曲線實驗結果與討論 - 49 -
4-1-1空白實驗結果 - 50 -
4-1-2 平衡吸附曲線實驗結果 - 54 -
4-1-3連續變溫吸脫附實驗 - 58 -
4-2貫流曲線實驗結果與討論 - 62 -
4-2-1塔內壓力及流速對貫流行為的影響 - 63 -
4-2-2 連續操作對貫流行為之影響 - 70 -
4-2-3 連續操作對不同批吸附劑貫流行為之影響 - 72 -
4-3變溫吸附實驗之實驗設計分析 - 73 -
4-3-1 殘差常態機率圖（Normal Probability Plot of the residuals）之分析 - 76 -
4-3-2變異數分析（Analysis of variance, ANOVA） - 83 -
4-3-3 Main Effect Plot與Interaction Plot - 90 -
4-3-4 Regression Analysis - 98 -
4-3-5 以模型回歸之結果與實驗值比較 - 115 -
4-4變溫吸附實驗結果 - 122 -
4-4-1 G1各組實驗隨循環數改變所產生變化 - 123 -
4-4-2 G2各組實驗與G1對應組別之比較 - 173 -
4-5連續變溫吸附實驗對吸附劑之影響 - 190 -
第五章、結論 - 192 -
參考文獻 - 193 -
附錄A、Thermo Cahn D-200操作流程 - 198 -
附錄B GC操作步驟 - 200 -
附錄C 單塔變溫吸附實驗第三步驟數據 - 202 -
附錄D 單塔變溫吸附實驗第四步驟數據 - 203 -
附錄E 單塔變溫吸附實驗總回收率數據 - 204 -

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指導教授

周正堂、楊閎舜
(C.T. Chou、H.S. Yang)

審核日期

2013-7-22

推文