熱處理對廢玻璃纖維作為 CLSM 摻料再利用之影響探討-以鉬金屬為例

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林永祥(Yung-Hsiang Lin) 查詢紙本館藏

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論文名稱

熱處理對廢玻璃纖維作為 CLSM 摻料再利用之影響探討-以鉬金屬為例

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至系統瀏覽論文 (2026-7-31以後開放)

摘要(中)

本研究針對廢棄電路板經物理處理後衍生之含鉬廢玻璃纖維，探討廢玻璃纖維樣品經熱處理前、後作為摻料製成控制性低強度回填材料(CLSM)，並經過養生後鉬溶出率之變化。經初步篩選後之22個廢玻璃纖維作為研究樣品，其中鉬含量最低5.4 ± 0.4 mg/kg，最高為344.9 ± 14.5 mg/kg，平均鉬含量為149.9 ± 89.3 mg/kg；平均鉬溶出率為0.19 ± 0.08 %。經熱處理後，平均鉬溶出率上升至9.09 ± 0.63 %。當CLSM加入15%廢玻璃纖維作為摻料，經養生後均符合再生粒料環境用途溶出標準(0.7 mg/L)。另將熱處理後之廢玻纖分別以15%、10%、5%作為CLSM摻料，由於水泥水化作用形成之AFm相、AFt相及C-S-H水化物固定鉬，使得CLSM鉬溶出率降低；經養生21日後，CLSM鉬含量高於40 mg/kg者 (37個)，鉬溶出濃度皆高於標準，低於20 mg/kg (15個)則全數合格。因此建議含鉬之廢玻璃纖維可直接再利用作為CLSM摻料；而經熱處理之廢玻璃纖維則否，若需再利用則可將鉬含量控制於20 mg/kg以下，以降低鉬溶出之風險。

摘要(英)

This study investigates the molybdenum-containing waste glass fibers derived from waste printed circuit boards (PCBs) after physical treatment. It examines the changes in molybdenum leaching rates before and after heat treatment of waste glass fiber samples used as additives to produce controlled low-strength material (CLSM). Among the 22 waste glass fiber samples collected for the study, the molybdenum content ranged from a minimum of 5.4 ± 0.4 mg/kg to a maximum of 344.9 ± 14.5 mg/kg, with an average molybdenum content of 149.9 ± 89.3 mg/kg. The average molybdenum leaching rate was 0.19 ± 0.08%. After heat treatment, the average molybdenum leaching rate increased to 9.09 ± 0.63%. When 15% waste glass fibers was added to CLSM as an additive, the molybdenum leaching rate after curing met the environmental use leaching standard for recycled aggregates (0.7 mg/L). Additionally, when heat-treated waste glass fibers were used as CLSM additives at 15%, 10%, and 5%, the molybdenum leaching rate decreased due to the fixation of molybdenum by AFm phase, AFt phase, and C-S-H hydrates formed during cement hydration. After 21 days of curing, CLSM samples with molybdenum content higher than 40 mg/kg (37 samples) exceeded the standard for molybdenum leaching, while those with molybdenum content lower than 20 mg/kg (15 samples) all met the standard. Therefore, it is recommended that molybdenum-containing waste glass fibers can be directly reused as CLSM additives. However, heat-treated waste glass fibers should not be reused unless the molybdenum content is controlled below 20 mg/kg to reduce the risk of molybdenum leaching.

關鍵字(中)

★ 熱處理
★ 廢玻璃纖維
★ CLSM
★ 鉬溶出

關鍵字(英)

★ Heat treatment
★ Waste glass fiber
★ CLSM
★ Molybdenum leaching

論文目次

摘　　　　要 I
ABSTRACT II
目　　　　錄 V
圖目錄 VIII
表目錄 X
第一章　前言 1
1-1 研究緣起 1
1-2 研究目的 2
第二章　文獻回顧 3
2-1 玻璃纖維 3
2-1-1 玻璃纖維種類 3
2-1-2 廢玻璃纖維處理方式 6
2-1-3 玻璃纖維應用於混凝土摻料 9
2-1-4 我國廢玻璃纖維現況 10
2-2 印刷電路板 16
2-2-1 印刷電路板的組成 16
2-2-2 廢印刷電路板處理方式 19
2-3 安定化/穩定化處理 22
2-3-1 鉬 22
2-3-2 水泥固化法 24
第三章　研究方法 30
3-1 研究流程 30
3-2 實驗設備及流程 31
3-2-1 實驗方法 31
3-2-2 儀器說明 33
3-3 分析方法 34
3-3-1 再生粒料環境用途溶出程序 34
3-3-2 廢棄物及底泥中金屬檢測方法 36
3-3-3 事業廢棄物水分測定方法 37
3-3-4 廢棄物中灰分、可燃分測定方法 38
第四章　結果與討論 39
4-1 廢玻璃纖維樣品篩選 39
4-2 基本性質 41
4-2-1 水分 41
4-2-2 灰分及可燃分 44
4-3 廢玻璃纖維 48
4-3-1 廢玻璃纖維鉬含量 48
4-3-2 廢玻璃纖維鉬溶出濃度及溶出率 51
4-3-3 熱處理後之廢玻璃纖維鉬含量及溶出濃度 53
4-4 廢玻璃纖維作為CLSM摻料 58
4-4-1 廢玻璃纖維作為CLSM摻料 - 15% 58
4-4-2 熱處理後之廢玻璃纖維作為CLSM摻料 – 15% 64
4-4-3熱處理後之廢玻璃纖維作為CLSM摻料 – 10% 72
4-4-4 熱處理後之廢玻璃纖維作為CLSM摻料 – 5% 79
第五章　結論與建議 88
參考文獻 91
附錄一　玻璃纖維原樣、去水分及灰分樣品 101

參考文獻

AGY strength in materials, "High strength glass fibers, an overview of glass fiber technology", 2021. https://www.agy.com/wp-content/uploads/2022/03/AGY_HighStBro_HR.pdf
Argumedo-Delira, R., Díaz-Martínez, M. E., Gómez-Martínez, M. J., "Microorganisms and plants in the recovery of metals from the printed circuit boards of computers and cell phones: a mini review", Metals, Vol 10, Issue 9, August 2020.
Ari, V., Das, A., "Kinetics and efficacy of froth flotation for the recovery of metal values from pulverized printed circuit boards", XXVI International Mineral Processing Congress (IMPC) 2012, New Delhi, September 2012.
Baig, A. A. M., An, J., Nam, B. H., "Recycling of municipal solid waste incineration (MSWI) ash as aggregate replacement in Portland cement concrete", pp. 2797-2806, IFCEE 2015, San Antonio, March 2015.
Bashir, S. T., Yang, L., Liggat, J. J., Thomason, J. L., "Kinetics of dissolution of glass fibre in hot alkaline solution", Journal of Materials Science, Vol 53, Issue , February 2018.
Chandramouli, K., Rao, S. P., Pannirselvam, N., Sekhar, S. T., Sravana, P., "Strength properties of glass fibre concrete", ARPN Journal of Engineering and Applied Sciences, Vol. 5, No. 4, April 2010.
Chappell, W., Meglen, R., Moure-Eraso, R., Solomons, C., Tsongas, T., "Human health effects of molybdenum in drinking water", Environmental Protection Agency, Washington, April 2004.
Chemical Book , Molybdenum chemical properties, April 2024. https://www.chemicalbook.com/
Chen, T., Mansfield, C. D., Ju, L., Baird, D. G., "The influence of mechanical recycling on the properties of thermotropic liquid crystalline polymer and long glass fiber reinforced polypropylene", Composites Part B: Engineering, Vol. 200, November 2020.
Chu, H., Qian, C., Tian, B., Qi, S., Wang, J., Xin, B., "Pyrometallurgy coupling bioleaching for recycling of waste printed circuit boards", Resources, Conservation and Recycling, Vol. 178, March 2022.
Cucchiella, F., D′Adamo, I., Koh, S. C. L., Rosa, P., "Recycling of WEEEs: an economic assessment of present and future e-waste streams", Renewable and Sustainable Energy Reviews, Vol. 51, pp. 263-272, November 2015.
Cui, H., Anderson, C. G., "Literature review of the hydrometallurgical recycling of printed circuit boards (PCBs)", Journal of Advanced Chemical Engineering, January 2016.
Cui, Q., Li, A., Gao, N., "Study on characteristics of printed circuit board liberation and its crushed products", Waste Management & Research, Vol. 30, Issue 11, pp. 1178-1186, November 2012.
Diaz Caselles, L., Roosz, C., Hot, J., Blotevogel, S., Cyr, M., "Immobilization of molybdenum by alternative cementitious binders and synthetic C-S-H: an experimental and numerical study", Science of the Total Environment, Vol. 789, October 2021.

Engelsen, C. J., van der Sloot, H. A., Wibetoe, G., Justnes, H., Lund, W., Stoltenberg-Hansson, E., "Leaching characterisation and geochemical modelling of minor and trace elements released from recycled concrete aggregates", Cement and Concrete Research, Vol. 40, Issue 12, pp. 1639-1649, December 2010.
Faraji, F., Golmohammadzadeh, R., Pickles, C. A., "Potential and current practices of recycling waste printed circuit boards: a review of the recent progress in pyrometallurgy", Journal of Environmental Management, Vol. 316, August 2022.
Fawell, J. K., Lund, U., Mintz, B., "Molybdenum in drinking-water", World Health Organization, Geneva, 1996.
Gonçalves, R. M., Martinho, A., Oliveira, J. P., "Recycling of reinforced glass fibers waste: current status", Materials, Vol. 15, Issue 4, pp. 1596, February 2022.
Gopalraj, S. K., Kärki, T., "A review on the recycling of waste carbon fibre/glass fibre-reinforced composites: fibre recovery, properties and life-cycle analysis", SN Applied Sciences, Vol. 2, February 2020.
Grivé, M., Olmeda, J., "Molybdenum behaviour in cementitious materials (AMPHOS)", European Commission, State of the Art Report, May 2015.
Gupta, U. C., "Molybdenum in agriculture", digitally printed, Cambridge University Press, New York, 2007.
Hadi, P., Xu, M., Lin, C. S. K., Hui, C.W., McKay, G., "Waste printed circuit board recycling techniques and product utilization", Journal of Hazardous Materials, Vol. 283, pp. 234-243, February 2015.
Hearle, J. W. S., "High-performance fibres", Woodhead Publishing Limited, England, 2001.
Holinski, R., Gänsheimer, J., "A study of the lubricating mechanism of molybdenum disulfide", Wear, Vol. 19, Issue 3, pp. 329-342, March 1972.
Hwang, C.L., Chiang, C.H., Huynh, T.P., Vo, D.H., Jhang, B.J., Ngo, S.H., "Properties of alkali-activated controlled low-strength material produced with waste water treatment sludge, fly ash, and slag", Construction and Building Materials, Vol. 135, pp. 459-471, March 2017.
Hyks, J., Nesterov, I., Mogensen, E., Jensen, P.A., Astrup, T., "Leaching from waste incineration bottom ashes treated in a rotary kiln", Waste Management, Vol. 29, Issue 10 , pp 995-1007, September 2011.
International Molybdenum Association ,global molybdenum market information ,2020. https://www.imoa.info/index.php
Jadhav, U., Hocheng, H., "Hydrometallurgical recovery of metals from large printed circuit board pieces", Scientific Reports, 2015.
Karataş, M. A., Gökkaya, H., "A review on machinability of carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) composite materials", Defence Technology, Vol. 14, Issue 4, pp. 318-326, August 2018.
Kim, B.J., Jang, J.G., Park, C.Y., Han, O.H., Kim, H.K., "Recycling of arsenic-rich mine tailings in controlled low-strength materials", Journal of Cleaner Production, Vol. 118, pp. 151-161, April 2016.
Khater, M. A., "High-speed printed circuit boards: A tutorial", IEEE Circuits and Systems Magazine, Vol. 20, Issue 3, pp. 34-45, August 2020.
Kindness, A., Lachowski, E. E., Minocha, A. K., Glasser, F. P., "Immobilisation and fixation of molybdenum (VI) by Portland cement", Waste Management, Issue 2, pp. 97-102, 1994.
Kreze, T., Stana-Kleinschek, K., Ribitsch, V., "Adsorption behavior of cellulose fibers", Lenzinger Berichte, pp. 28-31, January 2001.
Kumar, A., Holuszko, M. E., Janke, T., "Analysis of rejects from waste printed circuit board processing as an alternative fuel for the cement industry", Waste Management, Vol. 60, pp. 388-395, February 2017.
Kumar, A., Holuszko, M. E., Janke, T., "Characterization of the non-metal fraction of the processed waste printed circuit boards", Waste Management, Vol. 75, pp. 94-102, May 2018.
Lamas, W. de Q., Palau, J. C. F., de Camargo, J. R., "Waste materials co-processing in cement industry: ecological efficiency of waste reuse", Renewable and Sustainable Energy Reviews, Vol. 19, pp. 200-207, March 2013.
Lange, S., Deissmann, G., Read, D., Isaacs, M., Felipe-Sotelo, M., Bosbach, D., "Structural uptake and retention of safety relevant radionuclides in cementitious systems", AMPHOS 21 Consulting S.L., 2015.
Lange, S., Klinkenberg, M., Barthel, J., Bosbach, D., Felipe-Sotelo, M., Deissmann, G., "Uptake and retention of molybdenum in cementitious systems", Applied Geochemistry, Vol. 119, August 2020.

Lu, C.C., Hsu, M. H., Lin, Y.P., "Evaluation of heavy metal leachability of incinerating recycled aggregate and solidification/stabilization products for construction reuse using TCLP, multi-final pH and EDTA-mediated TCLP leaching tests", Journal of Hazardous Materials, Vol 368, pp. 336-344, April 2019.
Mancini, G., Palmeri, F., Luciano, A., Viotti, P., Fino, D., "Partial stabilization of Mo-containing hazardous wastes using a ferrous sulfate-based additive as a redox agent", Waste and Biomass Valorization, Vol. 11, pp. 5493–5502, May 2020.
Marques, A. C., Marrero, J. M. C., de Fraga Malfatti, C., "A review of the recycling of non-metallic fractions of printed circuit boards", Springerplus, October 2013.
Marty, N. C. M., Grangeon, S., Elkaïm, E., Tournassat, C., Fauchet, C., Claret, F., "Thermodynamic and crystallographic model for anion uptake by hydrated calcium aluminate (AFm): an example of molybdenum", Scientific Reports, Vol. 8, NO. 7943, May 2018.
Mendel, R. R., Bittner, F., "Cell biology of molybdenum", Biochimica et Biophysica Acta, Vol 1763, Issue 7, pp. 621-635, July 2006.
Naganathan, S., Abdul Razak, H., Abdul Hamid, S. N., "Corrosivity and leaching behavior of controlled low-strength material (CLSM) made using bottom ash and quarry dust", Journal of Environmental Management, Vol 128, pp. 637-641, October 2013.
Oliveux, G., Bailleul, J.L., Le Gal La Salle, E., "Chemical recycling of glass fibre reinforced composites using subcritical water", Applied Science and Manufacturing, Vol 43, Issue 11, pp. 1809-1818, November 2012.
Outteridge, T., Kinsman, N., Ronchi, G., Mohrbacher, H., "Editorial: industrial relevance of molybdenum in China", Advances in Manufacturing, Vol 8, pp. 35-39, 2020.
Patel, F., Lakshmi, B., "Bioleaching of copper and nickel from mobile phone printed circuit board using Aspergillus fumigatus A2DS", Brazilian Journal of Microbiology, June 2021.
Priya, A., Hait, S., "Comprehensive characterization of printed circuit boards of various end-of-life electrical and electronic equipment for beneficiation investigation", Waste Management, Vol. 75, pp. 103-123, May 2018.
Rajak, D. K., Pagar, D. D., Menezes, P. L., Linul, E., "Fiber-reinforced polymer composites: manufacturing, properties, and applications", Polymers, Vol. 11, Issue 10, October 2019.
Rajak, D. K., Wagh, P. H., Linul, E., "Manufacturing technologies of carbon/glass fiber-reinforced polymer composites and their properties: a review", Advanced Materials Research, Vol. 13, Issue 5, October 2021.
Rathore, N., Panwar, N. L., "Environmental impact and waste recycling technologies for modern wind turbines: An overview", Waste Management & Research, Vol. 41, Issue 4, pp. 744-759, April 2023.
Richardson, I. G., "Tobermorite/jennite- and tobermorite/calcium hydroxide-based models for the structure of C-S-H: applicability to hardened pastes of tricalcium silicate, β-dicalcium silicate, Portland cement, and blends of Portland cement with blast-furnace slag, metakaolin, or silica fume", Cement and Concrete Research, Vol. 34, Issue 9, pp. 1733-1777, September 2004.
Saadoon, T., Gómez-Meijide, B., Garcia, Á., "Prediction of water evaporation and stability of cold asphalt mixtures containing different types of cement", Construction and Building Materials, Vol. 186, pp. 751-761, October 2018.
Sartz, L., Bäckström, M., Karlsson, S., Allard, B., "Strategy for instant neutralisation and metal immobilisation in ARD", International Mine Water Association (IMWA) 2010, pp. 267-270, Sydney, Nova Scotia, Canada, 2010.
Statista, "Glass fiber capacity worldwide from 2011 to 2022",2023.https://www.statista.com/statistics/1177580/global-glass-fiber-capacity/
Sun, Z., Shen, Z., Ma, S., Zhang, X., "Sound absorption application of fiberglass recycled from waste printed circuit boards", Materials and Structures, Vol. 48, pp. 387-392, 2015.
Tang, P., Chen, W., Xuan, D., Zuo, Y., Poon, C. S., "Investigation of cementitious properties of different constituents in municipal solid waste incineration bottom ash as supplementary cementitious materials", Journal of Cleaner Production, Vol. 258, June 2020.
Tang, P., Florea, M. V. A., Spiesz, P., Brouwers, H. J. H., "Characteristics and application potential of municipal solid waste incineration (MSWI) bottom ashes from two waste-to-energy plants", Construction and Building Materials, Vol. 83, pp. 77-94, May 2015.
Topçu, İ. B., Elgün, V. B., "Influence of concrete properties on bleeding and evaporation", Cement and Concrete Research, Vol. 34, Issue 2, pp. 275-281, February 2004.
Uliasz-Bocheńczyk, A., Deja, J., Mokrzycki, E., "The use of alternative fuels in the cement industry as part of circular economy", Archives of Environmental Protection, Vol. 47, No. 4, pp. 109-117, 2021.
United States Geological Survey,Molybdenum: world mine production ,by country or locality, April 2023.
Van Gerven, T., Van Baelen, D., Dutré, V., Vandecasteele, C., "Influence of carbonation and carbonation methods on leaching of metals from mortars", Cement and Concrete Research, Vol. 34, Issue 1, pp. 149-156, January 2004.
Van Thillo, L., Blom, J., Moreels, A., Craeye, B., "Influence of aggregates, glass fibre reinforcement and recycled aggregates on polyester mortar", Construction and Building Materials, Vol. 293, July 2021.
Vollpracht, A., Brameshuber, W., "Binding and leaching of trace elements in Portland cement pastes", Cement and Concrete Research, Vol. 79, pp. 76-92, January 2016.
Wojnowska-Baryła, I., Bernat, K., Zaborowska, M., "Plastic waste degradation in landfill conditions: the problem with microplastics, and their direct and indirect environmental effects", International Journal of Environmental Research and Public Health, Vol. 19, Issue 20, October 2022.
Zeng, X., Mathews, J. A., Li, J., "Urban mining of e-waste is becoming more cost-effective than virgin mining", Environmental Science and Technology, March 2018.
章裕民，焚化處理技術，修訂一版，文京圖書，台北市，民國八十九年。
黃啟峰，「2021水泥業提升能源效率研討會」，2021年8月。
李明洋，「二維過渡金屬硫族化合物異質接面的合成與應用發展」，真空科技，31卷2期，9-12頁，2018年6月。
黃兆龍，高性能混凝土理論與實務，初版，詹氏書局，台北市，民國九十二年。
章裕民，廢棄物處理，第二版，文京圖書，台北市，民國八十九年。
林健三、林健榮，固體廢棄物處理，初版，高立圖書，台北縣，民國九十三年。
周展宇，「廢棄玻璃纖維樹脂粉再利用製成透水黏結砂漿」，國立臺北科技大學，碩士論文，民國111年。
陳建安，「廢棄電路板非金屬成分資源化於水泥混凝土之探討」，國立中央大學，碩士論文，民國100年。
顏保儀，「PCB摻料應用於一般營建混凝土工程之研究」，國立臺北科技大學，碩士論文，民國99年。
蔡雅亘，「廢玻璃纖維經不同表面處理進行回收再利用之研究」，朝陽科技大學，碩士論文，民國111年。

指導教授

張木彬(Moo-Been Chang)

審核日期

2024-7-26

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