Electrochemical performance of rechargeable Li/LiFePO4 cells with ionic liquid electrolyte: Effects of Li salt at 25 �c and 50 �c

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Title:	Electrochemical performance of rechargeable Li/LiFePO4 cells with ionic liquid electrolyte: Effects of Li salt at 25 �c and 50 �c
Authors:	李岱洲;Wongittharom, Nithinai;Lee, Tai-Chou;Hsu, Ching-Hua;Ting-Kuo Fey, George;Huang, Kai-Pin;Chang, Jeng-Kuei
Contributors:	工學院化學工程與材料工程學系
Keywords:	Applied sciences;Direct energy conversion and energy accumulation;Electrical engineering. Electrical power engineering;Electrical power engineering;Electrochemical conversion: primary and secondary batteries, fuel cells;Electrolyte;Exact sciences and technology;Ionic liquid;Li battery;Li salt;Temperature
Date:	2013-06-14
Issue Date:	2026-04-21 14:11:32 (UTC+8)
Publisher:	Elsevier;Amsterdam: Elsevier B.V
Abstract:	摘要： Lithium hexafluorophosphate (LiPF6) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) are used as Li salts in butylmethylpyrrolidinium–bis(trifluoromethanesulfonyl)imide (BMP–TFSI) ionic liquid (IL) electrolyte for Li/LiFePO4 cells. This kind of IL electrolyte shows high thermal stability (>400°C) and non-flammability, and is thus ideal for high-safety applications. At 25°C, a maximum capacity of 113mAhg−1 (at 0.1 C) is found for LiFePO4 in the IL with 0.5M LiTFSI. An excessive LiTFSI concentration leads to a capacity decrease due to reduced electrolyte ionic conductivity. At 50°C, the measured capacity and rate capability are significantly improved compared to those at 25°C. With 1M LiTFSI-doped IL electrolyte (the optimum concentration at 50°C), a capacity of 140mAhg−1 is found at 0.1 C and 45% of the capacity can be retained when the rate increases to 5 C, values which are comparable to those found in a traditional organic electrolyte. In the IL electrolyte, the LiFePO4 electrode shows better cyclic stability at 50°C than it does at 25°C; this trend is opposite to that found in the organic electrolyte. At 50°C, there is negligible capacity loss of LiFePO4 after 100 charge–discharge cycles in 1M LiTFSI-doped BMP–TFSI IL electrolyte. •LiTFSI is better than LiPF6 as solute in BMP–TFSI IL for Li/LiFePO4 cells.•LiTFSI concentration in IL greatly affects the cell performance.•At 50°C, the cell performance with IL is close to that with organic electrolyte.•The cell shows little decay after 100 cycles at 50°C in the IL electrolyte.•IL electrolyte is ideal for high-temperature and high-safety applications. 出版者： Amsterdam: Elsevier B.V 出版日期： 2013-10-15 出處： Journal of power sources, 2013-10, Vol.240, p.676-682 資源來源： ScienceDirect Journals 版權： 2013 Elsevier B.V. 版權： 2014 INIST-CNRS 識別號： ISSN: 0378-7753 識別號： DOI: 10.1016/j.jpowsour.2013.05.014 識別號： CODEN: JPSODZ
Appears in Collections:	[Department of Chemical and Materials Engineering] journal & Dissertation

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