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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/100046


    Title: Li2MnSiO4@C nanocomposite as a high-capacity cathode material for Li-ion batteries
    Authors: 鄭芳怡;Hu, Zhe;Zhang, Kai;Gao, Haiyan;Duan, Wenchao;Cheng, Fangyi;Liang, Jing;Chen, Jun
    Contributors: 地球科學學院大氣科學學系
    Keywords: ascorbic acid;carbon;cathodes;electrochemistry;ions;lithium;lithium batteries;nanocomposites;particle size;reducing agents;scanning electron microscopy;transmission electron microscopy;X-ray diffraction
    Date: 2013-10-28
    Issue Date: 2026-04-21 13:46:53 (UTC+8)
    Publisher: Royal Society of Chemistry
    Abstract: 摘要: In this paper, we report on the preparation of a Li₂MnSiO₄C nanocomposite and its application as a high-capacity cathode material for rechargeable Li-ion batteries. Li₂MnSiO₄C was synthesized via a hydrothermal-assisted solution route by using ascorbic acid as a carbon source and reductant. Based on the characterization by XRD, SEM, TEM, BET, elemental analysis and Raman analysis, it was found that the as-obtained homogenous Li₂MnSiO₄C nanocomposite was composed of a Li₂MnSiO₄ core in a high-purity phase and a graphitized carbon shell. The electrochemical measurement results showed that Li₂MnSiO₄C with an average particle size of 22.8 nm exhibited enhanced electrochemical properties, with initial discharge capacities of 281.5 mA h g⁻¹ at 25 °C and 321.4 mA h g⁻¹ at 45 °C, suggesting two lithium ions per formula unit.
    出版日期: 2013-01-01
    出處: Journal of materials chemistry. A, Materials for energy and sustainability, 2013-01, Vol.1 (40), p.12650-12656
    資源來源: Royal Society of Chemistry
    識別號: ISSN: 2050-7488
    識別號: ISSN: 2050-7496
    識別號: EISSN: 2050-7496
    識別號: DOI: 10.1039/c3ta12106b
    Appears in Collections:[Department of Atmospheric Sciences] journal & Dissertation

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