Determination of synthetic polycyclic musks in aqueous samples by ultrasound-assisted dispersive liquid-liquid microextraction and gas chromatography-mass spectrometry

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题名:	Determination of synthetic polycyclic musks in aqueous samples by ultrasound-assisted dispersive liquid-liquid microextraction and gas chromatography-mass spectrometry
作者:	丁望賢;Yang, Ching-Ya;Ding, Wang-Hsien
贡献者:	理學院化學學系
关键词:	Analysis;Analytical Chemistry;Biochemistry;Carbon tetrachloride;Characterization and Evaluation of Materials;Chemistry;Chemistry and Materials Science;Extraction;Fatty Acids, Monounsaturated - analysis;Fatty Acids, Monounsaturated - isolation & purification;Food Science;Gas chromatography;Gas Chromatography-Mass Spectrometry - methods;Laboratory Medicine;Liquid Phase Microextraction - methods;Mass spectrometry;Mathematical analysis;Monitoring/Environmental Analysis;Musk;Odorants - analysis;Original Paper;Sensitivity and Specificity;Spectrometry;Spectroscopy;Standard deviation;Ultrasonics - methods;Waste Disposal, Fluid;Water - analysis;Water Pollutants, Chemical - analysis;Water Pollutants, Chemical - isolation & purification
日期:	2012-02-01
上传时间:	2026-04-21 13:53:23 (UTC+8)
出版者:	Springer Verlag;Berlin/Heidelberg: Springer-Verlag
摘要:	摘要： A simple and solvent-minimized procedure for the determination of six commonly found synthetic polycyclic musks in aqueous samples using ultrasound-assisted dispersive liquid–liquid microextraction (UA-DLLME) coupled with gas chromatography–mass spectrometry (GC-MS) is described. The parameters affecting the extraction efficiency of analytes from water samples were systematically investigated. The best extraction conditions involved the rapid injection of a mixture of 1.0 mL of isopropyl alcohol (as a dispersant) and 10 μL of carbon tetrachloride (as an extractant) into 10 mL of water containing 0.5 g of sodium chloride in a conical-bottom glass tube. After ultrasonication for 1.0 min and centrifugation at 5,000 rpm (10 min), the sedimented phase 1.0 μL was directly injected into the GC-MS system. The limits of quantitation (LOQs) were less than 0.6 ng/L. The precision for these analytes, as indicated by relative standard deviations (RSDs), was less than 11% for both intra- and interday analysis. Accuracy, expressed as the mean extraction recovery, was between 71 and 104%. Their total concentrations were determined in the range from 8.3 to 63.9 ng/L in various environmental samples by using a standard addition method. 其他題名： Anal Bioanal Chem 出版者： Berlin/Heidelberg: Springer-Verlag 出版日期： 2012-02 出處： Analytical and bioanalytical chemistry, 2012-02, Vol.402 (4), p.1723-1730 資源來源： EBSCOhost Academic Search Premier 版權： Springer-Verlag 2011 版權： COPYRIGHT 2012 Springer 識別號： ISSN: 1618-2642 識別號： ISSN: 1618-2650 識別號： EISSN: 1618-2650 識別號： DOI: 10.1007/s00216-011-5573-3 識別號： PMID: 22139524
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