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姓名	郭建育(Kuo Chien-Yu)  查詢紙本館藏	畢業系所	化學學系
論文名稱	含聯噻唑的輔助配位基之釕錯合物的合成與其在染料敏化太陽能電池上的應用
相關論文	★ 導電高分子應用於鋁質電解電容器之研究 ★ 異参茚并苯衍生物合成與性質之研究 ★ 含雙吡啶或二氮雜啡衍生物配位 基之釕金屬錯合物的合成與其在 染料敏化太陽能電池之應用 ★ 新型噻吩環戊烷有機染料於染料敏化太陽能電池之應用 ★ 應用於染料敏化太陽能電池之新型釕金屬錯合物的合成與性質探討 ★ 釕金屬光敏化劑的設計與合成及其在染料敏化太陽能電池之應用 ★ 染敏電池用之非對稱釕錯合物之輔助配位基的設計與合成 ★ 含雙噻吩環戊烷之電變色高分子的研究 ★ 含噻吩衍生物非對稱方酸染料應用於染料敏化 太陽能電池 ★ 高品質導電聚苯胺薄膜的合成及應用 ★ 染料敏化太陽能電池用導電高分子聚苯胺及聚二氧乙基噻吩陰極催化劑的探討 ★ 具多功能性之非對稱型釕錯合物的設計與合成並應用於染料敏化太陽能電池 ★ 含乙烯噻吩固著配位基之非對稱型釕金屬錯合物應用於染料敏化太陽能電池 ★ 染料敏化太陽能電池用二茂鐵系統電解質的探討 ★ 合成含喹啉衍生物非對稱方酸染料應用於染料敏化太陽能電池 ★ 合成新穎輔助配位基於無硫氰酸釕金屬光敏劑在染料敏化太陽能電池上的應用
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摘要(中)	染料敏化太陽能電池(dye-sensitized solar cells, DSCs)具低製造成本與高效率的室內弱光發電特性。本實驗室先前合成出含cycloruthenated sensitizers (DUY24−DUY27)，並透過β-lowest unoccupied spin orbital (β-LUSO)分佈證明β-LUSO分佈在軟的硫原子，可以提高碘電解質與氧化態染料的作用能力，加快染料再生速率提高元件的光電轉換效率。本研究參考高光電轉換效率染料C101、C106及CYC-B20，將一個輔助配位基的bipyridine改為bithiazole，而β-LUSO分佈在thiazole之3號位置的硫原子，可以提高染料再生的速度，並且在thiazole接上2-(hexyl)thiophene、2 -(hexylthio) thiophene和5-(hexylthio)-ethylenedioxythiophene來增長輔助配位基的共軛長度，以增強染料在MLCT band的吸光強度，CYK系列染料的DMF溶液呈現深棕綠色，含bithiazole的CYK系列染料相對於含bipyridine的染料之MLCT最大吸收波長呈現紅位移(CYK17 : 560 nm, 紅移 7 nm；CYK18 : 597 nm, 紅移35 nm ; CYK19 : 580 nm, 紅移13 nm)，有利染料吸收太陽光。
摘要(英)	Dye-sensitized solar cells(DSCs) have low cost and high efficiency under dim-light condition. The laboratory previously synthesized cycloruthenated sensitizers (DUY24−DUY27) and proved that β-lowest unoccupied spin orbital distributes on the soft sulfur atom, which strengthens the interaction between the oxidized dye and iodide ion for efficient dye regeneration. The study refers to high efficiency dye C101、C106 and CYC-B20. We replaced the bipyridine of ancillary ligand with bithiazole, then use three cojugated moiety (2-(hexyl)thiophene、2 -(hexylthio) thiophene and 5-(hexylthio)-ethylenedioxythiophene) to attach on bithiazole. Increasing the conjugate length of the ancillary ligand to enhance the absorbance of the MLCT band. The color of CYK dye in DMF solution are brown green. The series of CYK dyes containing bithiazole exhibit red shift with respect to the dyes containing bipyridine. (CYK17 : 560 nm, red shift : 7 nm；CYK18 : 597 nm, red shift : 35 nm ; CYK19 : 580 nm, red shift : 13 nm).
關鍵字(中)	★ 釕金屬染料敏化太陽能電池	關鍵字(英)
論文目次	Abstract ii 第一章 緒論 1 1-1、前言 1 1-2、太陽能電池的發展 1 1-3、染料敏化電池的工作原理 2 1-4、染料分子之設計探討 4 1-5、染料敏化電池在室內弱光環境有高的光電轉換 5 1-6、釕金屬錯合物染料(Ruthenium Metal Complex) 6 1-6-1、具代表性的釕金屬錯合物染料N3和N719 6 1-6-2、增長輔助配位基的共軛長度，來增加染料分子的吸光能力 8 1-1、 含噻唑(Thiazole)單元之化合物 10 1-7-1、含聯噻唑(Bithiazole)之有機染料 10 1-7-2、含聯噻唑(Bithiazole)之釕錯合物性質 11 1-7-3、含噻唑(Thiazole)之釕錯合物染料 13 1-8 研究動機 14 第二章 實驗部分 15 2-1、實驗藥品 15 2-2、中間產物之結構與簡稱 17 2-3、最終產物之結構與簡稱 19 2-4、實驗步驟 20 2-4-1、BTz-Br的合成，如圖2-1所示 20 2-4-2、Tz17的合成，如圖2-2所示 21 2-4-3、Tz18的合成，如圖2-3所示 24 2-4-4、Tz19的合成，如圖2-4所示 26 2-4-5、Tz20的合成，如圖2-5所示 29 2-5、儀器分析與樣品製備 41 第三章 結果與討論 45 3-1、合成相關探討 45 3-2、 CYK17、CYK18和CYK19之TBA form的光學性質探討 51 3-3 、CYK系列染料之COOTBA form和COOH form之染料系附量之討論 3-4 、比較輔助配位基含Thiazol與Pyrine染料之光學性質差 56 3-5、CYK17、CYK18及CYK19之COOH form分子前置軌域的理論計算 61 3-6、釕錯合物電化學性質與前置軌域位能的量測 64 3-7、以CYK17、CYK18及CYK19染料所敏化之DSC元件效 能的探討 69 第四章 結論 75
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指導教授	吳春桂(Wu Chun-Guey)	審核日期	2019-8-21
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