論文目次 |
第1 章 緒論 1
1-1、 前言 1
1-2、 有機太陽能電池的發展歷史 2
1-3、 高分子太陽能電池的工作原理 9
1-4、 太陽能電池的光伏參數 11
1-5、 高分子太陽能電池相關文獻探討 14
1-6、 研究動機 25
第2 章 實驗部分 29
2-1、 實驗藥品 29
2-2、 共聚物與其中間產物的合成流程圖 33
2-2-1. (4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl)bis(trimethylstannane) (Ditin-DiEH-BDT)之合成 33
2-2-2. ((4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl)bis(thiophene-5,2-diyl))bis(trimethylstannane) (Ditin-DiT-DiEH-BDT)之合成 34
2-2-3. ((4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-
diyl)bis(4-hexylthiophene-5,2-diyl))bis(trimethylstannane) (Ditin-DiRT-DiEH-BDT)之合成 35
2-2-4. 5,8-dibromo-2,3-bis(4-(hexyloxy)phenyl)quinoxaline (DiBr-DBQ)之合成 36
2-2-5. 5,8-dibromo-2,3-bis(4-(hexyloxy)phenyl)pyrido[3,4-b]pyrazine (DiBr-DBP)之合成 37
2-2-6. 共聚物之聚合反應─密閉式微波加熱 38
2-2-7. 共聚物之聚合反應─傳統加熱 39
2-3、 合成之反應物、中間體及最後所得共聚物之結構、命名與簡稱 41
2-4、 組裝BHJ 元件之相關材料 46
2-5、 合成步驟 47
2-5-1. Thiophene-3-carbonyl chloride 的合成 47
2-5-2. N,N-diethylthiophene-3-carboxamide 的合成 47
2-5-3. Benzo[1,2-b:4,5-b′]dithiophene-4,8-dione 的合成 48
2-5-4. 4,8-Bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene的合成 49
2-5-5.(4,8-Bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl)bis(trimethylstannane)的合成 51
2-5-6. 4,8-Bis((2-ethylhexyl)oxy)-2,6-di(thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene 的合成 52
2-5-7. ((4,8-Bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl)bis(thiophene-5,2-diyl))bis(trimethylstannane)的合成 53
2-5-8. 4,8-Bis((2-ethylhexyl)oxy)-2,6-bis(3-hexylthiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene 的合成 54
2-5-9. ((4,8-Bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl)bis(4-hexylthiophene-5,2-diyl))bis(trimethylstannane)的合成 55
2-5-10. 1,2-Bis(4-hydroxyphenyl)ethane-1,2-dione 的合成 56
2-5-11. 1,2-Bis(4-(hexyloxy)phenyl)ethane-1,2-dione 的合成 57
2-5-12. 4,7-Dibromobenzo[1,2,5]thiadiazole 的合成 58
2-5-13. 3,6-Dibromobenzene-1,2-diamine 的合成 59
2-5-14. 5,8-Dibromo-2,3-bis(4-(hexyloxy)phenyl)quinoxaline的合成 60
2-5-15. 2,5-Dibromopyridine-3,4-diamine 的合成 61
2-5-16. 5,8-Dibromo-2,3-bis(4-(hexyloxy)phenyl)pyrido[3,4-b]-pyrazine 的合成 62
2-5-17. Poly{4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithio- phene-alt-2,3-bis[4-(hexyloxy)phenyl]quinoxaline}的合成─密閉式微波加熱 63
2-5-18. Poly{2,6-di-2-thienyl-4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]quinoxaline}的合成─密閉式微波加熱 64
2-5-19. Poly{2,6-bis(3-hexylthiophen-2-yl)-4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]quinox-aline}的合成─密閉式微波加熱 65
2-5-20. Poly{4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]quinoxaline}的合成─傳統加熱 66
2-5-21. Poly{2,6-di-2-thienyl-4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]quinoxaline}的合成─傳統加熱 68
2-5-22. Poly{2,6-bis(3-hexylthiophen-2-yl)-4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]quinoxaline}的合成─傳統加熱 69
2-5-23. Poly{4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]pyrido[3,4-b]pyrazine}的合成─傳統加熱 70
2-5-24. Poly{2,6-di-2-thienyl-4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]pyrido[3,4-b]pyrazine}的合成─傳統加熱 71
2-5-25. Poly{2,6-bis(3-hexylthiophen-2-yl)-4,8-bis(2’-ethylhexyloxy)-benzo[1,2-b:4,5-b’]dithiophene-alt-2,3-bis[4-(hexyloxy)phenyl]pyrido[3,4-b]pyrazine}的合成─傳統加熱 72
2-6、 共聚物純化方式 73
2-7、 儀器分析與樣品製備 74
2-7-1. 核磁共振光譜(Bruker 300 MHz Nuclear Magnetic Resonance Spectrometer, NMR) 74
2-7-2. 紫外光/可見光/近紅外光吸收光譜(HITACHI U-4100 Spectrophotometer) 75
2-7-3. 分子螢光光譜(HITACHI F-7000 Fluorescence Spectrophotometer) 76
2-7-4. 膠體滲透層析分析(HEWLETT PACKARD Series1100/Agilent 1100 Series, Gel Permeation Chromatography, GPC) 77
2-7-5. 熱重分析(TA Instruments TGA Q500) 79
2-7-6. 示差掃描熱分析(TA Instruments DSC Q2000) 79
2-7-7. 電化學循環伏安測試(AutoLab Potentiostat/Galvanostat PGSTAT30, CV) 80
2-7-8. 穿透式小角度X 光繞射分析(Rigaku-NANO-Viewer Diffractometer, GIXRD) 81
2-7-9. 塊材異質接面結構(BHJ)太陽能電池元件的組裝 82
2-7-10. 元件光伏參數的量測步驟 (Enlitech SS-F5-3A) 85
第3 章 結果與討論 86
3-1、 紫外光/可見光吸收光譜 86
3-2、 分子螢光光譜 91
3-3、 共聚物的分子量 93
3-4、 共聚物的熱分解溫度測定 97
3-5、 共聚物的玻璃轉換溫度測定 98
3-6、 電化學循環伏安測定共聚物的氧化還原電位 102
3-7、 共聚物所組裝的正相塊材異質接面結構(Regular Bulk Heterojunction, R-BHJ)太陽能電池元件的效率 106
3-8、 PTBDTQ 及PTBDTP 所組裝的反相塊材異質接面結構(Inverted Bulk Heterojunction, I-BHJ)太陽能電池元件的效率 109
第4 章 結論 116
參考文獻 117
附錄 121
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參考文獻 |
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