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| 題名: | In situ scanning tunneling microscopy characterization of thienothiophene-based semiconducting organic molecules adsorbed on a Au(111) electrode |
| 作者: | 姚學麟;Luo, Shu Rong;Chen, Sih Zih;Hsu, Ya Hua;Yau, Shueh Lin;Lin, Yu-Jou;Huang, Peng-Yi;Chen, Ming-Chou |
| 貢獻者: | 理學院化學學系 |
| 關鍵詞: | Adsorption;Anions;Au electrified interface;Charge injection;Condensed matter: electronic structure, electrical, magnetic, and optical properties;Condensed matter: structure, mechanical and thermal properties;Cross-disciplinary physics: materials science;rheology;Electrodes;Exact sciences and technology;In situ STM;Lamella;Molecular adsorption;Order disorder;Physics;Potential-induced ordering;Scanning tunneling microscopy;Surface chemistry;Thienothiophene |
| 日期: | 2013-10-01 |
| 上傳時間: | 2026-04-21 14:13:34 (UTC+8) |
| 出版者: | Elsevier;Kidlington: Elsevier B.V |
| 摘要: | 摘要： Organic molecules with a thienothiophene core are promising candidates for use in the fabrication of organic thin film transistors. In addition to the nature of the molecule, the adsorption orientation and spatial structure of admolecules at metal electrodes also affects the efficiency of charge injection at the molecule/metal interface. Scanning tunneling microscopy (STM), which is well-known for its sub-nanometer resolution, is particularly suitable in studying the structure of this interface. Dithieno[2,3-b:3,2-d]thiophene diphenyl (C6H5-DTT-C6H5) adsorbed on Au(111) electrode was previously examined. In this study we looked at molecules with perfluorophenyl substituents, 2-pentafluorophenyl-6-phenyldithieno[2,3-b:3′,2′-d]thiophene(C6F5-DTT-C6H5,1) and 2,6-bis(pentafluorophenyl)dithieno[3,2-b;2′,3′-d]thiophene(C6F5-DTT-C6F5, 2. In situ STM results obtained in 0.1M HClO4 showed that these molecules could be adsorbed in ordered adlattices on a Au(111) electrode from dosing solutions made of 50μM 1 or 2 in dicholobenzene. The adsorption strength of these molecules on Au(111) varied greatly with the electrochemical potential. They were mostly stable on Au(111) at 0.3V (vs. reversible hydrogen electrode), but could be displaced by water dipoles and perchlorate anions at E<0.2V and E>0.5V, respectively. It was possible to take advantage of this result to improve the degree of ordering by setting the potential at 0V briefly, then switching back to 0.3V. While 1 was adsorbed in a lamella structure as observed previously with C6H5-DTT-C6H5, 2 was arranged in a very different structure determined largely by the need to optimize the intermolecular interactions. •Thienothiophene-based molecules adsorbed on Au(111) were studied by in situ STM.•A proper potential program could increase molecular ordering.•Admolecules were arranged spatially to accommodate their dipole moments.
出版者： Kidlington: Elsevier B.V
出版日期： 2013-10-01
出處： Surface science, 2013-10, Vol.616, p.155-160
版權： 2013 Elsevier B.V.
版權： 2014 INIST-CNRS
識別號： ISSN: 0039-6028
識別號： EISSN: 1879-2758
識別號： DOI: 10.1016/j.susc.2013.05.013
識別號： CODEN: SUSCAS |
| 顯示於類別: | [化學學系] 期刊論文
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