超親水複合薄膜之製備及其表面特性分析

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姓名

張雅真(Ya-chen Chang) 查詢紙本館藏

畢業系所

光電科學與工程學系

論文名稱

超親水複合薄膜之製備及其表面特性分析
(Fabrication of superhydrophilic hybrid thin film and analysis of its surface character)

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至系統瀏覽論文 (2025-9-1以後開放)

摘要(中)

超親水複合薄膜(TiO2+SiO2)可簡單的利用溶膠-凝膠法製備，由二氧化鈦奈米顆粒混合溶膠-凝膠法製備出的二氧化矽而製得。整體膜層架構為一個雙層結構，分別為TiO2+SiO2/AR coating/glass以及TiO2+SiO2/SiO2/glass。

透過兩種不同中間層抗反射膜層(AR Coating)或二氧化矽薄膜(SiO2)提高整體膜層之穿透率。抗反射膜層之添加可使整體膜層在可見光波段(400-700 nm)的平均穿透率達到94.3%，而二氧化矽薄膜則可使穿透提升至91.4%。超親水複合薄膜的水滴接觸角在照UV光(253.7 nm, 4 mW/cm2)4小時後具有接觸角小於10°之超親水特性，且將薄膜置於暗房內其超親水特性可維持76小時。

機械性質方面，附著力測試根據ISO 2409標準下其品質等級為1，也就是薄膜整體的剝落程度<5%；薄膜進行鉛筆硬度測試，在3H鉛筆刻劃下無任何刮痕，可達到3H的鉛筆硬度；而對於耐磨耗測試，可耐磨大於1280次。

在環境測試部分，將超親水複合薄膜放置在不同溫度、濕度及時間，如高溫高濕試驗85℃、85%RH 100小時和高溫耐久性測試100℃, 168 h，考驗其抵抗能力，結果顯示薄膜皆無脫膜、裂膜現象，且照UV光之後超親水複合薄膜仍顯示具有超親水現象，因此對環境具有良好的抵抗能力。

摘要(英)

Sol-gel process is an easy method for fabricating a superhydrophilic hybrid thin film. A two-layer structure, TiO2+SiO2/AR coating/glass and TiO2+SiO2/SiO2/glass, was designed and fabricated.

The transmittance of superhydrophilic hybrid thin film was increased by inserting AR coating or SiO2 film between TiO2+SiO2 and glass. The transmittance of TiO2+SiO2/AR coating/glass and TiO2+SiO2/SiO2/glass was 94.3% and 91.4%, respectively.

The water contact angle (WCA) of the TiO2+SiO2 superhydrophilic hybrid thin film was less than 10° following treatment with ultraviolet irradiation (253.7 nm, 4 mW/cm2). The superhydrophilic hybrid thin film exhibited lasting superhydrophilicity when stored in a dark place (opaque acrylic box). After 76 h of storage in a dark place, the superhydrophilic hybrid thin film exhibited a significantly lower WCA.

To ensure that the durable TiO2+SiO2 superhydrophilic hybrid thin film, its mechanical properties were measured. The hardness of the superhydrophilic hybrid thin film was obtained (≥ 3 H) by performing the pencil hardness test. According to the ISO 2409 standard, the adhesion of a superhydrophilic hybrid thin film causes it to be given a quality rank of 1. The superhydrophilic property was be maintained after the thin film was treated by pressing steel wool under a 500 g weight and moving it parallel to the substrate, back and forth on it more than 1280 times.

The phenomenon of thin film cracking and stripping was not observed under 100 ℃ (168 h) and 85 %RH (100 h).

關鍵字(中)

★ 超親水
★ 薄膜
★ 表面特性

關鍵字(英)

★ Superhydrophilic
★ Thin film
★ Surface character

論文目次

摘要 i

Abstract ii

致謝 iv

目錄 v

圖目錄 viii

表目錄 xi

第一章：緒論 1

1-1 前言 1

1-2 研究動機與目的 2

1-3 研究目標 2

1-4 本文架構 3

第二章：基本理論 4

2-1 奈米級二氧化鈦簡介 4

2-1-1 光反應機制 8

2-1-2 超親水特性 10

2-1-3 奈米級二氧化鈦光觸媒材料應用及薄膜之製備方式 14

2-2 親水性簡介 17

2-2-1 水接觸角 17

2-2-2 親疏水性 19

2-3 溶膠-凝膠法 20

2-3-1 溶膠-凝膠法之發展與現況 20

2-3-2 溶膠-凝膠反應程序(Sol-Gel process) 21

2-3-3 溶膠-凝膠影響因素 22

2-3-4 溶膠-凝膠法之成膜方式 26

2-3-5 溶膠-凝膠法之應用 29

第三章：實驗步驟與實驗儀器設備 31

3-1 實驗製備流程： 31

3-2 鍍膜儀器設備 34

3-2-1 電子槍蒸鍍 34

3-2-2 浸泡成膜法(Dip-Coating) 36

3-2-3 自動拉膜機 37

3-3 量測與分析之設備儀器 38

3-3-1 可見光/近紅外光光譜儀 38

3-3-2 接觸角量測儀 38

3-3-3 鉛筆硬度計(Hardness test) 39

3-3-4 方格試驗機(Adhesion test) 40

3-3-5 鋼絲絨磨耗試驗(Abrasion test) 41

3-3-6 場發射式掃描電子顯微鏡 42

第四章：實驗結果與討論 45

4-1 超親水複合薄膜 45

4-2 超親水複合薄膜之光學特性 50

4-3 超親水複合薄膜之親水特性 55

4-4 超親水複合薄膜之機械性質 57

4-4-1 硬度測試(Hardness test) 57

4-4-2 附著力測試(Adhesion test) 58

4-4-3 耐磨耗測試(Abrasion test) 58

4-4-4 環境測試 60

第五章：結論 63

參考文獻 64

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指導教授

李正中(Cheng-chung Lee)

審核日期

2015-8-27

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