Diastereoselective vinylalumination for the synthesis of pericosine A, B and C

NCU Institutional Repository > 理學院 > 化學學系 > 期刊論文 > Item 987654321/100963

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://ir.lib.ncu.edu.tw/handle/987654321/100963

题名:	Diastereoselective vinylalumination for the synthesis of pericosine A, B and C
作者:	侯敦仁;Li, Long-Shiang;Hou, Duen-Ren
贡献者:	理學院化學學系
日期:	2014-01-01
上传时间:	2026-04-21 14:19:40 (UTC+8)
出版者:	Royal Society of Chemistry
摘要:	摘要： The vinylalumination of α-substituted aldehydes gave anti - and syn -adducts with moderate diastereoselectivity. The diastereomeric ratio was inverted by the addition of lithium or sodium perchlorates. Thus, both anti - and syn -adducts were isolated and transformed into the biologically active conduritols, pericosine B and C, respectively. Formal synthesis of pericosine A was achieved with the anti -adduct. The rationales for the different diastereoselectivity are discussed. The vinylalumination of α-substituted aldehydes gave anti - and syn -adducts with moderate diastereoselectivity. 出版日期： 2013-11-19 資源來源： Royal Society of Chemistry 識別號： EISSN: 2046-2069 識別號： DOI: 10.1039/c3ra45871g
显示于类别:	[化學學系] 期刊論文

文件中的档案:

档案	描述	大小	格式	浏览次数
index.html		0Kb	HTML	21	检视/开启

在NCUIR中所有的数据项都受到原著作权保护.

社群 sharing