細丹尼纖維深染助劑配方技術研究

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姓名

鄭家偉(Jya-wei Jeng) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

細丹尼纖維深染助劑配方技術研究
(The technology of deep dyeing auxiliary on PET microfiber.)

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摘要(中)

本研究合成陽離子型深染助劑，藉由染色前處理與染色同時處理之方法，探討染色溫度、助劑組成、助劑添加量、染色時間、升溫速率與助劑分子量等參數，對於細丹尼聚酯纖維之表觀顏色深度(K/S)之影響，並由水洗堅牢度測試與SEM 影像來觀察染色纖維的性質。
首先以3-丙烯醯胺丙基三甲基氯化銨(APTAC)與丙烯腈(AN)為單體，過硫酸銨(APS)為起始劑進行共聚合反應，合成各種組成與分子量之陽離子型深染助劑。
結果顯示，助劑的添加以染色同時處理方式效果較佳，對於K/S 的提昇可高達25％，同時也提高纖維對染色溫度變化的穩定性並且維持良好的水洗堅牢度。不同的助劑組成皆有大幅提昇K/S 的效果，隨著APTAC 的單體含量的增加，可相對減少助劑的使用量，而提高升溫速率與調整適當的助劑分子量則能夠增加纖維染色的K/S 穩定性。

摘要(英)

The deep dyeing effect of the disperse dye on polyester microfiber in the presence of cationic auxiliaries synthesized by (3-acrylamidopropyl)trimethyl ammonium chloride (APTAC) and acrylonitrile (AN) as monomers and ammonium persulfate (APS) as the initiator has been developed. The different parameters, dyeing temperature, auxiliary components, auxiliary content, dyeing holding time, dyeing temperature rate and auxiliary’s molecular weight, were discussed. Colour shade depth ( K/S ), wash fastness test and SEM photographs of dyed microfiber were measured.
The result showed that the K/S of the dyed microfiber was increased and maintain good wash fastness, with adding cationic auxiliaries (especially with low molecular weight) in the dye bath or decreasing dyeing temperature. The highest value of K/S, 550 (increase 25%), of dyed microfiber was obtained by adding auxiliary.

關鍵字(中)

★ 細丹尼纖維
★ 深染助劑

關鍵字(英)

★ deep dyeing
★ microfiber

論文目次

摘要.................................................................................................................. i
誌謝................................................................................................................iii
目錄................................................................................................................ iv
圖索引............................................................................................................ vi
表索引..........................................................................................................viii
第一章前言................................................................................................. 1
1-1 聚酯及細丹尼纖維之性質探討............................................................. 1
1-2 提高纖維深染性質之方法..................................................................... 2
1-3 研究目的.................................................................................................. 3
第二章實驗................................................................................................. 4
2-1 實驗材料.................................................................................................. 4
2-2 實驗儀器.................................................................................................. 6
2-3 實驗步驟.................................................................................................. 7
2-3-1 深染助劑之合成.................................................................................. 7
2-3-2 染色前處理法之染色加工.................................................................. 7
2-3-3 染色同時處理法之染色加工.............................................................. 8
2-4 實驗測試................................................................................................ 11
第三章結果與討論................................................................................... 12
3-1-1 空白細丹尼纖維布帛之熱定型溫度探討......................................... 12
3-1-2 細丹尼纖維與粗丹尼纖維之染色溫度探討..................................... 15
3-2 染色前預處理方式之探討.................................................................... 17
3-3-1 染色同時處理之染色溫度的探討.................................................... 19
3-3-2 添加不同助劑之結果探討................................................................ 23
3-3-3 改變助劑添加量之結果探討............................................................ 25
3-3-4 染色加工時溫度變化影響之探討.................................................... 31
3-3-5 染色加工之恆溫時間探討................................................................ 36
3-3-6 染色加工之快速升溫結果探討........................................................ 39
3-3-7 改變助劑分子量之結果探討............................................................ 41
第四章結論............................................................................................... 44
參考文獻....................................................................................................... 45

參考文獻

1. CL, B., Journal of the Society of Dyers and Colourists, Vol 72, pp.343, 1956
2. Mcgregor, R. and R.H. Peters, "The effect of rate of flow on rate of dyeing I-The diffusional boundary layer in dyeing", Journal of the Society of Dyers and Colourists, Vol 81, pp. 393, 1965.
3. A, M. and M. K, "Dye Auxiliaries in the Application of Disperse Dyes to Man-made Fibers.", Journal of the Society of Dyers and Colourists, Vol 87, pp.173, 1971.
4. Trotman, E.R., Dyeing and chemical technology of textile fibres. 6th ed, 1984.
5. Mclntyre, J.E. and P.N. Daniels, Textile Terms Definitions, 10th ed, 1995.
6. Burkinshaw, S.M., Chemical Principles of Synthetic Fiber Dyeing, 1995.
7. Shin, J.S. and M. Bide, "Dye distribution in the dyeing of mixed denier polyester fabrics.", Journal of the Society of Dyers and Colourists, Vol 116(10), pp. 305-309, 2000.
8. Park, K.H., M. Casetta, and V. Koncar, "Diffusion of disperse dyes into microfibres and conventional polyester fibres", Coloration Technology, Vol 118(6), pp. 319-324, 2002.
9. Park, K.H. and V. Koncar, "Diffusion of disperse dyes into super-microfibres", Coloration Technology, Vol 119(5), pp. 275-279. 2003.
10. P, K. and M. F, "Ein Beitrag. zur. Optik der. Farbanstriche." Z Tech Phys, Vol 12, pp. 593-601, 1931.
11. Park, K.H. and B. Kim, "Mathematical relationship between the colour shade depth and the fibre count for disperse dyeing of polyester fibres.", Coloration Technology, Vol 122(1), pp. 45-48, 2006.
12. JP, K. and B. SM, "Effect of o-Phenyl Phenol on the Dyeing of an Acrylic Fiber with Basic Dyes", Journal of Applied Polymer Science, Vol 49(9), pp. 1647-1652, 1993.
13. Ingamells, W. and K.V. Narasimham, "The Effect of Benzyl Alcohol on the Physical and Dyeing Properties of Poly(ethylene terephthalate) Filaments", Journal of The Society of Dyers and Colourists, Vol 93, pp. 306-312, 1977.
14. Ingamells, W. and A. Yabani, "The swelling and plasticization of poly during carrier dyeing", Journal of The Society of Dyers and Colourists, Vol 93(11), pp. 417, 1977.
15. Shukla, S.R., R.V. Hundekar, and A.N. Saligram, "Solvent-assisted dyeing of acrylic fibres. Part 1-Effect of solvents on physical properties of fibres", Journal of The Society of Dyers and Colourists, Vol 107, pp. 407, 1991.
16. Aitken, D. and S.M. Burkinshaw, "The effect of carriers on the dyeing of courtelles", Journal of The Society of Dyers and Colourists, Vol 108, pp. 219, 1992.
17. 半田信義和藤井吉宏, "纖維構造物の發色性改善法", 日本國特許廳, 特開昭55-26232, 1980.
18. Shukla, S.R. and M.R. Mathur, "Dyeing of solvent-pretreated polyesters", Journal of the Society of Dyers and Colourists, Vol 113(5-6), pp. 178-181, 1997.
19. 帆足杭治和瀧澤清, "纖維成形物およびその製造方法", 日本國特許廳, 特公昭59-011709, 1984.
20. 金谷義博,"ポリエステル纖維構造物の深色鮮明加工方法", 日本國特許廳, 特開昭60-88188, 1985.
21. 上野進, 黑田幸一和北村肇, "染色纖維製品の濃色化方法", 日本特許廳, 特開昭61-97490, 1986.
22. 長谷川明郎, 小島弘樂和清田隆夫, "生理活性物質の製造法", 日本特許廳, 特開昭62-26232, 1987.
23. 中島德彥, 石川善信, 進藤昭裕和妻鳥正樹, "濃色化劑", 日本國特許廳, 特開昭62-289685, 1987.
24. 清水邦夫和鈴木保之, "濃色化劑および濃色化方法", 日本國特許廳, 特開平9-291486, 1997.
25. 清水邦夫和鈴木保之, "濃色化劑および濃色化方法", 日本國特許廳, 特開平9-3774, 1997.
26. 村川昭和清水邦夫, "濃色化劑、それを用いた濃色化方法、及び該濃色化劑で處理をれた物品", 日本國特許廳, 特開2005-187957, 2005.
27. 福田肇和吉川泰博, "ポリエステル纖維染色物の濃色化劑", 日本國特許廳, 特開昭56-112583, 1981.
28. 鈴木東義, 網脇清和, 岡本悠治郎和關本雅章, "纖維用ポリエステルの製造法", 日本國特許廳, 特開昭57-139118, 1982.
29. 稻垣美奈阿部辰行, "纖維の濃色化方法", 日本國特許廳, 特開平2-259160, 1990.
30. 山根浩一和池田玲子, "著色固體の濃色化劑及び濃色化方法", 日本國特許廳, 特開平9-256280, 1997.
31. 小林重信和嶋田幸二郎, "深色化ポリエステル纖維布帛およびその製造方法", 日本國特許廳, 特開平3-269171, 1991.
32. 前島邦明和西野和忠, "濃色化劑および濃色化方法", 日本國特許廳, 特開2004-353093, 2004.
33. 佐野洋文, "編織物類の染色法", 日本國特許廳, 特開昭52-37881, 1977.
34. 佐野洋文, 中川潤洋和平松浩二, "極細纖維を用いた構造物の捺染法", 日本國特許廳, 特開昭52-132183, 1977.
35. 井樋昭人, 西勲和石井保夫, "ポリエステル用染色性向上添加劑及びこれを用染色用ポリエステル纖維", 日本國特許廳, 特開平5-321027, 1993.
36. 半田信義和増田豊, "ポリエステル系纖維構造物の染色方法", 日本國特許廳, 特開平5-195447, 1993.
37. 半田信義, 増田豊和樋口徹憲, "高染著性ポリエステル系纖維および高染著性ポリエステル系纖維構造物たらびにその染色方法", 日本國特許廳, 特開平8-199425, 1996.
38. 河村達夫, 石水俊雄和分部好孝, "纖維材料の染色加工法", 日本國特許廳, 特開平10-259579, 1998.
39. Choi, T.-S., et al., "Solubilization of disperse dyes in cationic gemini surfactant micelles", Dyes and Pigments, Vol 45(2), pp.145-152, 2000.
40. Choi, T.-S., et al., "Disperse dyeing of polyester fiber using gemini surfactants containing ammonium cations as auxiliaries", Dyes and Pigments, Vol 50(1), pp. 55-65, 2001.
41. Choi, T.-S., et al., "Disperse dyeing of nylon 6 fiber using gemini surfactants containing ammonium cations as auxiliaries", Dyes and Pigments, Vol 48(3), pp. 217-226, 2001.
42. 長森秀雄, 高橋政明, 榊原基伸和那波茂, "纖維布帛の深色性向上方法及び当該方法使用する染色前處理劑", 日本國特許廳, 特開2004-360137, 2004.

指導教授

陳暉(Hui Chen)

審核日期

2008-6-20

推文