開發一具備簡易製程之壓電水凝膠應用於自供電感測

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許博恩(Po-En Hsu) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

開發一具備簡易製程之壓電水凝膠應用於自供電感測
(A Facile Piezogel Design for Self-Powered Sensing Application)

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至系統瀏覽論文 (2029-10-17以後開放)

摘要(中)

具有優異壓電性的功能型水凝膠在下一代自供電電子設備有極大的關注度。
然而，壓電水凝膠本身壓電性質的不確定性與傳統壓電水凝膠的電子設備輸出
性能不足限制了他們的發展性。本研究提出一種基於金屬二硫化物的奈米複合
壓電水凝膠，並探討所設計的壓電水凝膠整體的壓電特性。此外，我們將設計
好的壓電水凝膠整合到壓電奈米壓電元件中，此元件具備著 2.2 V、12 nA 的輸出表現，並具有 355 nW/m2 的瞬時功率密度，且可以對 1 μF 的電容器進行充放電。並且我們將其應用於不同重量、不同粗糙度的主動感測應用。

摘要(英)

Functional hydrogels with excellent piezoelectric properties have garnered significant attention for next-generation self-powered electronic devices. However, the inherent uncertainty of the piezoelectric properties of piezoelectric hydrogels and the insufficient output performance of traditional piezoelectric hydrogels in electronic devices have limited their development potential. In this study, a piezoelectric gel (Piezogel) based on metal disulfide nanocomposites is proposed, and its overall piezoelectric characteristics are investigated. In addition, we will integrate the designed piezoelectric hydrogel into a piezoelectric nanogenerator, which exhibits an output performance of 2.2 V and 12 nA, with an instantaneous power density of 355 nW/m2, and can charge and discharge a 1 μF capactior. We will apply this device
toactive sensing applications with different weights and suface roughness.

關鍵字(中)

★ 壓電材料
★ 水凝膠

關鍵字(英)

論文目次

目錄
摘要…………………………………………………………………………………..i
Abstract………………………………………………………………………………ii
目錄…………………………………………………………………………………iv
圖目錄………………………………………………………………………………..v
表目錄……………………………………………………………………………...vii
第一章緒論…………………………………………………………………………1
第二章文獻回顧……………………………………………………………………2
2-1 Piezogel 簡介……………………………………………….………………..2
2-1-1 天然聚合Piezogel……………………………..……….………………3
2-1-2 合成聚合Piezogel……………………………………….……….…….4
2-2 甲基丙烯酸酐明膠…………………………………………………………5
2-3 二維材料與層狀二硫族化物………………………………………………7
2-4 研究動機及材料選擇……………………………………………………....8
第三章實驗方法…………………………………………………………………..10
3-1 材料製備…………………………………………………………………..10
3-1-1 甲基丙烯酸酐明膠合成………………………………………………10
3-1-2奈米材料合成…………..…….………………………………………..11
3-1-3 Piezogel 製備………………………………………………….……….11
3-1-4 PENG 製備………………………………………………….…………12
3-2 材料鑑定儀器………………………………………………………………12
3-2-1 核磁共振光譜儀……………………………………………………...13
3-2-2 掃描式電子顯微鏡…………………………………………………...14
3-2-3 拉曼光譜……………………………………………………………...15
3-2-4 X 光繞射儀……………………………………….……………………16
第四章結果與討論………………………………………………………………..17
4-1 甲基丙烯酸酐明膠鑑定與分析…………………………………………..17
4-2 材料鑑定與分析…………………………………………….…...………..18
4-2-1 表貌………………………………………………...……..…………...18
4-2-2 拉曼光譜鑑定………………………………..………………...……...18
4-2-3 晶形鑑定……………………………………..…………......................19
4-3 Piezogel 之鑑定與分析……………………………………….……………20
4-3-1 Piezogel 表貌…………………………………………….…………….20
4-3-2 Piezogel 之拉曼光譜鑑定……………………………….…………….21
4-3-3 Piezogel 之元素分析…………………………………….…………….21
4-3-4 Piezogel 交聯劑添加之機械性質………………………….………….22
4-3-5 Piezogel 奈米材料添加之機械性質……………………...………..….23
4-3-6 Piezogel 之壓電常數……………………………………….………….24
4-3-7 Piezogel 之細胞毒性……………………………………….………….24
4-4 Piezogel 輸出表現……………………………………………….…………24
4-4-1 實驗裝置架設………………………………………………………...24
4-4-2 PENG 機制探討…………………………………………….…………25
4-4-3 電性輸出表現………………………………………………………...26
4-4-4 驅動商用電子元件…………………………………………………...27
4-4-5 壓力式動作感測設計………………………………………………...29
4-4-6 文獻比較……………………………………………………………...30
第五章結論與未來展望…………………………………………………………..32
參考文獻

參考文獻

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指導教授

洪緯璿(Wei-Hsuan Hung)

審核日期

2024-10-17

推文