Comparison of light out-coupling enhancements in single-layer blue-phosphorescent organic light emitting diodes using small-molecule or polymer hosts

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/100838

Title:	Comparison of light out-coupling enhancements in single-layer blue-phosphorescent organic light emitting diodes using small-molecule or polymer hosts
Authors:	陳錦地;Chang, Yung-Ting;Liu, Shun-Wei;Yuan, Chih-Hsien;Ho, Yu-Hsuan;Chen, Kuan-Yu;Lee, Yi-Ting;Wu, Min-Fei;Lee, Chih-Chien;Wei, Pei-Kuen;Chen, Chin-Ti;Wu, Chih-I
Contributors:	理學院化學學系
Keywords:	ANISOTROPY;Applied physics;Atomic energy levels;BRIGHTNESS;CARRIER MOBILITY;CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;COUPLING;Coupling (molecular);Devices;DIPOLES;Efficiency;ENERGY LEVELS;LIGHT EMITTING DIODES;Luminous efficacy;Maximum power;Organic light emitting diodes;PHOSPHORESCENCE;PHOTOLUMINESCENCE;POLYMERS;Polyvinyl carbazole;Power efficiency;REFRACTIVE INDEX;Refractivity;SIMULATION;TRIPLETS
Date:	2013-11-07
Issue Date:	2026-04-21 14:15:50 (UTC+8)
Publisher:	American Institute of Physics;Melville: AIP Publishing
Abstract:	摘要： Single-layer blue phosphorescence organic light emitting diodes (OLEDs) with either small-molecule or polymer hosts are fabricated using solution process and the performances of devices with different hosts are investigated. The small-molecule device exhibits luminous efficiency of 14.7 cd/A and maximum power efficiency of 8.39 lm/W, which is the highest among blue phosphorescence OLEDs with single-layer solution process and small molecular hosts. Using the same solution process for all devices, comparison of light out-coupling enhancement, with brightness enhancement film (BEF), between small-molecule and polymer based OLEDs is realized. Due to different dipole orientation and anisotropic refractive index, polymer-based OLEDs would trap less light than small molecule-based OLEDs internally, about 37% better based simulation results. In spite of better electrical and spectroscopic characteristics, including ambipolar characteristics, higher carrier mobility, higher photoluminescence quantum yield, and larger triplet state energy, the overall light out-coupling efficiency of small molecule-based devices is worse than that of polymer-based devices without BEF. However, with BEF for light out-coupling enhancement, the improved ratio in luminous flux and luminous efficiency for small molecule based device is 1.64 and 1.57, respectively, which are significantly better than those of PVK (poly-9-vinylcarbazole) devices. In addition to the theoretical optical simulation, the experimental data also confirm the origins of differential light-outcoupling enhancement. The maximum luminous efficiency and power efficiency are enhanced from 14.7 cd/A and 8.39 lm/W to 23 cd/A and 13.2 lm/W, respectively, with laminated BEF, which are both the highest so far for single-layer solution-process blue phosphorescence OLEDs with small molecule hosts. 出版者： Melville: AIP Publishing 出版日期： 2013-11-07 出處： Journal of Applied Physics, 2013-11, Vol.114 (17), p.173106 資源來源： AIP Journals (American Institute of Physics) 版權： 2013 AIP Publishing LLC. 識別號： ISSN: 0021-8979 識別號： EISSN: 1089-7550 識別號： DOI: 10.1063/1.4829677
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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