博碩士論文 109223013 詳細資訊




以作者查詢圖書館館藏 以作者查詢臺灣博碩士 以作者查詢全國書目 勘誤回報 、線上人數:69 、訪客IP:3.148.117.62
姓名 邱彥瑜(Yan-Yu Qiu)  查詢紙本館藏   畢業系所 化學學系
論文名稱 以綠色分析化學技術檢測水樣中防曬乳成分的殘留―開發金屬有機骨架材料作為吸附劑之探討
相關論文
★ 以質譜技術探討非共價鍵結蛋白質聚合物之結構★ 以液相層析質譜儀檢測水樣與生物檢體中 全氟界面活性劑之濃度
★ 利用液相層析串聯質譜技術檢測水環境中藥物殘留物之方法開發與應用★ 直鏈式烷基苯基二甲基銨鹽類陽離子型界面活性劑在水環境中微量檢測方法的研究
★ 芳香族磺酸鹽類有機污染物在水環境中的分析與研究★ 以固相萃取及氣相層析質譜儀對水環境中壬基苯酚類 持久性有機污染物之分析與研究
★ 以固相萃取法及氣相層析質譜儀對水環境中動情激素類有機污染物之分析與研究★ 利用熱裂解直接高溫衍生化法快速分析直鏈式烷基三甲基銨鹽之方法建立與探討
★ 利用感應偶合電漿質譜儀檢測半導體製程用化學品中微量金屬不純物之分析研究★ 應用毛細管電泳間接偵測方法分離四級銨鹽界面活性劑
★ 利用毛細管電泳結合線上濃縮方法分離奈磺酸鹽之機制探討★ 快速分析水環境中醫療藥品殘留物之研究與探討
★ 以毛細管電泳法與電灑游離質譜法探討內包錯合物之研究★ 以氣相及液相層析質譜儀分析具荷爾蒙效應物質之方法開發
★ 以離子配對高效液相層析儀檢測螢光增白劑在不同基質中之研究★ 以氣相層析質譜儀檢測具荷爾蒙效應添加劑之方法開發與研究
檔案 [Endnote RIS 格式]    [Bibtex 格式]    [相關文章]   [文章引用]   [完整記錄]   [館藏目錄]   [檢視]  [下載]
  1. 本電子論文使用權限為同意立即開放。
  2. 已達開放權限電子全文僅授權使用者為學術研究之目的,進行個人非營利性質之檢索、閱讀、列印。
  3. 請遵守中華民國著作權法之相關規定,切勿任意重製、散佈、改作、轉貼、播送,以免觸法。

摘要(中) 本研究開發一套具有快速、環境友善的萃取方式檢測二苯基甲酮類化合物 (Benzophenones, 簡稱BPs)在環境水樣中的殘留。由於BPs為紫外線過濾劑,可以減輕有害輻射對皮膚和頭髮的負面影響,因此被廣泛使用在個人護理產品中,它們可能經由游泳、沐浴等與水相關的休閒活動方式或通過污水排放進入環境。相關研究指出,二苯基甲酮類化合物是潛在的內分泌干擾物,在生物系統中不僅含有潛在的危害性,且藉由生物累積的方式,易對環境及人類造成負面影響。
本研究萃取方法是以金屬有機骨架材料(ZIF-8)結合分散式微固相萃取法 (Zeolitic imidazolate frameworks 8-based dispersive micro solid phase extraction,簡稱ZIF-8-D-µ-SPE) 萃取環境水樣中共五種BPs衍生物,接著利用超高效液相層析串聯電灑游離 (+) −四極桿飛行時間質譜儀 (UHPLC−ESI(+)−QTOF−MS) 進行後續檢測。本方法中所利用的吸附劑為金屬有機骨架材料當中的ZIF-8,因其具有良好的化學與熱穩定性、低成本、高比表面積等,可以有效吸附目標待測物,合成ZIF-8材料的方式為機械力化學合成法,此合成法快速又可以減少溶劑使用量,使整體萃取方法達到綠色分析化學的宗旨。
透過使用Box−Behnken Design (BBD) 中的變異數分析 (Analysis of variance, 簡稱ANOVA) 優化各項數值因子得到實驗的最佳條件後,利用ZIF-8-D-µ-SPE方式,檢測五種BPs衍生物的偵測極限 (LOD) 為 0.05−7 ng/mL;Intra −day 和Inter−day 的相對標準偏差 (RSD) 低於8 %;而萃取回收率則介在 71 %−112 % 之間,表示本方法呈現良好的精密度及穩定性。在真實環境水樣檢測中,檢測到BP-3和BP-8的微量殘留。
摘要(英) Benzophenones (BPs) are a type of ultraviolet (UV) filters that can absorb UV radiation. They are used in a variety of personal care products to attenuate the negative effects of sunlight harmful radiation on skin and hair. Since benzophenone-type UV filters are widely used, they may enter the environment via wash-off from skin or via sewage discharges. Moreover, benzophenone-type UV filters are potential endocrine-disrupting chemical (EDC). They have attracted much public attention due to the negative effects in humans.
In this study, we used a simple and environmental−friendly method for the rapid determination of five BPs derivatives in water samples. The target analytes were effectively extracted from water samples using a Zeolitic imidazolate frameworks 8-based dispersive micro solid phase extraction (ZIF-8-D-µ-SPE), and their determination were performed by ultrahigh−performance liquid chromatography and electrospray ionization (+) −quadrupole time−of−flight mass spectrometry (UHPLC−ESI(+)−QTOF−MS). ZIF-8 is known for excellent chemical stability, thermal stability, and high surface area. Its application in sample pretreatment is appropriate for green chemistry, environmental protection, and sustainable development.
To overcome the challenges in different experimental conditions, the experimental parameters of ZIF-8-D-µ-SPE were screened and optimized by Box-Behnken Design (BBD). The developed method was validated after optimization. The method provided low limits of detection (LODs) ranging from 0.05 to 7 ng/mL; high precisions and reproducibility for both intra- and inter-day analysis (i.e., the relative standard deviations (RSDs) were all less than 8 %); and high accuracy (mean extraction recovery) ranging from 71 to 112 % at different spiked concentration levels. Successfully, the developed method was applied for the analysis of BPs in real water samples.
關鍵字(中) ★ 綠色分析化學技術檢測
★ 金屬有機骨架材料
關鍵字(英)
論文目次 摘要 I
Abstract III
謝誌 VII
目錄 IX
圖目錄 XII
表目錄 XIII
第一章 前言 1
1-1 研究緣起 1
1-2 研究目標 3
第二章 文獻回顧 5
2-1金屬有機骨架材料 5
2-1-1 金屬有機骨架材料簡介 5
2-1-2 機械力化學合成法 8
2-1-3 類沸石咪唑骨架材料ZIF-8 9
2-2分散式微固相萃取法 12
2-2-1 前言 12
2-2-2 原理 13
2-3 防曬乳成分 14
2-3-1二苯基甲酮 14
2-3-2對環境及人類的影響 16
2-3-3毒性研究 17
2-3-4每日暴露量 18
2-3-5相關法規 19
2-4 相關文獻 20
第三章 實驗步驟與樣品分析 23
3-1 實驗藥品與設備 23
3-1-1 實驗藥品 23
3-1-2 儀器設備 25
3-2 實驗步驟 27
3-2-1 標準品配製 27
3-2-2 超高效液相層析串聯質譜儀參數設定 28
3-2-3 質量校正 30
3-2-4 金屬有機骨架材料(MOF)合成 31
3-2-5 分散式微固相萃取法 32
3-2-6 樣品來源 33
第四章 結果與討論 35
4-1 UHPLC-QTOF-MS 對待測物之測定 35
4-1-1 待測物分析及其層析圖 35
4-1-2 待測物之質譜圖 36
4-2 分散式微固相萃取法最佳化條件探討 37
4-2-1 單因子最佳化探討 37
4-2-1-1 吸附過程之超音波震盪溫度 37
4-2-1-2 吸附過程之超音波震盪時間 38
4-2-1-3 脫附過程之Vortex時間 39
4-2-1-4 吸附劑重量 40
4-2-2 Experiment Design 41
4-2-2-1 Box-Behnken Design (BBD)與結果 41
4-2-2-2 因子間交互作用力探討 44
4-2-2-3 殘差分布圖 46
4-2-2-4 最佳化結果 49
4-3 檢量線與偵測極限 50
4-4 方法準確度與精密度 51
4-5 真實樣品檢測 52
4-6 Analytical Eco-Scale 56
4-7 金屬有機骨架材料(ZIF-8)性質探討 59
4-7-1 X射線繞射圖譜 59
4-7-2場發掃描式電子顯微鏡影像 60
4-7-3熱重分析圖 61
4-7-4氮氣等溫吸/脫附儀結果 62
4-8 ZIF-8材料之再現性探討 63
4-9 ZIF-8材料之重複使用率探討 64
第五章 結論 67
第六章 參考文獻 69
參考文獻  台灣質譜學會,質譜分析技術原理與應用,2015
 衛生福利部,衛授食字第1071608162號,2018
 Ameloot, R.; Stappers, L.; Fransaer, J.; Alaerts, L.; Sels, B.F.; De Vos, D.E., Patterned Growth of Metal-Organic Framework Coatings by Electrochemical Synthesis, Chemistry of Materials 2009, 21 (13), 2580-2582.
 Anadón, A.; Bell, D.; Binderup, M.L.; Bursch, W.; Castle, L.; Crebelli, R.; Engel, K.H.; Franz, R.; Gontard, N.; Haertlé, T.; Husøy, T.; Jany, K.D.; Leclercq, C.; Lhuguenot, J.C.; Mennes, W.; Milana, M.R.; Pfaff, K.; Svensson, K.; Toldrá, F.; Waring, R.; Wölfle, D., Toxicological evaluation of benzophenone, The EFSA Journal 2009, 1104, 1-30.
 Anderson, W.A.C.; Castle, L., Benzophenone in cartonboard packaging materials and the factors that influence its migration into food. Food Additives & Contaminants 2003, 20(6), 607-618.
 Asimakopoulos, A.G.; Thomaidis N.S.; Kannan, K., Widespread occurrence of bisphenol A diglycidyl ethers, p-hydroxybenzoic acid esters (parabens), benzophenone type-UV filters, triclosan, and triclocarban in human urine from Athens, Greece. Science of the Total Environment 2014a, 470, 1243-1249.
 Athar, M., Some Nano Bio-Mofs Evaluated For Storage Purpose of Drugs, Biomedical Journal of Scientific & Technical Research 2018, 2 (1), 2348-2359.
 Balázs, A.; Krifaton, C.; Orosz, I.; Szoboszlay, S.; Kovács, R.; Csenki, Z.; Urbányi, B.; Kriszt B., Hormonal activity, cytotoxicity and developmental toxicity of UV filters, Ecotoxicology and Environmental Safety 2016, 131, 45-53.
 Benedé, J.L.; Chisvert, A.; Lucena, R.; Cárdenas, S., A paper-based polystyrene/nylon Janus platform for the microextraction of UV filters in water samples as proof-of-concept, Microchim Acta 2021, 188, 391.
 Benedé, J.L.; Chisvert, A.; Salvador, A,; Sánchez-Quiles, D.; Tovar-Sánchez, A., Determination of UV filters in both soluble and particulate fractions of seawaters by dispersive liquid-liquid microextraction followed by gas chromatography-mass spectrometry, Analytica Chimica Acta 2014, 812, 50-8.
 Box, G.E.P.; Behnken, D.W., Some new three level designs for the study of quantitative variables, Technometrics 1960, 2, 455-475.
 Chaemchuen, S.; Kabir, N.A.; Zhou, K.; Verpoort, F., Metal-organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy, Chemical Society Reviews 2013, 42 (24), 9304-32.
 Chisvert, A.; Benedé, J.L.; Anderson, J.L.; Pierson, S.A.; Salvador, A., Introducing a new and rapid microextraction approach based on magnetic ionic liquids: Stir bar dispersive liquid microextraction, Analytica Chimica Acta 2017, 983, 130-140.
 Chughtai, A.H.; Ahmad, N.; Younus, H.A.; Laypkov, A.; Verpoort, F., Metal-organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations, Chemical Society Reviews 2015, 44 (19), 6804-49.
 Chung, W.H.; Tzing, S.H.; Ding, W.H., Optimization of dispersive micro solid-phase extraction for the rapid determination of benzophenone-type UV absorbers in aqueous samples, Journal of Chromatography A 2015, 1411(15), 12-17.
 Concepción, J.G.; Constable, D.J.C.; Ponder, C.S., Evaluating the “Greenness” of chemical processes and products in the pharmaceutical industry—a green metrics primer, Chemical Society Reviews 2012, 41, 1485-1498.
 Corada-Fernández, C.; Candela, L.; Torres-Fuentes, N.; Pintado-Herrera, M.G.; Paniw, M.; González-Mazo, E., Effects of extreme rainfall events on the distribution of selected emerging contaminants in surface and groundwater: The Guadalete River basin (SW, Spain), Science of the Total Environment 2017, 605, 770-783.
 Coronado, M.; Haro, H.D.; Deng, X.; Rempel, M.A.; Lavado, R.; Schlenk, D., Estrogenic activity and reproductive effects of the UV-filter oxybenzone(2-hydroxy-4-methoxyphenyl-methanone) in fish, Aquatic Toxicology 2008, 90(3), 182-187.
 Czaja, A.; Leung, E.; Trukhan, N., Industrial MOF Synthesis.In Metal–Organic Frameworks, Chemical Society Reviews 2009, 38, 1284–1293.
 D’Alessandro, D.M.; Smit, B.; Long, J.R., Carbon Dioxide Capture: Prospects for New Materials, Angewandte Chemie International Edition 2010, 49, 6058-6082.
 Do, J.L.; Frisčic, T., Mechanochemistry: A Force of Synthesis, ACS Central Science 2017, 3, 13-19.
 Everett, D.H., Manual of Symbols and Terminology for Physicochemical Quantities and Units, Pure and Applied Chemistry 1972, 31(4), 577.
 Farha, O.K.; Mulfort, K.L.; Thorsness, A.M.; Hupp, J.T., Separating Solids: Purification of Metal-Organic Framework Materials, Journal of the American Chemical Society 2008, 130 (27), 8598-8599.
 Friščić, T.; Childs, S.L.; Rizvi, S.A.A.; Jones, W., The role of solvent in mechanochemical and sonochemical cocrystal formation: a solubility-based approach for predicting cocrystallisation outcome, CrystEngCom 2009, 11, 418-426.
 Gałuszka, A.; Konieczka, P.; Migaszewski, Z.M.; Namies´nik, J., Analytical Eco−Scale for assessing the greenness of analytical procedures, Trends in Analytical Chemistry 2012, 37, 61-72.
 Ge, D.; Lee. H.K., Sonication-assisted emulsification microextraction combined with vortex-assisted porous membrane-protected micro-solid-phase extraction using mixed zeolitic imidazolate frameworks 8 as sorbent, Journal of Chromatography A 2012, 1263, 1-6.
 Ge, D.; Zhang, Y.; Dai, Y.; Yang, S., Air-assisted dispersive liquid–liquid microextraction based on a new hydrophobic deep eutectic solvent for the preconcentration of benzophenone-type UV filters from aqueous samples, Journal of Separation Science 2017, 41(7), 1635-1643.
 Giokas, D.L.; Salvador, A.; Chisvert, A., UV filters: From sunscreens to human body and the environment, Trends in Analytical Chemistry 2007, 26, 5.
 Gonzalez, H.; Jacobson, C.E.; Wennberg, A.M.; Larkö, O.; Farbrot, A., Solid-Phase Extraction and Reverse-Phase HPLC: Application to Study the Urinary Excretion Pattern of Benzophenone-3 and its Metabolite 2,4-Dihydroxybenzophenone in Human Urine, Analytical Chemistry Insights 2008, 3, 1-7.
 Ho, Y.C.; Ding, W.H., Solid-phase Extraction Coupled Simple On-line Derivatization Gas Chromatography Tandem Mass Spectrometry for the Determination of Benzophenone-type UV Filters in Aqueous Samples, Journal of the Chinese Chemical Society 2012, 59, 107-113.
 Huang, C.; Qiao, X.; Sun, W.; Chen, H.; Chen, X.; Zhang, L.; Wang, T., Effective Extraction of Domoic Acid from Seafood Based on Postsynthetic-Modified Magnetic Zeolite Imidazolate Framework‑8 Particles, Analytical Chemistry 2019, 91, 3, 2418-2424.
 Huang, X.C.; Lin, Y.Y.; Zhang, J.P.; Chen, X.M, Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(ii) Imidazolates with Unusual Zeolitic Topologies, Angewandte Chemie International Edition 2006, 45, 1557-1559.
 Jeon, H.K.; Chung, Y.; Ryua, J.C., Simultaneous determination of benzophenone-type UV filters in water and soil by gas chromatography–mass spectrometry, Journal of Chromatography A 2006, 1131, 192-202.
 Jiang, J.Q.; Yang, C.X.; Yan, X.P., Zeolitic Imidazolate Framework‑8 for Fast Adsorption and Removal of Benzotriazoles from Aqueous Solution, ACS Applied Materials & Interfaces 2013, 5, 9837-9842.
 Kawaguchi, M.; Ito, R.; Endo, N.; Sakui, N.; Okanouchi, N.; Saito, K.; Sato, N.; Shiozaki, T.; Nakazawa, H., Stir bar sorptive extraction and thermal desorption-gas chromatography-mass spectrometry for trace analysis of benzophenone and its derivatives in water sample, Analytica Chimica Acta 2006, 557, 272-277.
 Kim, S.; Jung, D.; Kho Y.; Choi, K., Effects of benzophenone-3 exposure on endocrine disruptionand reproduction of Japanese medaka (Oryzias latipes)—A twogeneration exposure study, Aquatic Toxicology 2014, 155, 244-252.
 Klinowski, J.; Paz, F.A.; Silva, P.; Rocha, J., Microwave-assisted synthesis of metal-organic frameworks, Dalton Transactions 2011, 40 (2), 321-30.
 Kotnik, K.; Kosjek, T.; Krajnc, U.; Heath, E., Trace analysis of benzophenone-derived compounds in surface waters and sediments using solid-phase extraction and microwave-assisted extraction followed by gas chromatography–mass spectrometry, Analytical and Bioanalytical Chemistry 2014, 406, 3179-3190.
 Kreno, L.E.; Leong, K.; Farha, O.K.; Allendorf, M.; Van Duyne, R.P.; Hupp, J.T., Metal-organic framework materials as chemical sensors, Chemical Reviews 2012, 112 (2), 1105-25.
 Ku, P.C.; Liu, T.Y.; Lee, S.H.; Kung, T.A.; Wang, W.H., An environmentally friendly strategy for determining organic ultraviolet filters in seawater using liquid-phase microextraction with liquid chromatography-tandem mass spectrometry, Environmental Science and Pollution Research 2020, 27(9), 9818-9825.
 Kung, T.A.; Lee, S.H.; Yang, T.C.; Wang, W.H., Survey of selected personal care products in surface water of coral reefs in Kenting National Park, Taiwan, Science of the Total Environment 2018, 635, 1302-1307.
 Kunisue, T.; Chen, Z.; Louis, G.M.B.; Sundaram, R.; Hediger, M.L..; Sun, L.; Kannan, K., Urinary Concentrations of Benzophenone-type UV Filters in U.S. Women and Their Association with Endometriosis, Environmental Science & Technology 2012, 46, 4624-4632.
 Li, N.; Zhou, L.; Jin, X.; Owens, G.; Chen, Z., Simultaneous removal of tetracycline and oxytetracycline antibiotics from wastewater using a ZIF-8 Metal Organic-Framework, Journal of Hazardous Materials 2018, 366, 563-572.
 Li, X.; Ma, W.; Li, H.; Bai, Y.; Liu, H., Metal-organic frameworks as advanced sorbents in sample preparation for small organic analytes, Coordination Chemistry Reviews 2019, 397, 1-13.
 Liao, C.; Kannan, K., Widespread Occurrence of Benzophenone-Type UV Light Filters in Personal Care Products from China and the United States: An Assessment of Human Exposure, Environmental Science & Technology 2014, 48, 4103-4109.
 Liu, X.; Wang, C.; Wang, Z.; Wu, Q.; Wang, Z., Nanoporous carbon derived from a metal organic framework as a new kind of adsorbent for dispersive solid phase extraction of benzoylurea insecticides, Microchimica Acta 2015, 182(11).
 Liu, Y.; Kita, H.; Tanaka, K.; Imawaka, K.; Tanaka, S.; Takewaki, T., Mechanochemically synthesized ZIF-8 nanoparticles blended into 6FDA-TrMPD membranes for C3H6/C3H8 separation, Journal of Applied Polymer Science 2020, 138(16), 50251.
 Mao, F.; You, L.; Reinhard, M.; He, Y.; Gin, K.Y.H., Occurrence and Fate of Benzophenone-Type UV Filters in a Tropical Urban Watershed, Environmental Science & Technology 2018, 52(7), 3960-3967.
 Miller, S.E.; Teplensky, M.H.; Moghadam, P.Z.; Fairen-Jimenez, D., Metal-organic frameworks as biosensors for luminescence-based detection and imaging, Interface Focus 2016, 6 (4), 20160027.
 Nasir Baig, R.B.; Varma, R.S., Alternative energy input: mechanochemical, microwave and ultrasound-assisted organic synthesis, Chemical Society Reviews 2012, 41, 1559-1584.
 Negreira, N.; Rodríguez, I.; Ramil, M.; Rubí, E.; Cela, R., Solid-phase extraction followed by liquid chromatography–tandem mass spectrometry for the determination of hydroxylated benzophenone UV absorbers in environmental water samples, Analytica Chimica Acta 2009, 654, 162-170.
 Park, K.S.; Ni, Z.; Coˆte´, A.P.; Choi, J.Y.; Huang, R.; Uribe-Romo, F.J; Chae, H.K.; O’Keeffe, M.; Yaghi, O.M., Exceptional chemical and thermal stability of zeolitic imidazolate frameworks, PNAS 2006, 103 (27), 10186-10191.
 Phan, A,; Doonan, C.J.; Uribe-Romo, F.J.; Knobler, C.B.; O’Keeffe, M.; Yaghi, O.M., Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks, Accounts of Chemical Research 2010, 43, 1, 58–67.
 Philippat, C.; Mortamais, M.; Chevrier, C.; Petit, C.; Calafat, A.M.; Ye, X.; Silva, M.J.; Brambilla, C.; Pin, I.; Charles, M.A.; Cordier, S.; Slama, R., Exposure to Phthalates and Phenols during Pregnancy and Offspring Size at Birth, Environmental Health Perspectives 2012, 120(3), 464-470.
 Pichon, A.; Lazuen-Garay, A.; James, S.L., Solvent-free synthesis of a microporous metal–organic framework, CrystEngComm 2006, 8 (3), 211.
 Qi, C.; Cai, Q.; Zhao, P.; Jia, X.; Lu, N.; He, L.; Hou, X., The metal-organic framework MIL-101(Cr) as efficient adsorbent in a vortex-assisted dispersive solid-phase extraction of imatinib mesylate in rat plasma coupled with ultra-performance liquid chromatography/mass spectrometry: Application to a pharmacokinetic study, Journal of Chromatography A 2016, 1449, 30–38.
 Qiang,Y.; Wang, W.F.; Dhodary, B.; Yang, J.L., Zeolitic imidazolate framework 8 (ZIF-8) reinforced macroporous resin D101 for selective solid-phase extraction of 1-naphthol and 2-naphthol from phenol compounds, Electrophoresis 2017, 38(13-14), 1685-1692.
 Qiu, L.G.; Li, Z.Q.; Wu, Y.; Wang, W.; Xu, T.; Jiang, X., Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines, Chemical Communications 2008, 3642–3644.
 Rabenau, A., The Role of Hydrothermal Synthesis in Preparative Chemistry, Angewandte Chemie International Edition 1985, 24, 1026-1040.
 Rocío-Bautista, P.; González-Hernández, P.; Pino, V.; Pasán, J.; Afonso, A.M., Metal-organic frameworks as novel sorbents in dispersive-based microextraction approaches, TrAC Trends in Analytical Chemistry 2017, 90, 114-134.
 Rodríguez-Gómez, R.; Zafra-Gómez, A.; Dorival-García, N.; Ballesteros, O.; Navalón, A.; Determination of benzophenone-UV filters in human milk samples using ultrasound-assisted extraction and clean-up with dispersive sorbents followed by UHPLC–MS/MS analysis, Talanta 2014, 134, 657-664.
 Sánchez-Brunete, C.; Miguel, E.; Albero, B.; Tadeo, J.L., Analysis of salicylate and benzophenone-type UV filters in soils and sediments by simultaneous extraction cleanup and gas chromatography–mass spectrometry, Journal of Chromatography A 2011, 1218, 4291-4298.
 Senosy, I.A.; Guo, H.M.; Ouyang, M.N.; Lu, Z.H.; Yang, Z.H.; Li, J.H., Magnetic solid-phase extraction based on nano-zeolite imidazolate framework-8-functionalized magnetic graphene oxide for the quantification of residual fungicides in water, honey and fruit juices, Food Chemistry 2020, 325, 126944.
 Sheberla, D.; Bachman, J.C.; Elias, J.S.; Sun, C.J.; Shao-Horn, Y.; Dincă, M., Conductive MOF electrodes for stable supercapacitors with high areal capacitance, Nature Materials 2016, 16, 220.
 Shekhah, O.; Liu, J.; Fischer, R.A.; Woll, C., MOF thin films: existing and future applications, Chemical Society Reviews 2011, 40 (2), 1081-106.
 Stock, N.; Biswas, S., Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites, Chemical Reviews 2012, 112 (2), 933-969.
 Sun, L.; Tang, W.; Zhu, T.; Row, K.H., Efficient Adsorptive Separation and Determination of Phenolic Acids from Orange Peels Using Hyper-Crosslinked Polymer Based Zeolitic Imidazolate Framework-8 (ZIF-8) Composites, Analytical Letters 2020, 55(3), 2636-2655.
 Taghvimi, A.; Tabrizi, A.B.; Dastmalchi, S.; Javadzadeh, Y., Metal organic framework based carbon porous as an efficient dispersive solid phase extraction adsorbent for analysis of methamphetamine from urine matrix, Journal of Chromatography B 2019, 1109, 149-154.
 Taheri, M.; Bernardo, I.D.; Lowe, A.; Nisbet, D.R.; Tsuzuki, T., Green Full Conversion of ZnO Nanopowders to Well-Dispersed Zeolitic Imidazolate Framework‑8 (ZIF-8) Nanopowders via a Stoichiometric Mechanochemical Reaction for Fast Dye Adsorption, Crystal Growth & Design 2020, 20, 4, 2761-2773.
 Tang, R.; Chen, M.J.; Ding, G.D.; Chen, X.J.; Han, X.M.; Zhou, K.; Chen, L.M.; Xia, Y.K.; Tian, Y.; Wang, X.R., Associations of prenatal exposure to phenols with birth outcomes, Environmental Pollution 2013, 178, 115-120.
 Tranchemontagne, D.J.; Hunt, J.R.; Yaghi, O.M., Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0, Tetrahedron 2008, 64 (36), 8553-8557.
 Tsui, M.M.P; Leung, H.W.; Wai, T.C.; Yamashita, N.; Taniyasu, S.; Liu, W.; Lam, P.K.S.; Murphy, M.B., Occurrence, distribution and ecological risk assessment of multiple classes of UV filters in surface waters from different countries, Water Research 2014, 67, 55-65.
 Vela-Soria, F..; Ballesteros, O.; Zafra-Gómez, A.; Ballesteros, L.; Navalón, A., A new method for the determination of benzophenone-UV filters in human serum samples by dispersive liquid–liquid microextraction with liquid chromatography–tandem mass spectrometry, Talanta 2014, 121, 97-104.
 Vela-Soria, F.; Jiménez-Díaz, I.; Rodríguez-Gómeza, R.; Zafra-Gómeza, A.; Ballesterosa, O.; Navalóna, A.; Vílcheza, J.L.; Fernándezb, M.F.; Olea, N., Determination of benzophenones in human placental tissue samples by liquid chromatography–tandem mass spectrometry, Talanta 2011, 85, 1848-1855.
 Wang, T.E.; Guo, M.; Song, W.L.; Zhang, Y.D.; Du, X.Z., A new nitrogen-containing carbon nanoparticles coated stainless steel fiber for selective solid-phase microextraction of ultraviolet filters, Analytical Methods 2015, 7, 3385-3394.
 Wang, Y.; Jin, S.; Wang, Q.; Lu, G.; Jiang, J.; Zhu, D., Zeolitic imidazolate framework-8 as sorbent of micro-solid-phase extraction to determine estrogens in environmental water samples, Journal of Chromatography A 2013, 1291, 27-32.
 Wasserstein, R.L.; Lazar, N.A., The ASA′s statement on p-values: context, process, and purpose, The American Statistician 2016, 70, 129-133.
 Watanabe, Y.; Kojima, H.; Takeuchi, S.; Uramaru, N.; Sanoh, S.; Sugihara, K.; Shigeyuki Kitamura.; Shigeru Ohta., Metabolism of UV-filter benzophenone-3 by rat and human liver microsomes and its effect on endocrine-disrupting activity, Toxicology and Applied Pharmacology 2015, 282, 119-128.
 Wei, T.H.; Wu, S.H.; Yi-Da Huang, Y.D.; Lo, W.S.; Williams, B.P.; Sheng-Yu Chen, S.Y.; Yang, H.C.; Hsu, Y.S.; Lin, Z.Y.; Chen, X.H.; Kuo,P.E.; Chou, L.Y.; Tsung, C.K.; Shieh, F.K., Rapid mechanochemical encapsulation of biocatalysts into robust metal–organic frameworks, Nature Communications 2019, 10, 5002.
 Weisbrod, C.J.; Kunz, P.Y.; Zenker, A.K.; Fent, K., Effects of the UV filter benzophenone-2 on reproduction in fish, Toxicology and Applied Pharmacology 2007, 225, 255-266.
 Wolff, M.S.; Engel, S.M.; Berkowitz, G.S.; Ye, X.; Silva, M.J.; Zhu, C.; Wetmur, J.; Calafat, A.M., Prenatal Phenol and Phthalate Exposures and Birth Outcomes, Environmental Health Perspectives 2008, 116(8), 1092-1097.
 Wu, H.; Zhou, W.; Yildirim, T., Hydrogen Storage in a Prototypical Zeolitic Imidazolate Framework-8, Journal of the American Chemical Society 2007, 129, 5314-5315.
 Yang, X.; Xu, Q., Bimetallic Metal–Organic Frameworks for Gas Storage and Separation, Crystal Growth & Design 2017, 17 (4), 1450-1455.
 Ye, L.; Liu, J.; Yang, X., Peng, Y.; Xu, L., Orthogonal array design for the optimization of ionic liquid-based dispersive liquid–liquid microextraction of benzophenone-type UV filters, Journal of Separation Science 2010, 34, 700-706.
 Yen, C.I.; Liu, S.M.; Lo, W.S.; Wu, J.W.; Liu, Y.H.; Chein, R.J.; Yang, R.; Wu, K.C.; Hwu, J.R.; Ma, N.; Shieh, F.K., Cytotoxicity of Postmodified Zeolitic Imidazolate Framework-90 (ZIF-90) Nanocrystals: Correlation between Functionality and Toxicity, Chemistry Europe 2016, 22 (9), 2925-9.
 Zhou, H.C.; Long, J.R.; Yaghi, O.M., Introduction to metal-organic frameworks, Chemical Reviews 2012, 112 (2), 673-4.
指導教授 丁望賢(Wang-Hsien Ding) 審核日期 2022-6-27
推文 facebook   plurk   twitter   funp   google   live   udn   HD   myshare   reddit   netvibes   friend   youpush   delicious   baidu   
網路書籤 Google bookmarks   del.icio.us   hemidemi   myshare   

若有論文相關問題,請聯絡國立中央大學圖書館推廣服務組 TEL:(03)422-7151轉57407,或E-mail聯絡  - 隱私權政策聲明