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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/100201


    Title: Drops sitting on a tilted plate: Receding and advancing pinning
    Authors: 曹恆光;Chou, Tung-He;Hong, Siang-Jie;Sheng, Yu-Jane;Tsao, Heng-Kwong
    Contributors: 工學院化學工程與材料工程學系
    Keywords: Chemistry;contact angle;deformation;Exact sciences and technology;General and physical chemistry;Gibbs free energy;liquids;mathematical models;Solid-liquid interface;Surface physical chemistry;surface tension
    Date: 2012-03-20
    Issue Date: 2026-04-21 13:53:27 (UTC+8)
    Publisher: American Chemical Society;Washington, DC: American Chemical Society
    Abstract: 摘要: The wetting behavior of a liquid drop sitting on an inclined plane is investigated experimentally and theoretically. Using Surface Evolver, the numerical simulations are performed based on the liquid-induced defect model, in which only two thermodynamic parameters (solid–liquid interfacial tensions before and after wetting) are required. A drop with contact angle (CA) equal to θ is first placed on a horizontal plate, and then the plate is tilted. Two cases are studied: (i) θ is adjusted to the advancing CA (θa) before tilting, and (ii) θ is adjusted to the receding CA (θr) before tilting. In the first case, the uphill CA declines and the downhill CA remains unchanged upon inclination. When the tilted drop stays at rest, the pinning of the receding part of the contact line (receding pinning) and the depinning of the advancing part of the contact line (advancing depinning) are observed. The free energy analysis reveals that upon inclination, the reduction of the solid–liquid free energy dominates over the increment of the liquid–gas free energy associated with shape deformation. In the second case, the downhill CA grows and the uphill CA remains the same upon inclination. Advancing pinning and receding depinning are noted for the tilted drop at rest. The free energy analysis indicates that upon inclination, the decrease of the liquid–gas free energy compensates the increment of the solid–liquid free energy. The experimental results are in good agreement with those of simulations.
    其他題名: Langmuir
    出版者: Washington, DC: American Chemical Society
    出版日期: 2012-03-20
    出處: Langmuir, 2012-03, Vol.28 (11), p.5158-5166
    資源來源: ACS:American Chemical Society
    版權: Copyright © 2012 American Chemical Society
    版權: 2015 INIST-CNRS
    識別號: ISSN: 0743-7463
    識別號: ISSN: 1520-5827
    識別號: EISSN: 1520-5827
    識別號: DOI: 10.1021/la300257t
    識別號: PMID: 22372858
    識別號: CODEN: LANGD5
    Appears in Collections:[Department of Chemical and Materials Engineering] journal & Dissertation

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