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姓名	龔成浩(Cheng-Hao Kung)  查詢紙本館藏	畢業系所	化學工程與材料工程學系
論文名稱	鈷擴散阻障層對碲化鍺熱電模組性質與 界面穩定度影響之研究 (Effect of Cobalt Diffusion Barrier on Thermoelectric Property of GeTe Thermoelectric Joint for Enhanced Performance and Thermal Stability)
相關論文	★ 錫碲擴散偶之擴散阻障層界面反應 ★ 熱電材料與擴散阻障層在電流影響下的界面反應研究 ★ 無鉛銲料與無電鍍鈷基板於多次迴焊之界面反應與可靠度測試 ★ 無電鍍鎳磷層應用於熱電材料與無鉛銲料之界面研究 ★ 高可靠度車用印刷電路板之表面處理層開發 ★ 共濺鍍銅鈦薄膜之相分離演化機制與其對機械性質於3DIC接合的影響 ★ 添加微量錫銀銅合金之銅薄膜與銅基板之接合研究 ★ 新式低溫合金焊料之開發與界面反應探討及可靠度分析 ★ 電遷移對純錫導線晶粒旋轉之研究 ★ 以同步輻射臨場量測電遷移對純錫導線應力分佈之研究 ★ 鋁鍺薄膜封裝研究 ★ 無鉛銲料錫銀鉍銦與銅電極之電遷移研究 ★ 以表面處理及塗佈奈米粒子抑制錫晶鬚生長 ★ 鋁鍺雙層薄膜之擴散行為與金屬誘發結晶現象研究 ★ 鋁(銅)與鎳混合導線於矽通孔製程之電遷移現象研究 ★ 無鉛銲料與碲化鉍基材之界面反應研究
檔案	[Endnote RIS 格式]    [Bibtex 格式]    [相關文章]   [文章引用]   [完整記錄]   [館藏目錄]   至系統瀏覽論文 (2029-7-31以後開放)
摘要(中)	在面對全球性氣候暖化危機的迫切需要下，實現淨零碳排放和碳中和已成為一項全球性的共同目標。不排放污染、結構簡單以及能夠將來自自然界、工業和汽車的廢熱轉換為電能的特點使得熱電發電裝置成為一項具有前景的技術。對於中溫區間段(200-500 oC)塊材熱電模組來說，高溫導致的原子擴散將影響模組的性能。本研究旨在發現加入鈷（Co）擴散屏障層能增強p型GeTe塊材的熱電性能，並探討影響模組性能的界面反應，因為模組內熱電材料跟電極之間的穩定連接對於確保熱電裝置的可靠性至關重要。透過分析GeTe的晶體結構及熱電性值的結果，表現出在添加Co擴散阻障層後GeTe的熱電效能（zT）值顯著增加。藉由電子微探儀（EPMA）分析，發現Co會朝GeTe擴散並反應出Co-Te界金屬化合物。在經歷了長時間熱處理測試後，銅電極與GeTe之間的界面接觸電阻有明顯增加。將Co阻障層電鍍到GeTe再經過長期熱處理後，電導率有所提高但材料的熱導率卻降低，發生這樣的改變是因為Co原子已經擴散到GeTe晶格中的空缺位置，造成聲子散射從而影響到熱導率。最後從結果發現添加Co阻障層並不會降低zT值，相反地電鍍Co阻障層能使p型GeTe的zT值增加56%。此外本研究強調的是探討GeTe zT值的提升，而不是追求極高的峰值。
摘要(英)	Achieving net zero carbon emissions and carbon neutrality has emerged as a global imperative in addressing the climate crisis. The qualities like no emission pollution, simple structure, and the ability to convert waste heat generated from nature, industry, and automobiles into electrical energy make thermoelectric power generation devices a promising technology. For mid-temperature bulk thermoelectric modules, the diffusion of atoms induced by higher temperature will affects the module’s performance. This study investigates the influence on thermoelectric properties of p-type GeTe after integrating cobalt (Co) diffusion barrier and focuses on the interfacial reactions in GeTe joint that degrade thermoelectric performance. It is essential to establish stable interconnections in the joint for ensuring the reliability of the device. The research highlights the significantly increased the figure of merit (zT) values of GeTe after adding of Co diffusion barrier by examining its improved thermoelectric properties. The diffusion of Co into GeTe and the formation of Co-Te intermetallic compounds were revealed through EPMA analysis. There is a substantial increase in contact resistivity of the GeTe joint after aging. However, electrical conductivity improves and thermal conductivity decreases after depositing Co and subjecting it to long-term aging. This improvement occurs because the Co atoms, which have diffused into the GeTe lattice, occupy vacancy sites. Instead of degrading the zT value, Co deposition leads to a 56% increase in the zT value for the p-type GeTe joint. This study emphasizes the improvement of the zT value rather than pursuing a high peak zT value for GeTe.
關鍵字(中)	★ 熱電塊材 ★ 熱電性質 ★ 擴散阻障層 ★ 鍺碲基 ★ 菱面體結構 ★ 交互擴散	關鍵字(英)	★ Thermoelectric bulk material ★ Thermoelectric property ★ Diffusion barrier ★ GeTe ★ Rhombohedral structure ★ Interdiffusion
論文目次	摘要 i Abstract ii 致謝 iii Table of Contents v List of Figures vii List of Tables x CHAPTER 1 Introduction 11 1-1 Background 11 1-2 Thermoelectric Material 15 1-2-1 Fundamental Theory and Thermoelectric Property 15 1-2-2 Applications of Thermoelectric Device 18 1-3 GeTe-based Thermoelectric Material 22 1-4 Interfacial Stability for GeTe-Based Thermoelectric Modules 25 1-4-1 Diffusion Soldering 26 1-4-2 Spark plasma sintering 28 1-4-3 Hot-press bonding 30 1-5 Electroplated Cobalt as diffusion barrier 32 1-6 Evaluation of GeTe Thermoelectric Module 35 CHAPTER 2 Motivation 38 CHAPTER 3 Experimental Procedure 40 3-1 Sample Preparation 40 3-1-1 Fabrication of GeTe Bulk Material 40 3-1-2 Electroplating 41 3-2 Interfacial reaction 43 3-3 Contact Resistivity 45 3-4 Thermoelectric Properties 47 CHAPTER 4 Results and Discussion 48 4-1 Characterization of GeTe Bulk Material and Electroplated Co Layer 48 4-2 Interfacial Reaction & Diffusion Behavior 52 4-2-1 Interfacial Reaction without diffusion barrier in GeTe module 52 4-2-2 Interfacial Reaction with diffusion barrier in GeTe module 54 4-3 Contact Resistivity 63 4-4 Thermoelectric Properties 67 4-4-1 Thermoelectric Properties of GeTe bulk material 67 4-4-2 Thermoelectric Properties of GeTe/Co Samples 72 4-4-3 Thermal Conductivity & zT value of GeTe & GeTe/Co samples 73 Chapter 5 Conclusion 77
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指導教授	吳子嘉(Tzu-Chia Wu)	審核日期	2024-9-12
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