Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe2O 6(OH)2(CH3CH(NH2)CH 2NH2)�2H2O

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/100832

Title:	Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe2O 6(OH)2(CH3CH(NH2)CH 2NH2)�2H2O
Authors:	李光華;Wang, Chih-Min;Chiu, Cheng-Wei;Lin, Hsiu-Mei;Lii, Kwang-Hwa;Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan, ROC
Contributors:	理學院化學學系
Keywords:	ABSORPTION SPECTROSCOPY;AMINES;ATOMS;BORON;CRYSTALS;EMISSION SPECTRA;EMISSION SPECTROSCOPY;GERMANIUM;INDIUM;INFRARED SPECTRA;INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;LIGANDS;MOLECULES;SYNTHESIS;THERMAL GRAVIMETRIC ANALYSIS
Date:	2013-11-06
Issue Date:	2026-04-21 14:15:44 (UTC+8)
Publisher:	Academic Press Inc.;United States
Abstract:	摘要： A new indium borogermanate incorporating an organic amine ligand, InBGe{sub 2}O{sub 6}(OH){sub 2}(CH{sub 3}CH(NH{sub 2})CH{sub 2}NH{sub 2})·2H{sub 2}O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In{sub 2}O{sub 6}N{sub 4} octahedral dimers, Ge{sub 2}O{sub 6}(OH) double tetrahedra, and BO{sub 3}(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm. - Graphical abstract: The first example of indium borogermanate incorporating an organic amine ligand was synthesized under solvothermal conditions. Infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy have also been studied. 出版者： United States 出版日期： 2013-12-15 出處： Journal of solid state chemistry, 2013-12, Vol.208 識別號： ISSN: 0022-4596 識別號： EISSN: 1095-726X 識別號： DOI: 10.1016/J.JSSC.2013.09.021
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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