Synthesis and characterization of highly conductive plasticized double core organic-inorganic hybrid electrolytes for lithium polymer batteries

NCU Institutional Repository > 理學院 > 化學學系 > 期刊論文 > Item 987654321/100619

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://ir.lib.ncu.edu.tw/handle/987654321/100619

题名:	Synthesis and characterization of highly conductive plasticized double core organic-inorganic hybrid electrolytes for lithium polymer batteries
作者:	史艾佳;Wu, Hao-Yiang;Saikia, Diganta;Chao, Hung-Yu;Pan, Yu-Chi;Fang, Jason;Tsai, Li-Duan;Fey, George;Kao, Hsien-Ming
贡献者:	理學院化學學系
关键词:	Electric batteries;Electrolytes;Ethers;Glycols;Lithium;Lithium batteries;Membranes;Solvents
日期:	2013-04-22
上传时间:	2026-04-21 14:08:51 (UTC+8)
出版者:	Elsevier
摘要:	摘要： A new highly ion conductive plasticized organicainorganic hybrid electrolyte membrane based on triblock co-polymer poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol) bis(2-aminopropyl ether) (ED2003), poly(ethylene glycol) diglycidyl ether (PEGDGE), poly(vinylidene fluoride-co-hexafluoropropylene) (PVdFaHFP), 2,4,6-trichloro-1,3,5-triazine (cyanuric chloride, CC) and 3-(glycidyloxypropyl)trimethoxysilane (GLYMO) has been synthesized by a sol-gel process and characterized by a variety of experimental techniques. FTIR and 13C NMR measurements have been performed to study the molecular structure of the hybrid as well as the interactions among the constituents of the membrane. The hybrid membrane is plasticized with different electrolyte solvents and exhibits remarkable swelling ratios in the range of 670a800%. The ionic conductivity of the hybrid electrolyte membranes is varied with different electrolyte solvents and shows a maximum value of 6.9 A 10a3 S cm-1 for 1 M LiClO4 in EC/PC at 30 degree C. The test cell carries initial discharge capacity of 115 mAh ga1 at a current rate of 0.2 C and shows good cycling performance up to 100 cycles and coulombic efficiency of 98a99% for the entire cycles. The plasticized organicainorganic hybrid electrolyte membrane holds promise for applications in lithium polymer batteries. 出版日期： 2013-09-01 出處： Journal of power sources, 2013-09, Vol.238, p.265-273 資源來源： Access articles in the ScienceDirect collection 識別號： ISSN: 0378-7753 識別號： DOI: 10.1016/j.jpowsour.2013.03.097
显示于类别:	[化學學系] 期刊論文

文件中的档案:

档案	描述	大小	格式	浏览次数
index.html		0Kb	HTML	18	检视/开启

在NCUIR中所有的数据项都受到原著作权保护.

社群 sharing

数据加载中.....