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    題名: Temperature effects on the oxidation of low carbon steel in N 2-H 2-H 2O at 800-1200 �c
    作者: 陳立業;Yin, H.;Chan, S. L. I.;Yuen, W. Y. D.;Young, D. J.
    貢獻者: 工學院化學工程與材料工程學系
    關鍵詞: Applied sciences;Chemistry and Materials Science;Corrosion;Corrosion and Coatings;Corrosion environments;Exact sciences and technology;Inorganic Chemistry;Materials Science;Metallic Materials;Metals. Metallurgy;Original Paper;Tribology
    日期: 2012-06-01
    上傳時間: 2026-04-21 13:56:29 (UTC+8)
    出版者: Springer New York;New York: Springer-Verlag
    摘要: 摘要: A low carbon, low silicon steel was reacted with flowing N 2 –H 2 –H 2 O gases at temperatures of 800–1,200 °C, to produce scales of fast-growing wüstite, the only stable iron oxide under these conditions. Scaling kinetics were parabolic, after an initial period of linear reaction. The parabolic rate constants measured in the range 800–1,100 °C were two orders of magnitude lower than values predicted from Wagner’s diffusion theory, and activation energies were higher than expected. At 1,200 °C, however, the measured parabolic rate constant was in agreement with prediction. The initial period of linear kinetics was extensive at 1,100 °C, and rates are in agreement with those predicted for surface reaction rate control. Because the surface reaction is much less sensitive to temperature than the solid-state diffusion process, the extent of the linear kinetic regime is smaller at lower temperatures.
    其他題名: Oxid Met
    出版者: New York: Springer-Verlag
    出版日期: 2012-06
    出處: Oxidation of metals, 2012-06, Vol.77 (5-6), p.305-323
    版權: Springer Science+Business Media, LLC 2012
    版權: 2015 INIST-CNRS
    識別號: ISSN: 0030-770X
    識別號: EISSN: 1573-4889
    識別號: DOI: 10.1007/s11085-012-9287-5
    識別號: CODEN: OXMEAF
    顯示於類別:[化學工程與材料工程學系 ] 期刊論文

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