博碩士論文 109326027 詳細資訊




以作者查詢圖書館館藏 以作者查詢臺灣博碩士 以作者查詢全國書目 勘誤回報 、線上人數:117 、訪客IP:18.224.68.242
姓名 郭沛妤(Pei-Yu Kuo)  查詢紙本館藏   畢業系所 環境工程研究所
論文名稱 運用靜電紡絲碳纖維電極複合錳氧化物於電容去離子系統進行結晶紫之脫色研究
(Decolorization of crystal violet by electrospinning carbon fiber modified MnOx electrode in capacitive deionization system)
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摘要(中) 電容去離子(CDI)是新穎的水再生技術,透過施加低外部電壓形成靜電場,將水中的離子吸附到電極的孔洞之中,是具有低能耗、低成本的優勢。在本研究中,運用靜電紡絲技術製備出碳纖維(CF),作為電容器的電極使用,再利用水熱合成法、電鍍法與滴製法,製成複合錳氧化物的碳奈米纖維,透過掃描式電子顯微鏡觀察纖維的形貌,運用循環伏安法檢測電極的電化學性能,透過此方式篩選出電鍍方法所製備的複合電極(MnCF-EP)進行脫鹽與結晶紫(CV)脫色的電容去離子實驗。
此研究結果顯示,在NaCl與CV溶液中,CF與MnCF-EP兩種電極皆具有去除NaCl與CV的能力。在NaCl與CV混合溶液中,CF與MnCF EP電極對CV的去除率分別為8.77%與33.43%,在此MnCF-EP具有較優異的去除率是因為電極不同於CF的特性,MnCF-EP具有MnOx附著、粗糙的表面、較多的孔隙,以及多了OH基提升親水性。MnCF-EP透過吸附、氧化與類似染料敏化太陽能電池的反應,將CV從溶液中去除。
結果表明,複合MnOx在CF上可能會帶來催化的效果,將此種電極用於CDI中,能同時去除離子與有機物。操作後的電極可觀察到電極發生的改變。結果表明製備的CF與MnCF-EP電極皆具有從含有NaCl的水中去除CV的能力,同時MnCF-EP對CV的去除能力優於CF。
摘要(英) Capacitive deionization (CDI) is a novel water regeneration technology. Through applied a low external voltage to form an electrostatic field, ions are adsorbed into the pores of the electrode, which has the advantages of low energy consumption and low cost. Manganese oxidation complex carbon fiber electrode (MnCF) was prepared by hydrothermal synthesis, electrodeposition, and dripping. The morphology characteristics of the fibers were observed by field emission scanning electron microscope, and the electrochemical performance of the electrode was detected by cyclic voltammetry. In this way, the composite electrode prepared by electrodeposition was chosen for CDI experiments of desalination and crystal violet (CV) decolorization.
The result showed that the CF and MnCF-EP electrode had ability to remove NaCl and CV from NaCl or CV solution. In the NaCl and CV mixed solution, the removal efficiency by CF and MnCF-EP electrode had 8.77% and 43.28%, respectively. MnCF-EP electrode had better removal efficiency than CF, because of the different characteristics. MnCF-EP had MnOx, rough surface, more pores, and -OH group to improve hydrophilicity. The MnCF-EP could remove CV from the solution by adsorption, oxidation, and reaction similar to dye-sensitized solar cell.
The result suggested that composite of MnOx on CF may introduce catalytic properties on CF. The CDI equipped with such electrodes can remove ions and organic compounds at the same time. The change of used electrode could be observed. The CF and MnCF-EP electrodes both had ability to remove the CV from the solution, and MnCF-EP had better ability than CF.
關鍵字(中) ★ 電容去離子
★ 靜電紡絲
★ 碳纖維修飾
★ 錳氧化物
★ 結晶紫
關鍵字(英) ★ capacitive deionization
★ electrospinning
★ carbon fiber modification
★ manganese oxidation
★ crystal violet
論文目次 摘要 v
Abstract vii
誌謝 ix
Content xi
List of Figure xiv
List of Table xvii
Chapter 1 Introduction 1
1.1 Background 1
1.2 Objective 3
Chapter 2 Literature Review 5
2.1 Capacitive deionization 5
2.1.1 Theory of capacitive deionization 6
2.1.2 Capacitor 7
2.2 Electrode material for CDI 13
2.2.1 Material of carbon electrode 13
2.2.2 Electrospinning 13
2.2.3 Modification of CDI electrode 19
2.3 Manganese oxide 21
2.3.1 Introduction of manganese dioxide 22
2.3.2 Preparation of manganese oxide modified electrode 24
2.4 Removal of dye by MnOx 26
2.4.1 Crystal violet 26
2.4.2 Oxidation of dye by MnOx 27
Chapter 3 Materials and Methods 28
3.1 Materials and Chemicals 28
3.2 Equipments and Instruments 29
3.3 Material Preparation 30
3.3.1 Preparation of carbon fiber (CF) 30
3.3.2 Preparation manganese oxide modified carbon fiber (MnCF) 33
3.4 Material Characterization 39
3.5 CDI operation system 41
3.5.1 Fabrication of CDI electrodes 41
3.5.2 CDI operation system 42
3.6 Data Analysis 43
3.6.1 Ion chromatography system, IC 43
3.6.2 Ultraviolet-visible spectrophotometer, UV-Vis 44
3.6.3 Adsorption amount 45
Chapter 4 Results and Discussions 46
4.1 Characterization of electrode materials 46
4.1.1 Morphology characterization of CF and MnCF 46
4.1.2 XRD analysis 61
4.1.3 Functional groups on CF and MnCF 63
4.1.4 Electrochemical characteristics 65
4.2 CDI performance of NaCl deionization & CV decolorization 71
4.2.1 NaCl deionization 71
4.2.2 CV decolorization 74
4.2.3 NaCl and CV mixed solution in CDI 78
4.2.4 Removal amount of NaCl deionization and CV decolorization 84
Chapter 5 Conclusions and Suggestions 89
5.1 Conclusions 89
5.2 Suggestions 91
Reference 92
Appendix 102
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指導教授 秦靜如 審核日期 2023-2-1
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