博碩士論文 104326603 詳細資訊




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姓名 徐明康(Minh-Khang Tu)  查詢紙本館藏   畢業系所 環境工程研究所
論文名稱 越南胡志明市氣膠化學成份 與污染來源推估
(The study on chemical characterization and contributing sources of atmospheric aerosol in Ho Chi Minh City, Vietnam)
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摘要(中) 本文於2017年1月9日至2017年2月14日在越南胡志明市,採集和分析PM2.5與PM10,研究越南都會區PM2.5 與PM10化學成份以及推估可能污染源, PM2.5與PM10樣本使用稱重方法來分析質量濃度,離子層析儀分析水溶性無機離子和碳分析儀器分析碳成份。研究結果顯示PM2.5與PM10平均質量濃度是31.8 μg m-3 和 65.8 μg m-3,碳成份占PM2.5、PM10是41%和14%,水溶性無機離子占PM2.5、PM10是26%和21%。本研究使用正矩陣因子法(Positive Matrix Factorization - PMF)推估貢獻因子(污染來源),結果顯示有六種污染來源分別是二次硫酸(占PM2.5 14%, PM10 8%),汽油車(占PM2.5 21%, PM10 12%),二次硝酸(占PM2.5 16%, PM10 11%),建設活動(占PM2.5 5%, PM10 7%),海鹽和塵土(占PM2.5 4%, PM10 5%),農廢燃燒(占PM2.5 8%, PM10 8%)。最後使用條件機率函數(Conditional Probability Function - CPF)結合風向資料,推估當地污染源來向。
摘要(英) Atmospheric aerosols were collected from 9 January to 14 February 2017 in the urban area of Ho Chi Minh City (HCMC), Vietnam. Aerosol mass concentrations, carbonaceous contents, and water-soluble inorganic ions (WSIIs) of PM2.5 and PM10 were determined by gravimetrical weighing, thermal-optical reflectance method, and ion chromatography, respectively. The average mass concentration of PM2.5 and PM10 during the sampling period were 31.8 μg m-3 and 65.8 μg m-3, respectively. A mong various components, carbonaceous contents accounted for 41% and 24% of PM2.5 and PM10 mass, respectively. In contrast, WSIIs contributed 26% and 21% of PM2.5 and PM10 mass, respectively. In this study, positive matrix factorization (PMF) was used to investigate major contributing sources of PM2.5 and PM10 in HCMC. Six sources were identified from PMF modeling including secondary sulfate (14% of PM2.5, 8% of PM10), gasoline vehicles (21% of PM2.5, 12% of PM10), secondary nitrate (16% of PM2.5, 11% of PM10), construction activities (5% of PM2.5, 7% of PM10), sea salts and soils (4% of PM2.5, 5% of PM10), and biomass burning (8% of PM2.5, 8% of PM10). Conditional Probability Function was applied to help identify potential sources from local activities in HCMC.
關鍵字(中) ★ PM2.5
★ PM10
★ 都市氣膠
★ 氣膠化學成份
★ 胡志明市
關鍵字(英) ★ PM2.5
★ PM10
★ urban aerosol
★ aerosol chemical characterization
★ Ho Chi Minh City
論文目次 Chapter 1 Introduction 1
1.1. Motivation 1
1.2. Goal 1
Chapter 2. Literature Review 3
2.1. Overview of atmospheric aerosol 3
2.1.1. Aerosol’s shape and size 3
2.1.2. Emission sources 4
2.1.3. Climate impact of atmospheric aerosol 7
2.1.4. The impact of atmospheric aerosol on human health 9
2.2. Chemical compositions of atmospheric aerosol 10
2.2.1. Water-soluble inorganic ions (WSIIs) 10
2.2.2. Carbonaceous matter (organic and black carbons) 11
2.3. Aerosol chemical characteristics in Asia 11
2.4. Aerosol chemical characteristics in Ho Chi Minh City, Vietnam 14
2.4.1. Concentration of PM 14
2.4.2. Factor analysis 17
Chapter 3 Methodology 19
3.1. Research Framework 19
3.2. Sampling site and sample collection 20
3.2.1. Short overview of Vietnam and Ho Chi Minh City. 20
3.2.2. Sampling site description 20
3.3. Sampling methods 21
3.4. Chemical analysis 23
3.4.1. PM mass determination 23
3.4.2. Water-soluble inorganic ions determination 24
3.4.3. Carbonaceous aerosol components 27
3.5. Air mass backward trajectory by HYSPLIT model 31
3.6. Source apportionment 31
3.6.1. Positive Matrix Factorization (PMF) model 32
Chapter 4 Results and Discussion 35
4.1. Time Series of PM2.5 and PM10 Chemical Components in Ho Chi Minh City 35
4.1.1 PM2.5 and its chemical components 35
4.1.2 PM10 and its chemical components 38
4.1.3 Partitions of components between fine and coarse particles 41
4.2 Water-soluble inorganic ions in urban aerosol 43
4.2.1 Charge balance 43
4.2.2 Characteristics and formation of nitrate 44
4.3 Carbonaceous contents in urban aerosol 45
4.3.1 OC/EC and char EC/soot EC ratios 45
4.3.2 Secondary Organic Carbon (SOC) 47
4.4 Source Apportionments of PM2.5 and PM10 50
4.4.1 Source apportionment of PM2.5 50
4.4.2 Source apportionment of PM10 57
Chapter 5 66
Conclusions 66
References 67
Supplementary data 73
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許家綺, 2015. 2011-2015年台灣都會區細懸浮微粒(PM2.5)成分濃度變化,污染來源推估及對能見度影響. 碩士論文.
指導教授 李崇德(Chung-Te Lee) 審核日期 2018-7-23
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