摘要: A solid lithium superionic conductor Li11AlP2S12 with a thio-LISICON analogous structure has been synthesized for the first time by sintering at 500 °C (LAlPS500). Such a pure lithium ionic conductor shows a conductivity of 8.02 × 10(-4) S cm(-1) at 25 °C, a low Ea of 25.4 kJ mol(-1), and a wide electrochemical voltage window of higher than 5.0 V (vs. Li(+)/Li). This facilitation of Li ionic conduction suggests the potential application in solid lithium ion batteries. 其他題名: Chem Commun (Camb) 出版者: England 出版日期: 2016-05-04 出處: Chemical communications (Cambridge, England), 2016-05, Vol.52 (36), p.6091-6094 資源來源: Royal Society of Chemistry 識別號: ISSN: 1364-548X 識別號: EISSN: 1364-548X 識別號: DOI: 10.1039/c6cc02131j 識別號: PMID: 27068086