合成吡啶基吲哚配位之鈀金屬錯合物並探討其光電性質

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簡鴻名(Hung-Ming Chien) 查詢紙本館藏

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化學學系

論文名稱

合成吡啶基吲哚配位之鈀金屬錯合物並探討其光電性質
(Synthesis of Palladium Complexes with Pyridylindolide Ligands and Investigation of Their Photoelectric Properties)

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摘要(中)

自工業革命以來，人類的生活便無法缺少能源。而新世代的替代能源當中，染料敏化太陽能電池因其低成本，製程簡易等特色受到相當大的矚目。光敏化劑為染敏電池當中影響效率之重要因素，因此科學家無不投入心力以開發新型具更優秀表現之敏化劑。釕金屬錯合物雖擁有高效率表現，但其因價格

本文所合成之染料IP-101為具有高總產率之有機染料，而我們嘗試開發以其作為配位基之鈀金屬染料，其以Indole此具高莫耳消光係數之雜環作為基本架構，再引入金屬與其配位，生成4配位之錯合物染料。我們於其錯合物與原先配位基的比較上發現了明顯的紅位移現
象，而我們亦希望此現象能夠應用於染敏電池之敏化劑。

摘要(英)

Since the industrial revolution, energy has dominated our lives. Among the all renewable energy resources, Dye-Sensitized Solar Cells (DSSC) have received much attention of academic and industrial due to its low-cost and simple manufacturing process. Sensitizer is one of the key components which will greatly affect the performance in DSSC; therefore, numerous researchers have developed various kinds of novel dye and achieve significant efficiency. Ruthenium-based dye was one of the best we have;however, it also led to some serious issues, such as environmental pollution and its rarity; thus, we would like to design some novel metal complex sensitizers to replace it.

The sensitizer IP-101, made up by indole derivatives possessing the advantage of high total yield, was designed and synthesized, and later play as a ligand in 4-coordinated palladium complex. Compared with the original ligand, the UV-Vis spectrum of palladium complex shows obviously red-shift in absorption band which could be beneficial to sensitizers of dye-sensitized solar cells.

關鍵字(中)

★ 鈀金屬錯合物

關鍵字(英)

論文目次

目錄
摘要 I
目錄 IV
圖目錄 V
表目錄 VI
一、緒論 1
1-1 前言 1
1-2 太陽能電池 6
1-2-1 太陽能電池之進程 6
1-2-2太陽能電池之種類與其簡介 8
1-3 染料敏化太陽能電池 15
1-3-1 基本組成與運作原理 16
1-3-2 元件內部反應 17
1-3-3 電池詳細架構 22
1-3-4 電池元件參數 28
1-4 文獻回顧 33
1-5 設計理念 54
二、合成方法與實驗討論 56
2-1 逆合成分析 56
2-2 合成規劃策略 58
2-3 實驗步驟 62
2-4 實驗儀器與藥品來源 74
三、結果與討論 78
3-1 合成討論 78
3-2 錯合物結構鑑定 85
3-3 錯合物光物理性質探討 87
3-4 未來展望 90
參考文獻 92
附錄 98

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指導教授

李文仁(Wen-Ren Li)

審核日期

2015-8-5

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