Synthesis and characterization of three-layered zinc phosphites containing tert-octylamine molecules with template and ligand roles

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/100515

Title:	Synthesis and characterization of three-layered zinc phosphites containing tert-octylamine molecules with template and ligand roles
Authors:	李光華;Wang, Chih-Min;Chiu, Cheng-Wei;Lin, Hsiu-Mei;Lii, Kwang-Hwa
Contributors:	理學院化學學系
Keywords:	ABSORPTION SPECTROSCOPY;AMINES;Cross-disciplinary physics: materials science;rheology;Exact sciences and technology;Growth from solutions;HYDROTHERMAL SYNTHESIS;INFRARED SPECTRA;INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;LAYERS;Ligand and template;LIGANDS;Materials science;Methods of crystal growth;physics of crystal growth;MONOCRYSTALS;PHOSPHOROUS ACID;Physics;REACTIVITY;Solvothermal synthesis;THERMAL GRAVIMETRIC ANALYSIS;X-RAY DIFFRACTION;ZINC;Zinc phosphite
Date:	2013-01-01
Issue Date:	2026-04-21 14:05:02 (UTC+8)
Publisher:	Academic Press Inc.;Amsterdam: Elsevier Inc
Abstract:	摘要： Three-layered zinc phosphites containing single monoamine molecules with different roles have been synthesized using hydro(solvo)thermal methods and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and infrared spectroscopy. Compound 1, (C8H17NH3)4Zn3(HPO3)5·3H2O, consists of 20-ring layer structures sandwiched by water molecules and protonated tert-octylamine molecules. The structure of Zn(C8H17NH2)(HPO3) (compound 2) is composed of 4.82 network structures, wherein the tert-octylamines are coordinated to the Zn atom as pendant groups. Compound 3, (C8H17NH3)2Zn4(C8H17NH2)(HPO3)5, was prepared in which the amine plays a dual role as both a ligand and a countercation. In addition, compound 1 is the first layered metal phosphite with large 20-ring windows. This group of substances represents the first example of the preparation of compounds in which the reactivity of incorporated single amine molecules is varied by adjusting the synthesis conditions. The first layered metal phosphite with large 20-ring windows, (C8H17NH3)4Zn3(HPO3)5·3H2O (1), sandwiched by water molecules and protonated tert-octylamine molecules. [Display omitted] •The first example of zinc phosphites contains amine molecules with template and ligand roles.•The reactivity of single amine molecules is varied by adjusting the synthesis conditions.•Compound 1 contains the largest pore opening of 20-rings in known layered metal phosphites.•Compound 3 has dual roles of amine molecules in its structure. 出版者： Amsterdam: Elsevier Inc 出版日期： 2013-08-01 出處： Journal of solid state chemistry, 2013-08, Vol.204, p.16-20 版權： 2013 Elsevier Inc. 版權： 2014 INIST-CNRS 識別號： ISSN: 0022-4596 識別號： EISSN: 1095-726X 識別號： DOI: 10.1016/j.jssc.2013.05.003 識別號： CODEN: JSSCBI
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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